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Sửa: \(14,7\%\)
\(n_{H_2SO_4}=\dfrac{200.14,7\%}{100\%.98}=0,3(mol)\\ a,PTHH:2Al+3H_2SO_4\to Al_2(SO_4)_3+3H_2\\ \Rightarrow n_{H_2}=0,3(mol)\\ \Rightarrow V_{H_2}=0,3.22,4=6,72(l)\\ b,n_{Al}=\dfrac{2}{3}n_{H_2SO_4}=0,2(mol)\\ \Rightarrow m_{Al}=0,2.27=5,4(g)\\ c,n_{Al_2(SO_4)_3}=\dfrac{1}{2}n_{Al}=0,1(mol)\\ \Rightarrow C\%_{Al_2(SO_4)_3}=\dfrac{0,1.342}{200+5,4-0,3.2}.100\%=16,7\%\\ c,m_{Al_2(SO_4)_3}=0,1.342=34,2(g)\)
PTHH: 2Al + 3H2SO4 ---> Al2(SO4)3 + 3H2.
Ta có: \(C_{\%_{H_2SO_4}}=\dfrac{m_{H_2SO_4}}{200}.100\%=14,7\%\)
=> \(m_{H_2SO_4}=29,4\left(g\right)\)
=> \(n_{H_2SO_4}=\dfrac{29,4}{98}=0,3\left(mol\right)\)
Theo PT: \(n_{Al_2\left(SO_4\right)_3}=\dfrac{1}{3}.n_{H_2SO_4}=\dfrac{1}{3}.0,3=0,1\left(mol\right)\)
=> \(m_{Al_2\left(SO_4\right)_3}=0,1.342=34,2\left(g\right)\)
PTHH: \(Fe_2O_3+3H_2SO_4\rightarrow Fe_2\left(SO_4\right)_3+3H_2O\)
Ta có: \(n_{Fe_2O_3}=\dfrac{4,8}{160}=0,03\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}n_{H_2SO_4}=0,09\left(mol\right)\\n_{Fe_2\left(SO_4\right)_3}=0,03\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{ddH_2SO_4}=\dfrac{0,09\cdot98}{9,8\%}=90\left(g\right)\\m_{Fe_2\left(SO_4\right)_3}=0,03\cdot400=12\left(g\right)\end{matrix}\right.\)
Bài 3 :
\(n_{Al}=\dfrac{2,7}{27}=0,1\left(mol\right)\)
Pt : \(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2|\)
2 3 1 3
0,1 0,15 0,05 0,15
a) \(n_{H2}=\dfrac{0,1.3}{2}=0,15\left(mol\right)\)
\(m_{H2}=0,15.2=0,3\left(g\right)\)
\(V_{H2\left(dktc\right)}=0,15.22,4=3,36\left(l\right)\)
b) \(n_{H2SO4}=\dfrac{0,1.3}{2}=0,15\left(mol\right)\)
⇒ \(m=0,15.98=14,7\left(g\right)\)
\(C_{ddH2SO4}=\dfrac{14,7.100}{200}=7,35\)0/0
c) \(n_{Al2\left(SO4\right)3}=\dfrac{0,15.1}{3}=0,05\left(mol\right)\)
⇒ \(m_{Al2\left(SO4\right)3}=0,05.342=17,1\left(g\right)\)
\(m_{ddspu}=2,7+200-0,3=302,4\left(g\right)\)
\(C_{Al2\left(SO4\right)3}=\dfrac{17,1.100}{302,4}=5,65\)0/0
Chúc bạn học tốt
Mình xin lỗi bạn nhé , bạn sửa lại giúp mình :
\(m_{ddspu}=2,7+200-0,3=202,4\left(g\right)\)
\(C_{Al2\left(SO4\right)3}=\dfrac{17,1.100}{202,4}=8,45\)0/0
2Al+6HCl----->2AlCl3+3H2
nAl=2,7/27=0,1 mol
cứ 2mol Al------> 2 mol AlCl3
0,1mol ----->0,1 mol
mAlCl3=0,1.133,5=13.35g
H%=80%------->mAlCl3 thực tế thu được =13,35.80/100=10,68g
n Al = 2,7/27 =0,1 mol
2Al + 6HCl ---> 2AlCl3 + 3H2
0,1 ---> 0,1
ADCT : H% =80% ----> m AlCl3 tạo thành = (m AlCl3 thực tế . H% ) / 100
hay m AlCl3 = ((0,1.133,5) .80 ) / 100 =10,68 %
a,\(n_{Al}=\dfrac{2,7}{27}=0,1\left(mol\right)\)
PTHH: 2Al + 3H2SO4 → Al2(SO4)3 + 3H2
Mol: 0,1 0,15 0,05 0,15
\(m_{H_2}=0,15.2=0,3\left(g\right)\)
\(V_{H_2}=0,15.24,79=3,7185\left(l\right)\)
b, \(m_{ddH_2SO_4}=\dfrac{0,15.98.100\%}{200}=7,35\%\)
c, mdd sau pứ = 2,7 + 200 - 0,3 = 202,4 (g)
\(C\%_{ddAl_2\left(SO_4\right)_3}=\dfrac{0,05.342.100\%}{202,4}=8,45\%\)
PTHH: \(Fe_2O_3+3H_2SO_4\rightarrow Fe_2\left(SO_4\right)_3+3H_2O\)
Ta có: \(\left\{{}\begin{matrix}n_{Fe_2O_3}=\dfrac{16}{160}=0,1\left(mol\right)\\n_{H_2SO_4}=\dfrac{200\cdot9,8\%}{98}=0,2\left(mol\right)\end{matrix}\right.\)
Xét tỉ lệ: \(\dfrac{0,1}{1}>\dfrac{0,2}{3}\) \(\Rightarrow\) Fe2O3 còn dư, tính theo axit
\(\Rightarrow\left\{{}\begin{matrix}n_{Fe_2\left(SO_4\right)_3}=0,1\left(mol\right)\\n_{Fe_2O_3\left(dư\right)}=\dfrac{1}{30}\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{Fe_2\left(SO_4\right)_3}=0,1\cdot400=40\left(g\right)\\m_{Fe_2O_3\left(dư\right)}=\dfrac{1}{30}\cdot160\approx5,3\left(g\right)\end{matrix}\right.\)
\(\Rightarrow C\%_{Fe_2\left(SO_4\right)_3}=\dfrac{40}{16+200-5,3}\cdot100\%\approx18,98\%\)
\(n_{Al}=\dfrac{2,7}{27}=0,1\left(mol\right)\\ 2Al+3CuCl_2\rightarrow2AlCl_3+3Cu\\ n_A=n_{AlCl_3}=n_{Al}=0,1\left(mol\right)\\ n_B=n_{Cu}=\dfrac{3}{2}.0,1=0,15\left(mol\right)\\ m_B=m_{Cu}=0,15.64=9,6\left(g\right)\\ C_{MddAlCl_3}=\dfrac{0,1}{0,2}=0,5\left(M\right)\)
mH2SO4 = 9,8%.200=19,6(g) -> nH2SO4=0,2(mol)
nAl=0,1(mol)
PTHH: 2Al +3 H2SO4 -> Al2(SO4)3 + 3H2
Ta có: 0,1/2 < 0,2/3 => H2SO4 dư, Al hết, tính heo nAl
nAl2(SO4)3=mAl/2=0,1/2=0,05(mol)
mAl2(SO4)3 (LT)= 0,05.342=17,1(g)
Vì: H=75%
=>mAl2(SO4)3 (TT)=75%. 17,1=12,825(g)