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\(\left\{{}\begin{matrix}n_{Fe}=a\left(mol\right)\\n_{Cu}=b\left(mol\right)\\n_{Fe_2O_3}=c\left(mol\right)\\n_{CuO}=d\left(mol\right)\end{matrix}\right.\)⇒ 56a + 64b + 160c + 80d = 12,4(1)
BT e : \(2n_{SO_2} = 3n_{Fe} + 2n_{Cu}\)
⇒ 3a + 2b = \(2. \dfrac{2,8}{22,4} = 0,25\) ⇔ 8(3a + 2b) = 0,25.8 ⇔ 24a + 16b = 2(2)
Lấy (1) + (2),ta có :
80a + 80b + 160c + 80d = 12,4 + 2 = 14,4
Bảo toàn nguyên tố với Fe,Cu
2Fe → Fe2O3
a..............0,5a.........(mol)
Cu → CuO
b............b...............(mol)
Fe2O3 → Fe2O3
c....................c...............(mol)
CuO → CuO
d...................d................(mol)
Vậy :
\(m_Z = m_{Fe_2O_3} + m_{CuO} = 160(0,5a + c) + 80(b+d)\\ = 80a + 80b + 160c + 80d \\= 14,4(gam)\)
Bài 4 :
\(m_{ct}=\dfrac{19.120}{100}=22,8\left(g\right)\)
\(n_{MgCl2}=\dfrac{22,8}{95}=0,24\left(mol\right)\)
Pt : \(MgCl_2+Ba\left(OH\right)_2\rightarrow Mg\left(OH\right)_2+BaCl_2|\)
1 1 1 1
0,24 0,24
Pt : \(Mg\left(OH\right)_2\underrightarrow{t^o}MgO+H_2O|\)
1 1 1
0,24 0,24
\(n_{MgO}=\dfrac{0,24.1}{1}=0,24\left(mol\right)\)
⇒ \(m_{MgO}=0,24.40=9,6\left(g\right)\)
Chúc bạn học tốt
BTKL
mX + mdd HNO3 = mdd X + mH2O + m↑
=> mdd X = 11,6 + 87,5 – 30 . 0,1 – 46 . 0,15 = 89,2g
=> C%Fe(NO3)3 = 13,565%
a) mNaOH= 200.20%= 40(g)
=>nNaOH=1(mol)
PTHH: 2 NaOH + CuCl2 -> 2 NaCl + Cu(OH)2
Dung dịch sau khi lọc kết tủa có NaCl.
nNaCl=nNaOH= 1(mol)
nCuCl2=nCu(OH)2=nNaOH/2=1/2=0,5(mol)
mNaCl=1.58,5=58,5(g)
mCuCl2=0,5.135=67,5(g)
=> mddCuCl2=(67,5.100)/10=675(g)
mCu(OH)2=0,5.98=49(g)
=>mddNaCl=mddNaOH+ mddCuCl2 - mCu(OH)2= 200+675 - 98=777(g)
=> \(C\%ddNaCl=\dfrac{58,5}{777}.100\approx7,529\%\)
b) PTHH: Cu(OH)2 -to-> CuO + H2O
0,5__________________0,5(mol)
m(rắn)=mCuO=0,5.80=4(g)
\(a.CuSO_4+2NaOH\rightarrow Cu\left(OH\right)_2+Na_2SO_4\\ Cu\left(OH\right)_2-^{t^o}\rightarrow CuO+H_2O\\b. n_{CuSO_4}=n_{Na_2SO_4}=0,2\left(mol\right)\\ m_{Na_2SO_4}=0,2.142=28,4\left(g\right)\\ c.BTNT\left(Cu\right):n_{CuO}=n_{CuSO_4}=0,2\left(mol\right)\\ \Rightarrow m_{CuO}=0,2.80=16\left(g\right)\)
\(a)n_K=\dfrac{7,8}{39}=0,2mol\\ 2K+2H_2O\rightarrow2KOH+H_2\\ n_{H_2}=2n_K=0,4mol\\ V_{H_2\left(đktc\right)}=0,4.22,4=8,96l\\ V_{H_2\left(đkc\right)}=0,4.24,79=9,916g\\ b)n_{KOH}=n_K=0,2mol\\ 2KOH+Cu\left(NO_3\right)_2\rightarrow2KNO_3+Cu\left(OH\right)_2\\ n_{Cu\left(OH\right)_2}=\dfrac{1}{2}n_{KOH}=0,1mol\\ m_{\downarrow}=m_{Cu\left(OH\right)_2}=0,1.98=9,8g\\ c)Cu\left(OH\right)_2\xrightarrow[]{t^0}CuO+H_2O\\ n_{CuO}=n_{Cu\left(OH\right)_2}=0,1mol\\ m_{CuO}=0,1.80=8g\)