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\(n_{CuSO4}=\dfrac{16\%.50}{100\%.160}=0,05\left(mol\right)\)
Pt : \(CuSO_4+2NaOH\rightarrow Cu\left(OH\right)_2+Na_2SO_4\)
0,05-------->0,1---------->0,05--------->0,05
a) \(C\%_{ddNaOH}=\dfrac{0,1.40}{250}.100\%=1,6\%\)
b) \(m_{ddspu}=50+250-0,05.98=295,1\left(g\right)\)
\(C\%_{Na2SO4}=\dfrac{0,05.142}{295,1}.100\%=2,41\%\)
\(n_{CuSO_4}=\dfrac{m_{dd}\cdot C\%}{100\cdot M}=\dfrac{50\cdot16\%}{100\cdot\left(64+32+16\cdot4\right)}=0,05\left(mol\right)\)
\(PTHH:CuSO_4+2NaOH\rightarrow Cu\left(OH\right)_2+Na_2SO_4\)
1 2 1 1
0,05 0,1 0,05 0,05 (mol)
\(a)C\%_{NaOH}=\dfrac{n\cdot100\cdot M}{m_{dd}}=\dfrac{01\cdot100\cdot\left(23+16+1\right)}{250}=1,6\%\)
\(b)m_{dd-sau-pư}=m_{dd_đ}+m_{ct_đ}-m\downarrow-m\uparrow\)
\(=50+250-\left(0,05\cdot23+32+16\cdot4\right)=294,05\left(g\right)\)
\(C\%_{Na_2SO_4}=\dfrac{n\cdot100\cdot M}{m_{dd}}=\dfrac{0,05\cdot100\cdot\left(23\cdot2+32+16\cdot4\right)}{294,05}\approx2,41\%.\)
a.Mg + H2SO4 -> MgSO4 + H2
b.\(nH2=\dfrac{4.704}{22.4}=0.21mol\) = nMg
mMg = 0.21\(\times24=5.04g\)
\(\%mMg=\dfrac{5.04\times100}{25}=20.16\%\)
\(\%mAg=100-20.16=79.84\%\)
c.MgSO4 + 2KOH -> K2SO4 + Mg(OH)2
0.21 0.42
H2SO4 + 2KOH -> K2SO4 + H2O
0.04 0.08
\(nH2SO4=\dfrac{9.8\times250}{100\times98}=0.25mol\)
Mà nH2SO4 phản ứng = nH2 = 0.21 mol
\(\Rightarrow nH2SO4dư=0.25-0.21=0.04mol\)
=> nKOH = 0.42 + 0.08 = 0.5mol
\(\Rightarrow CM_{KOH}=\dfrac{0.5}{0.625}=0.8M\)
a, \(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)
\(n_{H_2}=\dfrac{7,437}{24,79}=0,3\left(mol\right)\)
Theo PT: \(n_{Fe}=n_{H_2}=0,3\left(mol\right)\Rightarrow m_{Fe}=0,3.56=16,8\left(g\right)\)
b, \(n_{H_2SO_4}=n_{H_2}=0,3\left(mol\right)\Rightarrow C\%_{H_2SO_4}=\dfrac{0,3.98}{120}.100\%=24,5\%\)
c, m dd sau pư = 16,8 + 120 - 0,3.2 = 136,2 (g)
d, \(n_{FeSO_4}=n_{H_2}=0,3\left(mol\right)\)
\(\Rightarrow C\%_{FeSO_4}=\dfrac{0,3.152}{136,2}.100\%\approx33,48\%\)
\(a,PTHH:CuCl_2+2KOH\rightarrow Cu\left(OH\right)_2\downarrow+2KCl\\ n_{CuCl_2}=\dfrac{27}{135}=0,2\left(mol\right)\\ \Rightarrow n_{KOH}=2n_{CuCl_2}=0,4\left(mol\right)\\ \Rightarrow C\%_{KOH}=\dfrac{0,4}{0,2}=2M\\ b,PTHH:Cu\left(OH\right)_2\rightarrow^{t^o}CuO+H_2O\\ \Rightarrow n_{CuO}=n_{Cu\left(OH\right)_2}=n_{CuCl_2}=0,2\left(mol\right)\\ \Rightarrow m_{CuO}=0,2\cdot80=16\left(g\right)\)
a) Đặt: nMg=x(mol); nZnO=y(mol)
nH2SO4= 0,2(mol)
PTHH: Mg + H2SO4 -> MgSO4 + H2
x___________x____x_______x(mol)
ZnO + H2SO4 -> ZnSO4 + H2O
y____y______y(mol)
Ta có:
\(\left\{{}\begin{matrix}24x+81y=12,9\\22,4x=4,48\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}x=0,2\\y=0,1\end{matrix}\right.\)
mMg=0,2.24=4,8(g)
%mMg=(4,8/12,9).100=37,209%
=>%mZnO=62,791%
b) nH2SO4=x+y=0,3(mol)
=> \(C\%ddH2SO4=\dfrac{0,3.98}{120}.100=24,5\%\)
\(n_{BaSO_4}=\dfrac{58.25}{233}=0.25\left(mol\right)\)
\(BaCl_2+SO_3+H_2O\rightarrow BaSO_4+2HCl\)
\(0.25........0.25.......................0.25........0.5\)
\(V_{SO_3}=0.25\cdot22.4=5.6\left(l\right)\)
\(m_{dd_{BaCl_2}}=\dfrac{0.25\cdot208}{20\%}=260\left(g\right)\)
\(m_{dd}=m_{SO_3}+m_{dd_{BaCl_2}}-m_{BaSO_4}=0.25\cdot80+260-58.25=221.75\left(g\right)\)
\(C\%_{HCl}=\dfrac{0.5\cdot36.5}{221.75}\cdot100\%=8.2\%\)
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