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Theo bài ra, ta có: \(m_{Ag}=5,6\left(g\right)\)
PTHH: \(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\uparrow\)
a) Ta có: \(n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\) \(\Rightarrow n_{Al}=\dfrac{1}{15}\left(mol\right)\) \(\Rightarrow m_{Al}=\dfrac{1}{15}\cdot27=1,8\left(g\right)\)
\(\Rightarrow\%m_{Al}=\dfrac{1,8}{1,8+5,6}\cdot100\%\approx24,32\%\) \(\Rightarrow\%m_{Ag}=75,68\%\)
b) Theo PTHH: \(n_{H_2SO_4}=n_{H_2}=0,1mol\) \(\Rightarrow C_{M_{H_2SO_4}}=\dfrac{0,1}{0,1}=1\left(M\right)\)
c) PTHH: \(H_2SO_4+Ba\left(OH\right)_2\rightarrow BaSO_4\downarrow+2H_2O\)
Theo PTHH: \(n_{Ba\left(OH\right)_2}=n_{H_2SO_4}=0,1mol\)
\(\Rightarrow V_{ddBa\left(OH\right)_2}=\dfrac{0,1}{0,2}=0,5\left(l\right)=500\left(ml\right)\)
\(a)Fe+H_2SO_4\rightarrow FeSO_4+H_2\\ Fe_2O_3+3H_2SO_4\rightarrow Fe_2\left(SO_4\right)_3+3H_2O\\ b)n_{H_2}=\dfrac{2,24}{22,4}=0,1mol\\ n_{Fe}=n_{H_2}=0,1mol\\ m_{Fe}=0,1.56=5,6g\\ m_{Fe_2O_3}=21,6-5,6=16g\\ c)n_{Fe_2O_3}=\dfrac{16}{160}=0,1mol\\ n_{H_2SO_4}=0,1+0,1.3=0,4mol\\ C_{M_{H_2SO_4}}=\dfrac{0,4}{0,5}=0,8M\)
\(n_{H_2}=\dfrac{2,24}{22,4}=0,1(mol)\\ a,Zn+H_2SO_4\to ZnSO_4+H_2\\ b,n_{Zn}=0,1(mol)\Rightarrow m_{Zn}=0,1.65=6,5(g)\\ \Rightarrow \%_{Zn}=\dfrac{6,5}{10,5}.100\%=61,9\%\\ \Rightarrow \%_{Cu}=100\%-61,9\%=38,1\%\\ c,n_{H_2SO_4}=0,1(mol)\Rightarrow C_{M_{H_2SO_4}}=\dfrac{0,1}{0,5}=0,2M\)
0.1 0.1
nH2= 2.24: 22.4=0.1 mol
mZn= 0.1x65=6.5 g
mCu=10.5-6,5=4 g
%Zn=6.5:10.5x100%=61.9%
%Cu=4:10.5x100%=38.1%
Chất rắn không tan : Cu
\(m_{Cu}=3.2\left(g\right)\)
\(n_{H_2}=\dfrac{4.48}{22.4}=0.2\left(mol\right)\)
\(Zn+H_2SO_4\rightarrow ZnSO_4+H_2\)
\(0.2......0.2...........................0.2\)
\(m_{hh}=m_{Cu}+m_{Zn}=3.2+0.2\cdot65=16.2\left(g\right)\)
\(m_{H_2SO_4}=0.2\cdot98=19.6\left(g\right)\)
\(b=m_{dd_{H_2SO_4}}=\dfrac{19.6}{20\%}=98\left(g\right)\)
a) Đặt: nZn=x(mol); nFe= y(mol) (x,y: nguyên, dương)
Zn + H2SO4 -> ZnSO4 + H2
x_______x_______x________x
Fe + H2SO4 -> FeSO4 + H2
y____y_________y___y(mol)
b) m(rắn)=mCu=3(g)
=> m(Zn, Fe)= 21,6 - 3= 18,6(g)
Ta có hpt:
\(\left\{{}\begin{matrix}65x+56y=18,6\\22,4x+22,4y=6,72\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}x=0,2\\y=0,1\end{matrix}\right.\)
=> Zn= 65.0,2=13(g)
=>%mZn= (13/21,6).100=60,185%
%mCu=(3/21,6).100=13,889%
=>%mFe=25,926%
c) nH2SO4=x+y=0,3(mol) =>mH2SO4=29,4(g)
=> mddH2SO4= (29,4.100)/25=117,6(g)
\(n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
PTHH:
\(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)
0,2 0,2 0,2 0,2
\(a,\%m_{Fe}=\dfrac{0,2.56}{20}.100\%=56\%\)
\(\%m_{Cu}=100\%-56\%=44\%\)
\(b,C_{M\left(H_2SO_4\right)}=\dfrac{0,2}{0,1}=2\left(M\right)\)
\(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)
\(1\) \(1\) \(1\)
\(0,2\) \(0,2\) \(0,2\)
\(n_{H_2}=\dfrac{V}{22,4}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
\(m_{Fe}=n.M=0,2.56=11,2\left(g\right)\)
\(^0/_0Fe=\dfrac{11,2}{20}.100^0/_0=56^0/_0\)
\(^0/_0Cu=100^0/_0-56^0/_0=44^0/_0\)
\(C_{M_{H_2SO_4}}=\dfrac{n}{V_{dd}}=\dfrac{0,2}{0,1}=2M\)
a) PTHH: \(Zn+H_2SO_4\rightarrow ZnSO_4+H_2\)
b) Ta có: \(n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)=n_{Zn}\) \(\Rightarrow\left\{{}\begin{matrix}\%m_{Zn}=\dfrac{0,1\cdot65}{6,5+2,16}\cdot100\%\approx75,06\%\\\%m_{Ag}=24,94\%\end{matrix}\right.\)
c) Theo PTHH: \(n_{H_2SO_4}=n_{Zn}=0,1\left(mol\right)\) \(\Rightarrow C_{M_{H_2SO_4}}=\dfrac{0,1}{0,5}=0,2\left(M\right)\)
d) PTHH: \(2Ag+2H_2SO_{4\left(đ\right)}\xrightarrow[]{t^o}Ag_2SO_4+SO_2\uparrow+2H_2O\)
Ta có: \(n_{SO_2}=\dfrac{1}{2}n_{Ag}=\dfrac{1}{2}\cdot\dfrac{2,16}{108}=0,01\left(mol\right)\) \(\Rightarrow V_{SO_2}=0,01\cdot22,4=0,224\left(l\right)\)