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PTHH: Zn + 2HCl \(\rightarrow\) ZnCl2 + H2\(\uparrow\)
nZn = \(\dfrac{6,5}{65}=0,1\left(mol\right)\)
Theo PT: nHCl = 2nZn =2.0,1=0,2(mol)
nH2=nZn=0,1 ( mol )
=>VH2=0,1 . 22,4= 2,24( l )
Đổi : 500ml=0,5l
=> CM = \(\dfrac{n}{V}\) = \(\dfrac{0,2}{0,5}\) = 0,4( M )
PTHH: \(H_2SO_4+2KOH\rightarrow K_2SO+2H_2O\)
Ta có: \(n_{H_2SO_4}=0,2\cdot1=0,2\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}n_{KOH}=0,4\left(mol\right)\\n_{K_2SO_4}=0,2\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}V_{ddKOH}=\dfrac{\dfrac{0,4\cdot56}{6\%}}{1,048}\approx356,2\left(ml\right)\\C_{M_{K_2SO_4}}=\dfrac{0,2}{0,2+0,3562}\approx0,36\left(M\right)\end{matrix}\right.\)
\(n_{H_2SO_4}=1.0,2=0,2\left(mol\right)\\ H_2SO_4+2KOH\rightarrow K_2SO_4+2H_2O\\ 0,2.........0,4........0,2.......0,2\left(mol\right)\\ a.m_{ddKOH}=\dfrac{0,4.56.100}{6}=\dfrac{1120}{3}\left(g\right)\\ V_{ddKOH}=\dfrac{\dfrac{1120}{3}}{1,048}=\dfrac{140000}{393}\left(ml\right)\approx0,356\left(l\right)\)
\(b.C_{MddK_2SO_4}=\dfrac{0,2}{\dfrac{140000}{393}+0,2}\approx0,00056\left(M\right)\)
\(n_{CO_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\)
PT: \(CO_2+Ca\left(OH\right)_2\rightarrow CaCO_3+H_2O\)
Theo PT: \(n_{Ca\left(OH\right)_2}=n_{CaCO_3}=n_{CO_2}=0,25\left(mol\right)\)
a, \(C_{M_{Ca\left(OH\right)_2}}=\dfrac{0,25}{0,1}=2,5\left(M\right)\)
b, \(m_{CaCO_3}=0,25.100=25\left(g\right)\)
c, \(Ca\left(OH\right)_2+2HCl\rightarrow CaCl_2+2H_2O\)
Theo PT: \(n_{HCl}=2n_{Ca\left(OH\right)_2}=0,5\left(mol\right)\)
\(\Rightarrow m_{ddHCl}=\dfrac{0,5.36,5}{20\%}=91,25\left(g\right)\)
nFeCl3=0,1mol
nKOH=0,4mol
FeCl3+3KOH→Fe(OH)3↓+3KCl
-Tỉ lệ: 0,11<0,43→KOH dư
nFe(OH)3=nFeCl3=0,1mol
mFe(OH)3=0,1.107=10,7gam
2Fe(OH)3t0→Fe2O3+3H2O
nFe2O3=12nFe(OH)3=12.0,1=0,05mol
mFe2O3=0,05.160=8gam
nKCl=nKOH(pu)=3nFeCl3=0,3mol
nKOH(dư)=0,4−0,3=0,1mol
Vdd=0,1+0,4=0,5l
CMKOH=nv=0,10,5=0,2M
CMKCl=nv=0,30,5=0,6M
a)
$K_2SO_4 + BaCl_2 \to BaSO_4 + 2KCl$
b)
$n_{K_2SO_4} = 0,2.2 = 0,4(mol)$
$n_{BaCl_2} = 0,3.1 = 0,3(mol)$
Ta thấy :
$n_{K_2SO_4} : 1 > n_{BaCl_2} : 1$ nên $K_2SO_4$ dư
$n_{BaSO_4} = n_{BaCl_2} = 0,3(mol)$
$m_{BaSO_4} = 0,3.233 = 69,9(gam)$
c) $n_{K_2SO_4} = 0,4 - 0,3 = 0,1(mol)$
$V_{dd\ sau\ pư} = 0,2 + 0,3 = 0,5(lít)$
$C_{M_{K_2SO_4} } = \dfrac{0,1}{0,5} = 0,2M$
$C_{M_{KCl}} = \dfrac{0,6}{0,5} = 1,2M$
a.250ml=0,25l ; nHCl=0,25.1,5=0,375mol
KOH+HCl->KCl+H2O
1mol 1mol 1mol
0,375 0,375 0,375
VKOh=0,375/2=0,1875l
b.CM KCL=0,375/0,25=1,5M
c.NaOH+HCL=NaCl+H2O
1mol 1mol
0,375 0,375
mdd NaOH=0,375.40.100/10=150g
Ta có: \(n_{KOH}=0,2\cdot2=0,4\left(mol\right)\)
a) PTHH: \(2KOH+H_2SO_4\rightarrow K_2SO_4+2H_2O\)
Theo PTHH: \(n_{H_2SO_4}=\frac{1}{2}n_{KOH}=0,2mol\)
\(\Rightarrow m_{H_2SO_4}=0,2\cdot98=19,6\left(g\right)\) \(\Rightarrow m_{ddH_2SO_4}=\frac{19,2}{20\%}=98\left(g\right)\)
b) Sửa đề: vào 200ml ddA nói trên
PTHH: \(MgCl_2+2KOH\rightarrow Mg\left(OH\right)_2+2KCl\)
Ta có: \(n_{MgCl_2}=0,3\cdot1=0,3\left(mol\right)\)
Xét tỉ lệ: \(\frac{0,3}{1}>\frac{0,4}{2}\) \(\Rightarrow\) KOH phản ứng hết, MgCl2 còn dư
\(\Rightarrow\left\{{}\begin{matrix}n_{KCl}=n_{KOH}=0,4mol\\n_{MgCl_2\left(dư\right)}=0,1mol\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}C_{M_{KCl}}=\frac{0,4}{0,5}=0,8\left(M\right)\\C_{M_{MgCl_2\left(dư\right)}}=\frac{0,1}{0.5}=0,2\left(M\right)\end{matrix}\right.\) (Coi như thể tích dd không đổi)