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\(n_{SO2}=\dfrac{6,4}{64}=0,1\left(mol\right)\)
Pt : \(S+O_2\rightarrow\left(t_o\right)SO_2|\)
1 1 1
0,1 0,1
\(n_{O2}=\dfrac{0,1.1}{1}=0,1\left(mol\right)\)
\(V_{O2\left(lt\right)}=0,1.22,4=2,24\left(l\right)\)
⇒ \(V_{O2\left(tt\right)}=\dfrac{2,24.100}{80}=2,8\left(l\right)\)
Chúc bạn học tốt
2KMnO4-to>K2MnO4+MnO2+O2
1,2-------------------------------------0,6 mol
n O2=13,44\22,4=0,6 mol
H =75%
=>m KMnO4 tt= 1,2.158 .100\75=252,8g
\(n_{O_2}=\dfrac{13,44}{22,4}=0,6\left(mol\right)\)
PTHH: 2KMnO4 ---to→ K2MnO4 + MnO2 + O2
Mol: 1,2 0,6
\(m_{KMnO_4\left(lt\right)}=1,2.158=189,6\left(g\right)\Rightarrow m_{KMnO_4\left(tt\right)}=\dfrac{189,6}{75}.100=252,8\left(g\right)\)
\(n_{Fe}=\dfrac{16,8}{56}=0,3\left(mol\right)\\ n_{O_2}=\dfrac{13,44}{22,4}=0,6\left(mol\right)\\ 3Fe+2O_2\underrightarrow{^{to}}Fe_3O_4\\ Vì:\dfrac{0,6}{2}>\dfrac{0,3}{3}\Rightarrow O_2dư\\ n_{Fe_3O_4\left(LT\right)}=\dfrac{0,3}{3}=0,1\left(mol\right)\\ n_{Fe_3O_4\left(TT\right)}=\dfrac{18,56}{232}=0,08\left(mol\right)\\ H=\dfrac{0,08}{0,1}.100=80\%\)
\(n_{O_2}=\dfrac{0,672}{22,4}=0,03\left(mol\right)\\ n_{KMnO_4}=\dfrac{15,8}{158}=0,1\left(mol\right)\\ 2KMnO_4\underrightarrow{^{to}}K_2MnO_4+MnO_2+O_2\\ n_{O_2\left(LT\right)}=\dfrac{0,1}{2}=0,05\left(mol\right)\\ H=\dfrac{0,03}{0,05}.100=60\%\)
$n_{H_2SO_4} = 0,18(mol) \Rightarrow n_{H^+} = 0,18.2 = 0,36(mol)$
$n_{H_2} = \dfrac{0,336}{22,4} = 0,015(mol)$
$2H^+ + O^{2-} \to H_2O$
$2H^+ + 2e \to H_2$
Ta có :
$n_{H^+} = 2n_O + 2n_{H_2} \Rightarrow n_O = \dfrac{0,36 - 0,015.2}{2} = 0,165(mol)$
$\Rightarrow m = m_X - m_O = 11,04 - 0,165.16 = 8,4(gam)$
\(n_{KClO_3}=\dfrac{24,5}{122,5}=0,2\left(mol\right)\\ 2KClO_3\underrightarrow{^{to}}2KCl+3O_2\\ n_{O_2\left(LT\right)}=\dfrac{3}{2}.0,2=0,3\left(mol\right)\\ Vì:H=90\%\Rightarrow n_{O_2\left(TT\right)}=90\%.0,3=0,27\left(mol\right)\\ V_{O_2\left(đktc,thực.tế\right)}=0,27.22,4=6,048\left(l\right)\)
A tác dụng với NaHCO3 cho khí CO2 → A: axit CH3COOH
BTKL: m + mO2 = mCO2 + mH2O => m = 1,8
=> nCH3COOH = 0,03
CH3COOH + C2H5OH → CH3COOC2H5 + H2O
0,03 0,02 0,0125
=> H = 62,5%
C chứa N2, O2
Gọi \(\left\{{}\begin{matrix}n_{N_2}=x\left(mol\right)\\n_{O_2\left(dư\right)}=y\left(mol\right)\end{matrix}\right.\)
=> \(\overline{M}=\dfrac{28x+32y}{x+y}=15,2.2=30,4\left(g/mol\right)\)
=> 2,4x = 1,6y
=> 1,5x = y (1)
\(n_{H_2O}=\dfrac{9}{18}=0,5\left(mol\right)\)
Gọi số mol CO2 là z (mol)
=> \(x+y+z=\dfrac{14,56}{22,4}=0,65\left(mol\right)\) (2)
Bảo toàn C: nC(A) = z (mol)
Bảo toàn H: nH(A) = 1 (mol)
Bảo toàn N: nN(A) = 2x (mol)
\(n_{O_2\left(pư\right)}=\dfrac{13,44}{22,4}-y=0,6-y\left(mol\right)\)
Bảo toàn O: \(n_{O\left(A\right)}+2n_{O_2\left(pư\right)}=2n_{CO_2}+n_{H_2O}\)
=> \(n_{O\left(A\right)}=2y+2z-0,7\left(mol\right)\)
Do mA = 15 (g)
=> 12z + 1 + 28x + 32y + 32z - 11,2 = 15
=> 28x + 32y + 44z = 25,2 (3)
(1)(2)(3) => \(\left\{{}\begin{matrix}x=0,1\left(mol\right)\\y=0,15\left(mol\right)\\z=0,4\left(mol\right)\end{matrix}\right.\)
nC(A) = 0,4 (mol)
nH(A) = 1 (mol)
nO(A) = 0,4 (mol)
nN(A) = 0,2 (mol)
Xét nC(A) : nH(A) : nO(A) : nN(A) = 0,4 : 1 : 0,4 : 0,2 = 2 : 5 : 2 : 1
Mà A có 1 nguyên tử N
=> CTPT: C2H5O2N
\(CH_4+2O_2\underrightarrow{^{to}}CO_2+2H_2O\\ n_{H_2O}=\dfrac{3,6}{18}=0,2\left(mol\right)\\ n_{CH_4\left(LT\right)}=\dfrac{0,2}{2}=0,1\left(mol\right)\\ n_{CH_4\left(TT\right)}=0,1:\left(100\%-10\%\right)=\dfrac{1}{9}\left(mol\right)\\ V_{CH_4\left(TT\right)}=\dfrac{1}{9}.22,4\approx2,489\left(l\right)\)
\(n_{O_2}=\dfrac{13,44}{22,4}=0,6\left(mol\right)\\ n_P=\dfrac{6,2}{31}=0,2\left(mol\right)\\ 4P+5O_2\underrightarrow{^{to}}2P_2O_5\\ Vì:\dfrac{0,6}{5}>\dfrac{0,2}{1}\\ \Rightarrow O_2dư\\ n_{P_2O_5\left(LT\right)}=\dfrac{2}{4}.0,2=0,1\left(mol\right)\\ n_{P_2O_5\left(TT\right)}=0,1.75\%=0,075\left(mol\right)\\ m_{P_2O_5\left(TT\right)}=142.0,075=10,65\left(g\right)\)
\(n_P=\dfrac{6,2}{31}=0,2\left(mol\right);n_{O_2}=\dfrac{13,44}{22,4}=0,6\left(mol\right)\)
PTHH: 4P + 5O2 ---to→ 2P2O5
Mol: 0,2 0,1
Ta có:\(\dfrac{0,2}{4}< \dfrac{0,6}{5}\) ⇒ P hết, O2 dư
\(m_{P_2O_5\left(lt\right)}=0,1.142=14,2\left(g\right)\Rightarrow m_{P_2O_5\left(tt\right)}=\dfrac{14,2}{75}.100=18,94\left(g\right)\)