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a, \(n_{H_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
\(n_{Fe}=n_{H_2}=0,15\left(mol\right)\Rightarrow m_{Fe}=0,15.56=8,4\left(g\right)\)
b, \(n_{Na_2O}=\dfrac{6,2}{62}=0,1\left(mol\right)\)
\(Na_2O+H_2O\rightarrow2NaOH\)
\(n_{NaOH}=2n_{Na_2O}=0,2\left(mol\right)\Rightarrow C_{M_{NaOH}}=\dfrac{0,2}{0,5}=0,4\left(M\right)\)
\(a,n_{H_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)
PTHH:
\(Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\)
0,15 0,3 0,15 0,15
\(m_{Fe}=0,15.56=8,4\left(g\right)\)
\(a,n_{Na_2O}=\dfrac{6,2}{62}=0,1\left(mol\right)\)
PTHH :
\(Na_2O+H_2O\rightarrow2NaOH\)
0,1 0,1 0,2
\(C_{M\left(A\right)}=\dfrac{0,2}{0,5}=0,4\left(M\right)\)
Ta có: \(n_{Mg}=\dfrac{4,8}{24}=0,2\left(mol\right)\)
PT: \(Mg+2HCl\rightarrow MgCl_2+H_2\)
a, \(n_{H_2}=n_{Mg}=0,2\left(mol\right)\)
\(\Rightarrow V_{H_2}=0,2.22,4=4,48\left(l\right)\)
b, \(n_{HCl}=2n_{H_2}=0,4\left(mol\right)\)
\(\Rightarrow C_{M_{HCl}}=\dfrac{0,4}{0,2}=2\left(M\right)\)
c, PT: \(HCl+KOH\rightarrow KCl+H_2O\)
Theo PT: \(n_{KOH}=n_{HCl}=0,4\left(mol\right)\)
\(\Rightarrow m_{ddKOH}=\dfrac{0,4.56}{5,6\%}=400\left(g\right)\)
\(\Rightarrow V_{ddKOH}=\dfrac{400}{1,045}\approx382,78\left(ml\right)\)
a, \(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)
\(n_{H_2}=\dfrac{7,437}{24,79}=0,3\left(mol\right)\)
Theo PT: \(n_{Fe}=n_{H_2}=0,3\left(mol\right)\Rightarrow m_{Fe}=0,3.56=16,8\left(g\right)\)
b, \(n_{H_2SO_4}=n_{H_2}=0,3\left(mol\right)\Rightarrow C\%_{H_2SO_4}=\dfrac{0,3.98}{120}.100\%=24,5\%\)
c, m dd sau pư = 16,8 + 120 - 0,3.2 = 136,2 (g)
d, \(n_{FeSO_4}=n_{H_2}=0,3\left(mol\right)\)
\(\Rightarrow C\%_{FeSO_4}=\dfrac{0,3.152}{136,2}.100\%\approx33,48\%\)
a, \(n_{Zn}=\dfrac{19,5}{65}=0,3\left(mol\right)\)
\(m_{HCl}=200.14,6\%=29,2\left(g\right)\Rightarrow n_{HCl}=\dfrac{29,2}{36,5}=0,8\left(mol\right)\)
PT: \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
Xét tỉ lệ: \(\dfrac{0,3}{1}< \dfrac{0,8}{2}\), ta được HCl dư.
Theo PT: \(n_{H_2}=n_{Zn}=0,3\left(mol\right)\Rightarrow V_{H_2}=0,3.22,4=6,72\left(l\right)\)
b, \(n_{ZnCl_2}=n_{Zn}=0,3\left(mol\right)\Rightarrow m_{ZnCl_2}=0,3.136=40,8\left(g\right)\)
c, \(n_{HCl\left(pư\right)}=2n_{Zn}=0,6\left(mol\right)\Rightarrow n_{HCl\left(dư\right)}=0,2\left(mol\right)\)
Ta có: m dd sau pư = 19,5 + 200 - 0,3.2 = 218,9 (g)
\(\Rightarrow\left\{{}\begin{matrix}C\%_{HCl}=\dfrac{0,2.36,5}{218,9}.100\%\approx3,33\%\\C\%_{ZnCl_2}=\dfrac{40,8}{218,9}.100\%\approx18,64\%\end{matrix}\right.\)
\(a)n_{Zn}=\dfrac{19,5}{65}=0,3mol\\ n_{HCl}=\dfrac{200.14,6}{100.36,5}=0,8mol\\ Zn+2HCl\rightarrow ZnCl_2+H_2\\ \Rightarrow\dfrac{0,3}{1}< \dfrac{0,8}{2}\Rightarrow HCl.dư\\ n_{H_2}=n_{ZnCl_2}=n_{Zn}=0,3mol\\ V_{H_2}=0,3.22,4=6,72l\\ b)m_{ZnCl_2}=0,3.136=40,8g\\ c)n_{HCl.pư}=0,3.2=0,6mol\\ C_{\%ZnCl_2}=\dfrac{40,8}{200+19,5-0,3.2}\cdot100=18,64\%\\ C_{\%HCl.dư}=\dfrac{\left(0,8-0,6\right).36,5}{200+19,5-0,3.2}\cdot100=3,33\%\)
\(n_{Na_2CO_3}=\dfrac{360.21,2\%}{100\%.106}=0,72(mol)\\ n_{H_2SO_4}=2,5.0,2=0,5(mol)\\ PTHH:Na_2CO_3+H_2SO_4\to Na_2SO_4+H_2O+CO_2\uparrow\\ a,\text {Vì }\dfrac{n_{Na_2CO_3}}{1}>\dfrac{n_{H_2SO_4}}{1} \text {nên }Na_2CO_3\text { dư}\\ \Rightarrow n_{CO_2}=n_{H_2SO_4}=0,5(mol)\\ \Rightarrow V_{CO_2}=0,5.22,4=11,2(l)\\\)
\(b,A:Na_2SO_4\\ n_{Na_2SO_4}=n_{H_2SO_4}=0,5(mol)\\ m_{dd_{H_2SO_4}}=200.1,1=220(g);V_{dd_{Na_2CO_3}}=\dfrac{360}{1,2}=300(ml)=0,3(l)\\ \Rightarrow C\%_{Na_2SO_4}=\dfrac{0,5.142}{360+200-0,5.44}.100\%=13,2\%\\ C_{M_{Na_2SO_4}}=\dfrac{0,5}{0,3+0,2}=1M\)
a, \(2Al+6HCl\rightarrow2AlCl_3+3H_2\)
\(n_{H_2}=\dfrac{14,874}{24,79}=0,6\left(mol\right)\)
Theo PT: \(n_{Al}=\dfrac{2}{3}n_{H_2}=0,4\left(mol\right)\Rightarrow m_{Al}=0,4.27=10,8\left(g\right)\)
b, \(n_{HCl}=2n_{H_2}=1,2\left(mol\right)\Rightarrow C\%_{HCl}=\dfrac{1,2.36,5}{250}.100\%=17,52\%\)
c, m dd sau pư = 10,8 + 250 - 0,6.2 = 259,6 (g)
d, \(n_{AlCl_3}=\dfrac{2}{3}n_{H_2}=0,4\left(mol\right)\)
\(\Rightarrow C\%_{AlCl_3}=\dfrac{0,4.133,5}{259,6}.100\%\approx20,57\%\)
