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![](https://rs.olm.vn/images/avt/0.png?1311)
PT: \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
\(C_2H_2+2Br_2\rightarrow C_2H_2Br_4\)
Gọi: \(\left\{{}\begin{matrix}n_{C_2H_4}=x\left(mol\right)\\n_{C_2H_2}=y\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow x+y=\dfrac{2,24}{22,4}=0,1\left(mol\right)\left(1\right)\)
\(n_{Br_2}=n_{C_2H_4}+2n_{C_2H_2}=x+2y=\dfrac{24}{160}=0,15\left(mol\right)\left(2\right)\)
Từ (1) và (2) \(\Rightarrow x=y=0,05\left(mol\right)\)
\(\Rightarrow\%V_{C_2H_4}=\%V_{C_2H_2}=\dfrac{0,05.22,4}{2,24}.100\%=50\%\)
![](https://rs.olm.vn/images/avt/0.png?1311)
n Br2=\(\dfrac{32}{160}\)=0,2 mol
C2H2+2Br2->C2H2Br4
0,1------0,2 mol
=>%VC2H2=\(\dfrac{0,1.22,4}{5,6}\).100=40%
=>%VCH4=100-40=60%
=>n CH4=\(\dfrac{5,6-0,1.22,4}{22,4}\)=0,15 mol
CH4+2O2-to>CO2+2H2O
0,15----0,3
C2H2+\(\dfrac{5}{2}\)O2-to>2CO2+H2O
0,1-----0,25 mol
=>VO2=(0,3+0,25).22,4=12,32l
![](https://rs.olm.vn/images/avt/0.png?1311)
\(n_{hh}=\dfrac{3,36}{22,4}=0,15mol\)
\(n_{Br_2}=\dfrac{2,4}{160}=0,015mol\)
\(C_2H_2+2Br_2\rightarrow C_2H_2Br_4\)
0,0075 0,015 ( mol )
\(V_{C_2H_2}=0,0075.22,4=0,168l\)
\(V_{CH_4}=3,36-0,168=3,192l\)
\(\%V_{C_2H_2}=\dfrac{0,168}{3,36}.100=5\%\)
\(\%V_{CH_4}=100\%-5\%=95\%\)
![](https://rs.olm.vn/images/avt/0.png?1311)
\(n_{hh}=\dfrac{6,72}{22,4}=0,3mol\)
\(n_{C_2H_4Br_2}=\dfrac{16}{188}=\dfrac{4}{47}mol\)
\(\Rightarrow n_{etilen}=\dfrac{4}{47}mol\)
\(\Rightarrow n_{metan}=0,3-\dfrac{4}{47}=\dfrac{101}{470}mol\)
\(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
\(\%V_{etilen}=\dfrac{\dfrac{4}{47}}{0,3}\cdot100\%=28,37\%\)
\(\%V_{metan}=100\%-28,37\%=71,63\%\)
![](https://rs.olm.vn/images/avt/0.png?1311)
a) \(n_{Br_2}=\dfrac{32}{160}=0,2\left(mol\right)\)
PTHH: C2H2 + 2Br2 --> C2H2Br4
0,1<-----0,2
=> mC2H2 = 0,1.26 =2,6 (g)
\(\%m_{C_2H_2}=\dfrac{2,6}{8}.100\%=32,5\%\)
\(\%m_{CH_4}=\dfrac{8-2,6}{8}.100\%=67,5\%\)
b) \(n_{CH_4}=\dfrac{8-2,6}{16}=0,3375\left(mol\right)\)
PTHH: CH4 + 2O2 --to--> CO2 + 2H2O
0,3375->0,675
2C2H2 + 5O2 --to--> 4CO2 + 2H2O
0,1---->0,25
=> VO2 = (0,675 + 0,25).22,4 = 20,72 (l)
=> Vkk = 20,72.5 = 103,6 (l)
refer
Gọi x, y lần lượt là số mol của C2H4, C2H2 ( x, y > 0 )
nBr2 = 0,2 mol
C2H4 + Br2 → C2H4Br2
x............x...............x
C2H2 + 2Br2 → C2H2Br4
y.............2y..............y
Ta có hệ
{28x+26y=4,1x+2y=0,2{28x+26y=4,1x+2y=0,2
⇒ {x=0,1y=0,05{x=0,1y=0,05
⇒ %C2H4 = 0,1.28.100%4,10,1.28.100%4,1≈≈68,3%
⇒ %C2H2 = 0,05.26.100%4,10,05.26.100%4,1 ≈≈ 31,7%
C2H4 + 3O2 ---to---> 2CO2 + 2H2O
0,1.........0,3
⇒ VO2 = 0,3.22,4 = 6,72 (l)
2C2H2 + 5O2 ---to---> 4CO2 + 2H2O
0,05.......0,125
⇒ VO2 = 0,125.22,4 = 2,8 (l)
⇒ ∑∑VO2 = 6,72 + 2,8 = 9,52 (l)
![](https://rs.olm.vn/images/avt/0.png?1311)
Tính % thể tích các khí :
% V C 2 H 2 = 0,448/0,896 x 100% = 50%
% V CH 4 = % V C 2 H 6 = 25%
![](https://rs.olm.vn/images/avt/0.png?1311)
\(a) C_2H_4 + Br_2 \to C_2H_4Br_2\\ n_{C_2H_4} = n_{Br_2} = \dfrac{48}{160} = 0,3(mol)\\ \%V_{C_2H_4} = \dfrac{0,3.22,4}{8,96}.100\% = 75\%\\ \%V_{CH_4} = 100\% -75\% = 25\%\\ b)\)
Khí còn lại : CH4
\(CH_4 + 2O_2 \xrightarrow{t^o} CO_2 + H_2O\\ n_{CO_2} = n_{CH_4} = \dfrac{8,96.25\%}{22,4} = 0,1(mol)\\ m_{CO_2} = 0,1.44 = 4,4(gam)\)
Đáp án A