Hãy nhập câu hỏi của bạn vào đây, nếu là tài khoản VIP, bạn sẽ được ưu tiên trả lời.
![](https://rs.olm.vn/images/avt/0.png?1311)
Gọi \(\left\{{}\begin{matrix}n_{Mg}=x\left(mol\right)\\n_{Al}=y\left(mol\right)\end{matrix}\right.\)
\(n_{BaSO_4}=\dfrac{11,65}{233}=0,05\left(mol\right)\)
\(Mg+CuSO_4\rightarrow MgSO_4+Cu\)
x------>x--------->x------------>x
\(2Al+3CuSO_4\rightarrow Al_2\left(SO_4\right)_3+3Cu\)
y------>1,5y-------->0,5y-------->1,5y
Có hệ \(\left\{{}\begin{matrix}24x+27y=0,78\\x+1,5y=\dfrac{2,56}{64}\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}x=0,01\\y=0,02\end{matrix}\right.\)
Giả sử \(CuSO_4\) phản ứng hết, dung dịch C có: \(\left\{{}\begin{matrix}n_{MgSO_4}=x=0,01\left(mol\right)\\n_{Al_2\left(SO_4\right)_3}=0,5y=0,5.0,02=0,01\left(mol\right)\end{matrix}\right.\)
\(MgSO_4+BaCl_2\rightarrow MgCl_2+BaSO_4\) (1)
0,01-------------------------------->0,01
\(Al_2\left(SO_4\right)_3+3BaCl_2\rightarrow3BaSO_4+2AlCl_3\) (2)
0,01------------------------>0,03
Từ PTHH (1), (2) có: \(\Sigma n_{BaSO_4}=0,01+0,03=0,04\left(mol\right)< 0,05\left(mol\right)_{theo.đề}\)
=> Giả sử sai, \(CuSO_4\) dư
\(CuSO_4+BaCl_2\rightarrow BaSO_4+CuCl_2\)
0,01<-----------------0,01
\(CM_{CuSO_4}=a=\dfrac{x+1,5y+0,01}{0,2}=\dfrac{0,01+1,5.0,02+0,01}{0,2}=0,25\left(M\right)\)
Trong A:
\(n_{Al}=0,02\left(mol\right)\\ n_{Mg}=0,01\left(mol\right)\)
![](https://rs.olm.vn/images/avt/0.png?1311)
Gọi \(n_{Fe_3O_4}=a\left(mol\right)\rightarrow n_{Cu}=3a\left(mol\right)\)
\(232a+64.3a=21,2\\ \Leftrightarrow a=0,05\left(mol\right)\)
\(m_{HCl}=125.14,6\%=18,25\left(g\right)\)
PTHH:
Fe3O4 + 8HCl ---> FeCl2 + 2FeCl3 + 4H2O
0,05------>0,4------->0,05---->0,1
\(m_X=0,05.3.64=9,6\left(g\right)\)
\(m_{dd}=232.0,05+125=136,6\left(g\right)\\ \rightarrow\left\{{}\begin{matrix}C\%_{FeCl_2}=\dfrac{0,05.127}{136,6}.100\%=4,65\%\\C\%_{FeCl_3}=\dfrac{0,1.162,5}{136,6}.100\%=11,9\%\\C\%_{HCl\left(dư\right)}=\dfrac{18,25-0,4.36,5}{136,6}=2,67\%\end{matrix}\right.\)