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C2H2+2Br2->C2H2Br4
0,05-----0,1
n Br2=\(\dfrac{16}{160}\)=0,1 mol
=>VC2H2=0,05.22,4=1,12l
CaC2+2H2O->Ca(OH)2+C2H2
0,05------------------------------0,05
=>m CaC2=0,05.64=3,2g
\(n_{Br_2}=\dfrac{16}{160}=0,1mol\)
\(C_2H_2+2Br_2\rightarrow C_2H_2Br_4\)
0,05 0,1 ( mol )
\(V_{C_2H_2}=0,05.22,4=1,12l\)
\(CaC_2+2H_2O\rightarrow C_2H_2+Ca\left(OH\right)_2\)
0,05 0,05 ( mol )
\(m_{CaC_2}=0,05.64=3,2g\)
\(C_2H_2+2Br_2->C_2H_2Br_4\\ n_{hh}=\dfrac{3,36}{22,4}=0,15mol\\ n_{CH_4}=\dfrac{2,24}{22,4}=0,1mol\\ n_{C_2H_2}=0,05mol\\ n_{Br_2}=2.0,05=0,1mol\\ m_{Br_2}=0,1.160=16g\\ \%V_{CH_4}=\dfrac{0,1}{0,15}.100\%=66,67\%\\ \%V_{C_2H_2}=33,33\%\)
a) \(n_{Br_2}=\dfrac{32}{160}=0,2\left(mol\right)\)
PTHH: C2H2 + 2Br2 --> C2H2Br4
0,1<-----0,2
=> mC2H2 = 0,1.26 =2,6 (g)
\(\%m_{C_2H_2}=\dfrac{2,6}{8}.100\%=32,5\%\)
\(\%m_{CH_4}=\dfrac{8-2,6}{8}.100\%=67,5\%\)
b) \(n_{CH_4}=\dfrac{8-2,6}{16}=0,3375\left(mol\right)\)
PTHH: CH4 + 2O2 --to--> CO2 + 2H2O
0,3375->0,675
2C2H2 + 5O2 --to--> 4CO2 + 2H2O
0,1---->0,25
=> VO2 = (0,675 + 0,25).22,4 = 20,72 (l)
=> Vkk = 20,72.5 = 103,6 (l)
refer
Gọi x, y lần lượt là số mol của C2H4, C2H2 ( x, y > 0 )
nBr2 = 0,2 mol
C2H4 + Br2 → C2H4Br2
x............x...............x
C2H2 + 2Br2 → C2H2Br4
y.............2y..............y
Ta có hệ
{28x+26y=4,1x+2y=0,2{28x+26y=4,1x+2y=0,2
⇒ {x=0,1y=0,05{x=0,1y=0,05
⇒ %C2H4 = 0,1.28.100%4,10,1.28.100%4,1≈≈68,3%
⇒ %C2H2 = 0,05.26.100%4,10,05.26.100%4,1 ≈≈ 31,7%
C2H4 + 3O2 ---to---> 2CO2 + 2H2O
0,1.........0,3
⇒ VO2 = 0,3.22,4 = 6,72 (l)
2C2H2 + 5O2 ---to---> 4CO2 + 2H2O
0,05.......0,125
⇒ VO2 = 0,125.22,4 = 2,8 (l)
⇒ ∑∑VO2 = 6,72 + 2,8 = 9,52 (l)
PT: \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
\(C_2H_2+2Br_2\rightarrow C_2H_2Br_4\)
Gọi: \(\left\{{}\begin{matrix}n_{C_2H_4}=x\left(mol\right)\\n_{C_2H_2}=y\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow x+y=\dfrac{2,24}{22,4}=0,1\left(mol\right)\left(1\right)\)
\(n_{Br_2}=n_{C_2H_4}+2n_{C_2H_2}=x+2y=\dfrac{24}{160}=0,15\left(mol\right)\left(2\right)\)
Từ (1) và (2) \(\Rightarrow x=y=0,05\left(mol\right)\)
\(\Rightarrow\%V_{C_2H_4}=\%V_{C_2H_2}=\dfrac{0,05.22,4}{2,24}.100\%=50\%\)
a, \(n_{Br_2}=\dfrac{32}{160}=0,2\left(mol\right)\)
PT: \(C_2H_2+2Br_2\rightarrow C_2H_2Br_4\)
Theo PT: \(n_{C_2H_2}=\dfrac{1}{2}n_{Br_2}=0,1\left(mol\right)\)
\(\Rightarrow V=V_{CH_4}=4,48-0,1.22,4=2,24\left(l\right)\)
b, \(n_{CH_4}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{CH_4}=\dfrac{0,1.16}{0,1.16+0,1.26}.100\%\approx38,1\%\\\%m_{C_2H_2}\approx61,9\%\end{matrix}\right.\)
a)
$C_2H_2 + 2Br_2 \to C_2H_2Br_4$
b) $n_{Br_2} = \dfrac{40.20\%}{160} = 0,05(mol)$
Theo PTHH : $n_{C_2H_2Br_4} = n_{C_2H_2} = \dfrac{1}{2}n_{Br_2} = 0,025(mol)$
$m_{C_2H_2Br_4} = 0,025.346 = 8,65(gam)$
c) $\%V_{C_2H_2} = \dfrac{0,025}{0,5}.100\% = 5\%$
$\%V_{CH_4} = 100\% - 5\% = 95\%$
\(C_2H_2+2Br_2\rightarrow C_2H_2Br_4\\ V_{CH_4}=4,48\left(l\right)\\ \Rightarrow V_{C_2H_2}=11,2-4,48=6,72\left(mol\right)\\ \Rightarrow\%V=\dfrac{6,72}{11,2}.100=60\%\)
C2H2+2Br2->C2H2Br4
0,05-----0,1
n Br2=\(\dfrac{16}{160}\)=0,1 mol
=>VC2H2=0,05.22,4=1,12l
\(n_{Br_2}=\dfrac{16}{160}=0,1mol\)
\(C_2H_2+2Br_2\rightarrow C_2H_2Br_4\)
0,05 0,1
\(V_{C_2H_2}=0,05\cdot22,4=1,12l\)