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\(n_{NaOH}=\dfrac{200.15\%}{40}=0,75\left(mol\right)\)
\(\left\{{}\begin{matrix}n_{H_2SO_4}=0,0001V\left(mol\right)\\n_{Fe_2\left(SO_4\right)_3}=0,00005V\left(mol\right)\end{matrix}\right.\)
PTHH: 2NaOH + H2SO4 --> Na2SO4 + 2H2O
0,0002V<-0,0001V
6NaOH + Fe2(SO4)3 --> 3Na2SO4 + 2Fe(OH)3
0,0003V<-0,00005V---------------->0,0001V
=> 0,0002V + 0,0003V = 0,75
=> V = 1500 (ml)
nFe(OH)3 = 0,15 (mol)
=> m1 = 0,15.107 = 16,05 (g)
PTHH: 2Fe(OH)3 --to--> Fe2O3 + 3H2O
0,15--------->0,075
=> mFe2O3 = 0,075.160 = 12 (g)
nH2SO4=0,2.0,5=0,1(mol)
nMgSO4=0,3.0,5=0,15(mol)
nMgO=\(\dfrac{4}{40}=0,1mol\)
PTHH: 2NaOH + H2SO4 --> Na2SO4 + 2H2O
0,2<-----0,1
2NaOH + MgSO4 --> Mg(OH)2 + Na2SO4
0,2<------------------0,1
Mg(OH)2 --to--> MgO + H2O
0,1<------------0,1
=> nNaOH = 0,2 + 0,2 = 0,4 (mol)
=> mNaOH = 0,4.40 = 16 (g)
=> m1=\(\dfrac{16.100}{10}=160g\)
m2 = 0,1.58 = 5,8 (g)
a)
$Fe_2(SO_4)_3 + 6KOH \to 2Fe(OH)_3 + 3K_2SO_4$
b)
$n_{Fe_2(SO_4)_3} = 0,3.1 = 0,3(mol)$
$n_{KOH} = \dfrac{16,8}{56} =0,3(mol)$
Ta thấy :
$n_{KOH} : 3 < n_{Fe_2(SO_4)_3} : 1$ nên $Fe_2(SO_4)_3$ dư
$n_{Fe(OH)_3} = \dfrac{1}{3}n_{KOH} = 0,1(mol)$
$n_{Fe_2O_3} = \dfrac{1}{2}n_{Fe(OH)_3} = 0,05(mol)$
$m_{Fe_2O_3} = 0,05.160 = 8(gam)$
\(3NaOH+FeCl_3\rightarrow Fe\left(OH\right)_3+3NaCl\)
\(n_{NaCl}=n_{NaOH}=0,2.3=0,6\left(mol\right)\)
=> \(C_{M\left(NaCl\right)}=\dfrac{0,6}{0,2}=3M\)
\(n_{Fe\left(ỌH\right)_3}=\dfrac{1}{3}n_{NaOH}=0,2\left(mol\right)\)
\(2Fe\left(OH\right)_3-^{t^o}\rightarrow Fe_2O_3+3H_2O\)
Ta có \(n_{Fe_2O_3}=\dfrac{1}{2}n_{Fe\left(OH\right)_3}=0,1\left(mol\right)\)
=> m Fe2O3 = 0,1 . 160=16(g)
\(\left\{{}\begin{matrix}n_{H_2SO_4}=0,2.0,5=0,1\left(mol\right)\\n_{MgSO_4}=0,3.0,5=0,15\left(mol\right)\end{matrix}\right.\)
\(n_{MgO}=\dfrac{4}{40}=0,1\left(mol\right)\)
PTHH: 2NaOH + H2SO4 --> Na2SO4 + 2H2O
0,2<-----0,1
2NaOH + MgSO4 --> Mg(OH)2 + Na2SO4
0,2<------------------0,1
Mg(OH)2 --to--> MgO + H2O
0,1<------------0,1
=> nNaOH = 0,2 + 0,2 = 0,4 (mol)
=> mNaOH = 0,4.40 = 16 (g)
=> \(m_1=\dfrac{16.100}{10}=160\left(g\right)\)
m2 = 0,1.58 = 5,8 (g)
\(n_{CuCl_2}=0,1.0,3=0,03mol\)
PTHH: \(CuCl_2+2KOH\rightarrow2KCl+Cu\left(OH\right)_2\)
\(Cu\left(OH\right)_2\rightarrow^{t^o}CuO+H_2O\)
\(m_{CuO}=0,03.80=2,4g\)
\(a,PTHH:3NaOH+FeCl_3\rightarrow3NaCl+Fe\left(OH\right)_3\downarrow\\ 2Fe\left(OH\right)_3\rightarrow^{t^o}Fe_2O_3+3H_2O\uparrow\\ b,n_{FeCl_3}=1,5\cdot0,2=0,3\left(mol\right)\\ \Rightarrow n_{NaOH}=3n_{FeCl_3}=0,9\left(mol\right)\\ \Rightarrow V_{dd_{NaOH}}=\dfrac{0,9}{2}=0,45\left(l\right)\)
Theo đề: \(\left\{{}\begin{matrix}X:Fe\left(OH\right)_3\\A:NaCl\\Y:Fe_2O_3\end{matrix}\right.\)
Theo PT: \(n_{NaCl}=3n_{FeCl_3}=0,9\left(mol\right)\)
\(\Rightarrow C_{M_{NaCl}}=\dfrac{0,9}{0,45+0,2}\approx1,4M\)
\(c,\) Theo PT: \(n_{Fe\left(OH\right)_3}=n_{FeCl_3}=0,3\left(mol\right);n_{Fe_2O_3}=\dfrac{1}{2}n_{Fe\left(OH\right)_3}=0,15\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}m_X=m_{Fe\left(OH\right)_3}=0,3\cdot107=32,1\left(g\right)\\m_Y=m_{Fe_2O_3}=0,15\cdot160=24\left(g\right)\end{matrix}\right.\)
CuSO4 + 2NaOH -> Cu(OH)2 + Na2SO4 (1)
Cu(OH)2 -> CuO + H2O (2)
nNaOH=0,5(mol)
Theo PTHH 1 ta có:
nCu(OH)2=\(\dfrac{1}{2}\)nNaOH=0,25(mol)
mCu(OH)2=98.0,25=24,5(g)
Theo PTHH 2 ta có:
nCuO=nCu(OH)2=0,25(mol)
mCuO=80.0,25=20(g)