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a) PTHH: \(Fe+2HCl\rightarrow FeCl_2+H_2\) (1)
\(2Al+6HCl\rightarrow2AlCl_3+3H_2\) (2)
b) Ta có: \(\Sigma n_{H_2}=\dfrac{3,024}{22,4}=0,135\left(mol\right)\)
Gọi số mol của Fe là \(a\) \(\Rightarrow n_{H_2\left(1\right)}=a\)
Gọi số mol của Al là \(b\) \(\Rightarrow n_{H_2\left(2\right)}=\dfrac{3}{2}b\)
Ta lập được hệ phương trình:
\(\left\{{}\begin{matrix}a+\dfrac{3}{2}b=0,135\\56b+27b=4,14\end{matrix}\right.\) \(\Leftrightarrow\left\{{}\begin{matrix}a=0,045\\b=0,06\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{Fe}=0,045\cdot56=2,52\left(g\right)\\m_{Al}=1,62\left(g\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{Fe}=\dfrac{2,52}{4,14}\cdot100\%\approx60,87\%\\\%m_{Al}=39,13\%\end{matrix}\right.\)
c) PTHH: \(FeCl_2+2NaOH\rightarrow2NaCl+Fe\left(OH\right)_2\downarrow\)
\(AlCl_3+3NaOH\rightarrow Al\left(OH\right)_3\downarrow+3NaCl\)
\(4Fe\left(OH\right)_2+O_2\underrightarrow{t^o}2Fe_2O_3+4H_2O\)
\(2Al\left(OH\right)_3\underrightarrow{t^o}Al_2O_3+3H_2O\)
Theo các PTHH: \(\left\{{}\begin{matrix}n_{Fe\left(OH\right)_2}=n_{FeCl_2}=0,045mol\\n_{Al\left(OH\right)_3}=n_{AlCl_3}=0,06mol\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}n_{Fe_2O_3}=0,0225mol\\n_{Al_2O_3}=0,03mol\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{Fe_2O_3}=0,0225\cdot160=3,6\left(g\right)\\m_{Al_2O_3}=0,03\cdot102=3,06\left(g\right)\end{matrix}\right.\)
\(\Rightarrow m_{chấtrắn}=3,06+3,6=6,66\left(g\right)\)
a)
$Fe + 2HCl \to FeCl_2 + H_2$
$FeO +2 HCl \to FeCl_2 + H_2O$
b)
Theo PTHH :
$n_{Fe} = n_{H_2} = \dfrac{4,48}{22,4} = 0,2(mol)$
$\%m_{Fe} = \dfrac{0,2.56}{20}.100\% = 56\%$
$\%m_{FeO} = 100\% - 56\% = 44\%$
c) $n_{FeO} = \dfrac{11}{90}(mol)$
$n_{HCl} = 2n_{Fe} + 2n_{FeO} = \dfrac{29}{45}(mol)$
$m_{dd\ HCl} = \dfrac{ \dfrac{29}{45}.36,5}{7,3\%} = 322,22(gam)$
theo bài ta có:nH2=6,72/22,4=0,3(mol)
pthh; 2Al+3H2SO4------>Al2(SO4)3+3H2 (1)
2Al2O3+3H2SO4-------->Al2(SO4)3+3H2O (2)
ta có:nAl=0,3(mol)
=>mAl=0,3*27=8,1(g)
=>mAl2O3=15,6-8,1=7,5(g)
=>nAl2O3=7,5/102=5/68(mol)
=>nH2SO4=1,5*0,3+1,5*5/68=0,56(mol)
=>V(H2SO4)=0,56/1,5=0,37(l)
Chúc bạn học tốt
\(n_{H_2}=\dfrac{2,24}{22,4}=0,1mol\)
a)\(Fe+2HCl\rightarrow FeCl_2+H_2\)
0,1 0,1 0,1
\(m_{Fe}=0,1\cdot56=5,6\left(g\right)\)
b)\(\Rightarrow\%m_{Fe}=\dfrac{5,6}{12}\cdot100\%=46,67\%\) \(\Rightarrow\%m_{Cu}=100\%-46,67\%=53,33\%\)
c)\(n_{NaOH}=0,1\cdot1=0,1mol\)
\(2NaOH+FeCl_2\rightarrow Fe\left(OH\right)_2+2NaCl\)
0,1 0,1 0,1
\(m_{Fe\left(OH\right)_2}=0,1\cdot90=9\left(g\right)\)
PTHH:
\(CaCO_3+2HCl\rightarrow CaCl_2+H_2O+CO_2\uparrow\)
0,15 0,15
\(CaO+2HCl\rightarrow CaCl_2+H_2O\)
Ta có: \(n_{CO_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)
\(\Rightarrow m_{CaCO_3}=0,15\cdot100=15\left(g\right)\)
\(\Rightarrow m_{CaO}=20,6-15=5,6\left(g\right)\)
\(\Rightarrow\%m_{CaCO_3}=\dfrac{15\cdot100}{20,6}\approx73\%\)
\(\Rightarrow\%m_{CaO}=100\%-73\%=27\%\)
a, PT: \(2Al+6HCl\rightarrow2AlCl_3+3H_2\)
\(FeO+2HCl\rightarrow FeCl_2+H_2O\)
b, Ta có: \(n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)
Theo PT: \(n_{Al}=\dfrac{2}{3}n_{H_2}=0,2\left(mol\right)\)
\(\Rightarrow m_{Al}=0,2.27=5,4\left(g\right)\)
⇒ mFeO = 12,6 - 5,4 = 7,2 (g)
c, Phần này đề cho dd NaOH dư hay vừa đủ bạn nhỉ?
d, Cho hh vào dd H2SO4 đặc nguội thì có khí thoát ra.
PT: \(2FeO+4H_2SO_{4\left(đ\right)}\rightarrow Fe_2\left(SO_4\right)_3+SO_2+4H_2O\)
Ta có: \(n_{FeO}=\dfrac{7,2}{72}=0,1\left(mol\right)\)
Theo PT: \(n_{SO_2}=\dfrac{1}{2}n_{FeO}=0,05\left(mol\right)\)
\(\Rightarrow V_{SO_2}=0,05.22,4=1,12\left(l\right)\)
\(n_{H_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)
PTHH :
\(Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\)
0,15 0,3 0,15 0,15
\(Fe_2O_3+6HCl\rightarrow2FeCl_3+3H_2O\)
0,1 0,6 0,2 0,3
\(m_{Fe}=0,15.56=8,4\left(g\right)\)
\(m_{Fe_2O_3}=15-8,4=6,6\left(g\right)\)
\(n_{Fe_2O_3}=\dfrac{16}{160}=0,1\left(mol\right)\)
\(C_{M\left(HCl\right)}=\dfrac{0,3+0,6}{0,05}=18\left(M\right)\)
\(FeCl_2+2NaOH\rightarrow Fe\left(OH\right)_2+2NaCl\)
0,35 0,35
\(m_{Fe\left(OH\right)_2}=0,35.90=31,5\left(g\right)\)