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\(n_{Al} = a\ ; n_{Fe} =b\\ \Rightarrow 27a + 56b = 11(1)\\ 2Al + 6HCl \to 2AlCl_3 + 3H_2\\ Fe + 2HCl \to FeCl_2 + H_2\\ n_{H_2} = 1,5a + b = \dfrac{8,96}{22,4} = 0,4(2)\\ (1)(2) \Rightarrow a = 0,2 ; b = 0,1\\ n_{HCl\ dư} = \dfrac{200.21,9\%}{36,5} - 0,2.3 - 0,1.2 = 0,4(mol)\\ m_{dd\ sau\ pư} = 11 + 200 - 0,4.2 = 210,2(gam)\\ C\%_{HCl} = \dfrac{0,4.36,5}{210,2}.100\% = 6,95\%\\ \)
\(C\%_{AlCl_3} = \dfrac{0,2.133,5}{210,2}.100\% = 12,7\%\\ C\%_{FeCl_2} = \dfrac{0,1.127}{210,2}.100\% = 6,04\%\)
\(n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right)\\ n_{H_2SO_4}=0,5.0,1=0,05\left(mol\right)\\ pthh:2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)
\(LTL:\dfrac{0,2}{2}>\dfrac{0,05}{3}\)
=> Al dư
\(n_{H_2}=n_{H_2SO_4}=0,05\left(mol\right)\)
\(V_{H_2}=0,05.22,4=1,12l\\
C_M=\dfrac{\dfrac{1}{60}}{0,1}=0,16M\)
Ta có: \(n_{SO_2}=\dfrac{16,8}{22,4}=0,75\left(mol\right)\)
\(m_{H_2SO_4}=300.78,4\%=235,2\left(g\right)\Rightarrow n_{H_2SO_4}=\dfrac{235,2}{98}=2,4\left(mol\right)\)
PT: \(2Fe+6H_2SO_{4\left(đ\right)}\underrightarrow{t^o}Fe_2\left(SO_4\right)_3+3SO_2+6H_2O\)
____0,5____1,5________0,25______0,75 (mol)
\(\Rightarrow n_{H_2SO_4\left(dư\right)}=2,4-1,5=0,9\left(mol\right)\)
Ta có: m dd sau pư = mFe + m dd H2SO4 - mSO2
= 0,5.56 + 300 - 0,75.64 = 280 (g)
\(\Rightarrow\left\{{}\begin{matrix}C\%_{H_2SO_4\left(dư\right)}=\dfrac{0,9.98}{280}.100\%=31,5\%\\C\%_{Fe_2\left(SO_4\right)_3}=\dfrac{0,25.400}{280}.100\%\approx35,7\%\end{matrix}\right.\)
Bạn tham khảo nhé!
\(a.2Al+3H_2SO_4->Al_2\left(SO_4\right)_3+3H_2\\ n_{H_2SO_4}=\dfrac{100.29,4}{98.100}=0,3mol\\ m_{Al}=\dfrac{2}{3}.27.0,3=5,4g=m\\ V_{H_2}=22,4.0,3=6,72L\\ m_{ddsau}=m+100-0,3.2=104,8g\\b. C\%=\dfrac{342.0,1}{104,8}.100\%=32,63\%\)
a)
PTHH: 2Al+3H\(_2\)SO\(_4\) → Al\(_2\)(SO4)\(_3\)+3H\(_2\)
n\(_{H_2SO_4}\) = \(\dfrac{100.29,4\%}{98}\) = 0,3 (mol)
Theo PT: n\(_{H_2}\)= n\(_{H_2SO_4}\)= 0,3 (mol)
\(\Rightarrow\)V\(_{H_2}\)= 0,3.22,4 = 6,72(l)
Theo PT: n\(_{Al}\) = \(\dfrac{2}{3}\)n\(_{H_2}\) = 0,2 (mol)
\(\Rightarrow\)m=m\(_{Al}\) = 0,2.27 = 5,4 (g)
b)
m\(_{dd}\) = 5,4+100−0,3.2 = 104,8 (g)
Theo PT: n\(_{Al_2\left(SO_4\right)_3}\) = \(\dfrac{1}{2}\)n\(_{Al}\) = 0,1 (mol)
\(\Rightarrow\) C%\(_{Al_2\left(SO_4\right)_3}\) = \(\dfrac{0,1.342}{104,8}\).100% = 32,63%
\(n_{Al}=\dfrac{5.4}{27}=0.2\left(mol\right)\)
\(n_{H_2SO_4}=\dfrac{200\cdot39.2\%}{98}=0.8\left(mol\right)\)
\(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)
Lập tỉ lệ :
\(\dfrac{0.2}{2}< \dfrac{0.8}{3}\) => H2SO4 dư
\(n_{H_2}=\dfrac{3}{2}\cdot0.2=0.3\left(mol\right)\)
\(V_{H_2}=0.3\cdot22.4=6.72\left(l\right)\)
\(m_{dd}=5.4+200-0.3\cdot2=204.8\left(g\right)\)
\(m_{Al_2\left(SO_4\right)_3}=0.1\cdot342=34.2\left(g\right)\)
\(C\%_{Al_2\left(SO_4\right)_3}=\dfrac{34.2}{204.8}\cdot100\%=16.7\%\)
\(n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right)\)
PT: \(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)
Theo PT: \(n_{H_2}=\dfrac{3}{2}n_{Al}=0,3\left(mol\right)\)
\(\Rightarrow V_{H_2}=0,3.24,79=7,437\left(l\right)\)
a, PT: \(Zn+H_2SO_4\rightarrow ZnSO_4+H_2\)
\(CuO+H_2SO_4\rightarrow CuSO_4+H_2O\)
b, Ta có: \(n_{H_2}=\dfrac{11,2}{22,4}=0,5\left(mol\right)\)
Theo PT: \(n_{Zn}=n_{H_2}=0,5\left(mol\right)\)
\(\Rightarrow m_{Zn}=0,5.65=32,5\left(g\right)\)
\(\Rightarrow m_{CuO}=72,5-32,5=40\left(g\right)\)
c, Ta có: \(n_{CuO}=\dfrac{40}{80}=0,5\left(mol\right)\)
Theo PT: \(n_{H_2SO_4}=n_{Zn}+n_{CuO}=1\left(mol\right)\)
\(\Rightarrow b=C_{M_{H_2SO_4}}=\dfrac{1}{2,5}=0,4M\)
c, Theo PT: \(\left\{{}\begin{matrix}n_{ZnSO_4}=n_{Zn}=0,5\left(mol\right)\\n_{CuSO_4}=n_{CuO}=0,5\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}C_{M_{ZnSO_4}}=\dfrac{0,5}{2,5}=0,2M\\C_{M_{CuSO_4}}=\dfrac{0,5}{2,5}=0,2M\end{matrix}\right.\)
Bạn tham khảo nhé!
a, \(Zn+H_2SO_4\rightarrow ZnSO_4+H_2\left(I\right)\)
\(CuO+H_2SO_4\rightarrow CuSO_4+H_2O\left(II\right)\)
b, Theo PTHH(1) : \(n_{Zn}=n_{H_2}=0,5\left(mol\right)\)
\(\Rightarrow m_{Zn}=32,5\left(g\right)\)
\(\Rightarrow m_{CuO}=m_{hh}-m_{Zn}=40\left(g\right)\)
\(\Rightarrow n_{CuO}=\dfrac{m}{M}=0,5\left(mol\right)\)
c, Theo PTHH (1) và (2) : \(n_{H2SO4}=n_{CuO}+n_{Zn}=1\left(mol\right)\)
\(\Rightarrow C_{MH2SO4}=b=\dfrac{n}{V}=\dfrac{1}{2,5}=0,4M\)
d, ( Chắc là thể tích coi như không đổi )
Thấy sau phản ứng thu được A gồm \(0,5molZnSO_4,0,5molCuSO_4\)
\(\Rightarrow C_{MCuSO4}=C_{MZnSO4}=\dfrac{n}{V}=\dfrac{0,5}{2,5}=0,2M\)
Vậy ...
PTHH: \(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\uparrow\)
Ta có: \(\left\{{}\begin{matrix}n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right)\\n_{H_2SO_4}=\dfrac{200\cdot29,4\%}{98}=0,6\left(mol\right)\end{matrix}\right.\)
Xét tỉ lệ: \(\dfrac{0,2}{2}< \dfrac{0,6}{3}\) \(\Rightarrow\) Axit còn dư, Nhôm p/ứ hết
\(\Rightarrow\left\{{}\begin{matrix}n_{Al_2\left(SO_4\right)_3}=0,1\left(mol\right)\\n_{H_2}=0,3\left(mol\right)\\n_{H_2SO_4\left(dư\right)}=0,6-0,3=0,3\left(mol\right)\end{matrix}\right.\)\(\Rightarrow\left\{{}\begin{matrix}m_{Al_2\left(SO_4\right)_3}=0,1\cdot342=34,2\left(g\right)\\m_{H_2SO_4\left(dư\right)}=0,3\cdot98=29,4\left(g\right)\\m_{H_2}=0,3\cdot2=0,6\left(g\right)\\V_{H_2}=0,3\cdot22,4=6,72 \left(l\right)\end{matrix}\right.\)
Mặt khác: \(m_{dd\left(saup/ứ\right)}=m_{Al}+m_{ddH_2SO_4}-m_{H_2}=204,8\left(g\right)\)
\(\Rightarrow\left\{{}\begin{matrix}C\%_{Al_2\left(SO_4\right)_3}=\dfrac{34,2}{204,8}\cdot100\%\approx16,7\%\\C\%_{H_2SO_4\left(dư\right)}=\dfrac{29,4}{204,8}\cdot100\%\approx14,36\%\end{matrix}\right.\)