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\(n_{Fe_2O_3}=\dfrac{20}{160}=0,125\left(mol\right)\)
PTHH:
\(Fe_2O_3+3H_2SO_4\rightarrow Fe_2\left(SO_4\right)_3+3H_2O\)
0,125 0,375 0,125 0,375
\(m_{ddH_2SO_4}=\dfrac{0,375.98.100}{25}=147\left(g\right)\)
\(C\%_{Fe_2\left(SO_4\right)_3}=\dfrac{0,125.406}{20+147}\approx30,39\%\)
Bài 2:
a) PTHH: \(Na_2O+H_2O\rightarrow2NaOH\)
b) Dung dịch A là dung dịch bazơ
Ta có: \(n_{Na_2O}=\dfrac{3,1}{62}=0,05\left(mol\right)\) \(\Rightarrow n_{NaOH}=0,1\left(mol\right)\) \(\Rightarrow C_{M_{NaOH}}=\dfrac{0,1}{1}=0,1\left(M\right)\)
c) Sửa đề: dd H2SO4 9,8%
PTHH: \(2NaOH+H_2SO_4\rightarrow Na_2SO_4+2H_2O\)
Theo PTHH: \(n_{H_2SO_4}=\dfrac{1}{2}n_{NaOH}=0,05\left(mol\right)\)
\(\Rightarrow m_{ddH_2SO_4}=\dfrac{0,05\cdot98}{9,8\%}=50\left(g\right)\) \(\Rightarrow V_{ddH_2SO_4}=\dfrac{50}{1,14}\approx43,86\left(ml\right)\)
Bài 1:
PTHH: \(CuO+H_2SO_4\rightarrow CuSO_4+H_2O\)
Ta có: \(\left\{{}\begin{matrix}n_{CuO}=\dfrac{16}{80}=0,2\left(mol\right)\\n_{H_2SO_4}=\dfrac{200\cdot19,6\%}{98}=0,4\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\) Axit còn dư
\(\Rightarrow n_{CuSO_4}=0,2\left(mol\right)=n_{H_2SO_4\left(dư\right)}\)
\(\Rightarrow\left\{{}\begin{matrix}C\%_{CuSO_4}=\dfrac{0,2\cdot160}{200+16}\cdot100\%\approx14,81\%\\C\%_{H_2SO_4\left(dư\right)}=\dfrac{0,2\cdot98}{200+16}\cdot100\%\approx9,07\%\end{matrix}\right.\)
\(n_{KOH}=\dfrac{100.14}{100.56}=0,25(mol)\\ 2KOH+CuCl_2\to Cu(OH)_2\downarrow+2KCl\\ \Rightarrow n_{CuCl_2}=n_{Cu(OH)_2}=0,125(mol);n_{KCl}=0,25(mol)\\ a,m_{CuCl_2}=0,125.135=16,875(g)\\ b,m_{Cu(OH)_2}=0,125.98=12,25(g)\\ c,C\%_{KCl}=\dfrac{0,25.74,5}{100+16,875-12,25}.100\%=17,8\%\\ d,Cu(OH)_2\xrightarrow{t^o}CuO+H_2O\\ \Rightarrow n_{CuO}=0,125(mol)\\ \Rightarrow m_{CuO}=0,125.80=10(g)\)
\(n_{Ba\left(OH\right)_2}=0,5.0,2=0,1\left(mol\right);n_{H_2SO_4}=0,3.0,4=0,12\left(mol\right)\)
PTHH: Ba(OH)2 + H2SO4 → BaSO4↓ + 2H2O
Mol: 0,1 0,1 0,1
Ta có: \(\dfrac{0,1}{1}< \dfrac{0,12}{1}\) ⇒ Ba(OH)2 hết, H2SO4 dư
\(C_{M_{H_2SO_4dư}}=\dfrac{0,12-0,1}{0,2+0,3}=0,04M\)
mdd sau pứ = 200.2,3+300.1,6-0,1.233 = 916,7 (g)
\(C\%_{H_2SO_4dư}=\dfrac{0,02.98.100\%}{916,7}=0,21\%\)
mình giải ở dưới r nhé.