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![](https://rs.olm.vn/images/avt/0.png?1311)
n Ba(OH)2 = 2.0,2=0,4 mol
\(Ba\left(OH\right)_2+SO_2->BaSO_3+H_2O\)
0,4 ................0,4...........0,4
m BaSO3 = 0,4. ( 138+32+16.3)=87,2 g
v SO2 = 0,4.22,4=8,96 lít
m BaSO3 = 0,4. ( 137+32+16.3)=86,8 g
xin lũi nha mình nhìn nhầm bạn thông cảm
![](https://rs.olm.vn/images/avt/0.png?1311)
a.CuCl2 + 2NaOH -> Cu(OH)2 + 2NaCl
0.15 0.3 0.15 0.3
Cu(OH)2 -> CuO + H2O
0.15 0.15
nNaOH = 0.3 mol
\(CM_{CuCl2}=\dfrac{0.15}{2}=0.075M\)
b.Vdd sau phản ứng = 0.2 + 0.15 = 0.35l
\(CM_{NaCl}=\dfrac{0.3}{0.35}=0.86M\)
c.mCuO = \(0.15\times80=12g\)
![](https://rs.olm.vn/images/avt/0.png?1311)
\(n_{NaOH}=\dfrac{200.10\%}{40}=0,5\left(mol\right)\)
\(PTHH:CuCl_2+2NaOH\rightarrow2NaCl+Cu\left(OH\right)_2\)
bđ: 0,3 0,5
pứ: 0,25 0,5 0,5 0,25
[ ]: 0,05 0 0,5 0,25
\(PTHH:Cu\left(OH\right)_2\underrightarrow{t^o}CuO+H_2O\)
(mol) 0,25 0,25
\(a.m_C=80.0,25=20\left(g\right)\)
\(b.m_{NaCl}=58,5.0,5=29,25\left(g\right)\\ m_{Cu\left(OH\right)_2}=0,25.98=24,5\left(g\right)\\ m_{CuCl_2\left(du\right)}=135.0,05=6,75\left(g\right)\)
\(c.m_{ddspu}=100+200-24,5=275,5\left(g\right)\\ C\%_{ddCuCl_2\left(du\right)}=\dfrac{135.0,05}{275,5}.100=2,45\left(\%\right)\\ C\%_{ddNaCl}=\dfrac{0,5.58,5}{275,25}.100=10,62\left(\%\right)\)
![](https://rs.olm.vn/images/avt/0.png?1311)
\(n_{FeCl_2}=\dfrac{254}{127}=2mol\)
\(n_{NaOH}=\dfrac{200}{40}=5mol\)
\(FeCl_2+2NaOH\rightarrow Fe\left(OH\right)_2\downarrow+2NaCl\)
bđ 2 5
pứ 2 4 2 4
kt 0 1 2 4
a) Chất rắn C thu được là: Fe(OH)2
\(\Rightarrow m_{Fe\left(OH\right)_2}=2\cdot90=180mol\)
b) \(m_{NaCl}=4\cdot58,5=234g\)
\(m_{NaOHdư}=1\cdot40=40g\)
![](https://rs.olm.vn/images/avt/0.png?1311)
a)
$Mg + CuCl_2 \to MgCl_2 + Cu$
$Fe + CuCl_2 \to FeCl_2 + Cu$
$MgCl_2 + 2NaOH \to Mg(OH)_2 + 2NaCl$
$FeCl_2 + 2NaOH \to Fe(OH)_2 + 2NaCl$
$Mg(OH)_2 \xrightarrow{t^o} MgO + H_2O$
$4Fe(OH)_2 + O_2 \xrightarrow{t^o} 2Fe_2O_3 + 4H_2O$
b)$m_A = 3,16 < m_{oxit}$ Chứng tỏ Fe dư.
Gọi $n_{Mg} =a ;n_{Fe\ pư} = b ; n_{Fe\ dư} = c(mol)$
$\Rightarrow 24a + 56b + 56c = 3,16(1)$
Bảo toàn Mg,Fe :
$40a + 80b = 1,4(2)$
$m_C =m_{Cu} + m_{Fe\ dư} = (a + b).64 + 56c = 3,48(3)$
Từ (1)(2)(3) suy ra a = 0,005 ; b = 0,015;
$\%m_{Mg} = \dfrac{0,005.24}{3,16}.100\% = 3,8\%$
$\%m_{Fe} = 96,2\%$
$n_{CuCl_2} = 0,005 + 0,015 = 0,02(mol)$
$C_{M_{CuCl_2}} = \dfrac{0,02}{0,25} = 0,08M$
Ta thấy :
![](https://rs.olm.vn/images/avt/0.png?1311)
\(n_{CuSO_4}=2.0,34=0,68(mol)\\ a,CuSO_4+2NaOH\to Na_2SO_4+Cu(OH)_2\downarrow\\ Cu(OH)_2\xrightarrow{t^o}CuO+H_2O\\ \Rightarrow n_{Cu(OH)_2}=0,68(mol)\\ \Rightarrow m_{Cu(OH)_2}=0,68.98=66,64(g)\\ b,n_{CuO}=0,68(mol)\\ \Rightarrow m_{CuO}=0,68.80=54,4(g)\\ c,V_{dd_{NaOH}}=\dfrac{200}{1,25}=160(ml)\\ n_{NaOH}=\dfrac{200.32\%}{100\%.40}=1,6(mol)\)
Vì \(\dfrac{n_{CuSO_4}}{1}<\dfrac{n_{NaOH}}{2}\) nên \(NaOH\) dư
\(\Rightarrow n_{NaOH(dư)}=1,6-0,68.2=0,24(mol); n_{Na_2SO_4}=0,68(mol)\\ \Rightarrow \begin{cases} C_{M_{NaOH(dư)}}=\dfrac{0,24}{0,16}=1,5M\\ C_{M_{Na_2SO_4}}=\dfrac{0,68}{0,16}=4,25M \end{cases}\)
![](https://rs.olm.vn/images/avt/0.png?1311)
Chất rắn thu được sau khi nung là ZnO.
\(\Rightarrow n_{ZnO}=\dfrac{8,1}{81}=0,1\left(mol\right)\)
BTNT Zn, có: nZn = nZnO = 0,1 (mol)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{Zn}=\dfrac{0,1.65}{13,5}.100\%\approx48,15\%\\\%m_{Fe}\approx100-48,15=51,85\%\end{matrix}\right.\)
A
chọn đáp án A