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a. PTHH:
\(BaO+2HCl--->BaCl_2+H_2O\left(1\right)\)
\(BaCO_3+2HCl--->BaCl_2+CO_2\uparrow+H_2O\left(2\right)\)
Ta có: \(n_{CO_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
Theo PT(2): \(n_{BaCO_3}=n_{CO_2}=0,2\left(mol\right)\)
\(\Rightarrow m_{BaCO_3}=0,2.197=39,4\left(g\right)\)
\(\Rightarrow\%_{m_{BaCO_3}}=\dfrac{39,4}{54,7}.100\%=72,03\%\)
\(\%_{m_{BaO}}=100\%-72,03\%=27,97\%\)
b. Ta có: \(m_{BaO}=54,7-39,4=15,3\left(g\right)\)
\(\Rightarrow n_{BaO}=\dfrac{15,3}{153}=0,1\left(mol\right)\)
\(\Rightarrow n_A=0,1+0,2=0,3\left(mol\right)\)
Theo PT(1,2): \(n_{HCl}=2.n_A=2.0,3=0,6\left(mol\right)\)
\(\Rightarrow m_{HCl}=0,6.36,5=21,9\left(g\right)\)
Ta có: \(C_{\%_{HCl}}=\dfrac{21,9}{m_{dd_{HCl}}}.100\%=20\%\)
\(\Rightarrow m_{dd_{HCl}}=109,5\left(g\right)\)
\(n_{CO2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
a) Pt : \(BaO+2HCl\rightarrow BaCl_2+H_2O|\)
1 2 1 1
0,1 0,2
\(BaCO_3+2HCl\rightarrow BaCl_2+CO_2+H_2O|\)
1 2 1 1 1
0,2 0,4 0,2
\(n_{BaCO3}=\dfrac{0,2.1}{1}=0,2\left(mol\right)\)
\(m_{BaCO3}=0,2.197=39,4\left(g\right)\)
\(m_{BaO}=54,7-39,4=15,3\left(g\right)\)
0/0BaO = \(\dfrac{15,3.100}{54,7}=27,97\)0/0
0/0BaCO3 = \(\dfrac{39,4.100}{54,7}=72,03\)0/0
b) Có : \(m_{BaO}=15,3\left(g\right)\)
\(n_{BaO}=\dfrac{15,3}{153}=0,1\left(mol\right)\)
\(n_{HCl\left(tổng\right)}=0,2+0,4=0,6\left(mol\right)\)
\(m_{HCl}=0,6.36,5=21,9\left(g\right)\)
\(m_{ddHCl}=\dfrac{21,9.100}{20}=109,5\left(g\right)\)
Chúc bạn học tốt
Sửa đề: 1,755 (g) → 17,55 (g)
a, Giả sử CTHH cần tìm là A2On.
PT: \(A_2O_n+2nHCl\rightarrow2ACl_n+nH_2O\)
Ta có: \(n_{A_2O_n}=\dfrac{9,3}{2M_A+16n}\left(mol\right)\)
\(n_{ACl_n}=\dfrac{17,55}{M_A+35,5n}\left(mol\right)\)
Theo PT: \(n_{ACl_n}=2n_{A_2O_n}\Rightarrow\dfrac{17,55}{M_A+35,5n}=\dfrac{2.9,3}{2M_A+16n}\)
⇒ MA = 23n (g/mol)
Với n = 1 thì MA = 23 (g/mol) là thỏa mãn.
→ CTHH: Na2O.
b, Ta có: \(n_{Na_2O}=\dfrac{9,3}{62}=0,15\left(mol\right)\)
Theo PT: \(n_{HCl}=2n_{Na_2O}=0,3\left(mol\right)\)
\(\Rightarrow m_{HCl}=0,3.36,5=10,95\left(g\right)\)
\(\Rightarrow m_{ddHCl}=\dfrac{10,95}{20\%}=54,75\left(g\right)\)
\(n_{K_2O}=\dfrac{1,88}{94}=0,02(mol)\\ a,K_2O+H_2O\to 2KOH\\ b,n_{KOH}=0,04(mol)\\ \Rightarrow C_{M_{KOH}}=\dfrac{0,04}{0,5}=0,08M\\ c,n_{KOH}=0,04.50\%=0,02(mol)\\ KOH+HCl\to KCl+H_2O\\ \Rightarrow n_{HCl}=0,02(mol)\\ \Rightarrow m_{dd_{HCl}}=\dfrac{0,02.36,5}{7,3\%}=10(g)\)
a) PTHH: \(Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\)
a_____2a______a_____a (mol)
\(2Al+6HCl\rightarrow2AlCl_3+3H_2\uparrow\)
b_____3b_______b_____\(\dfrac{3}{2}\)b (mol)
Ta lập HPT: \(\left\{{}\begin{matrix}56a+27b=36,1\\a+\dfrac{3}{2}b=\dfrac{21,28}{22,4}=0,95\end{matrix}\right.\) \(\Leftrightarrow\left\{{}\begin{matrix}a=0,5\\b=0,3\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}m_{Fe}=0,5\cdot56=28\left(g\right)\\m_{Al}=8,1\left(g\right)\end{matrix}\right.\)
b+c) Theo các PTHH: \(\left\{{}\begin{matrix}n_{HCl}=2a+3b=1,9\left(mol\right)\\n_{FeCl_2}=0,5\left(mol\right)\\n_{AlCl_3}=0,3\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}C_{M_{HCl}}=\dfrac{1,9}{0,2}=9,5\left(M\right)\\C_{M_{FeCl_2}}=\dfrac{0,5}{0,2}=2,5\left(M\right)\\C_{M_{AlCl_3}}=\dfrac{0,3}{0,2}=1,5\left(M\right)\end{matrix}\right.\)
\(Fe_2O_3 + 6HCl \rightarrow 2FeCl_3 + 3H_2O\)
\(CuO + 2HCl \rightarrow CuCl_2 + H_2O\)
\(NaOH + HCl \rightarrow NaCl + H_2O\)
\(n_{NaOH} = 0,2 . 1 = 0,2 mol\)
\(n_{HCl dư} = n_{NaOH}= 0,2 mol\)
\(\Rightarrow n_{HCl pư}= n_{HCl ban đầu} - n_{HCl dư}= 1,4- 0,2 = 1,2 mol\)
Gọi n\(Fe_2O_3\) và n\(CuO\) là x, y
\(\begin{cases} 160x + 80y=40\\ 6x + 2y= 1,2 \end{cases} \)
\(\begin{cases} x=0,1\\ y=0,3 \end{cases} \)
\(\Rightarrow m_{Fe_2O_3}= 0,1 . 160= 16g\)
\(m_{CuO} = 0,3 . 80=24g\)
Đặt nK2O=a(mol); nK2O=b(mol) (a,b>0)
Ta có: nHCl=0,6(mol)
K2O + H2O -> 2 KOH
a____________2a(mol)
Na2O + H2O -> 2 NaOH
b___________2b(mol)
KOH + HCl -> KCl + H2O
2a____2a____2a(mol)
NaOH + HCl -> NaCl + H2O
2b___2b______2b(mol)
Ta có hpt:
\(\left\{{}\begin{matrix}94a+62b=25\\2a+2b=0,6\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,2\\b=0,1\end{matrix}\right.\)
=> mK2O=0,2.94=18,8(g)
=>%mK2O= (18,8/25).100=75,2%
=>%mNa2O=24,8%
b) m(muối)= mKCl+ mNaCl= 74,5.0,4+ 58,5.0,2=41,5(g)