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a, \(CuCl_2+2NaOH\rightarrow2NaCl+Cu\left(OH\right)_2\)
\(Cu\left(OH\right)_2\underrightarrow{t^o}CuO+H_2O\)
b, \(n_{CuCl_2}=\dfrac{27}{135}=0,2\left(mol\right)\)
Theo PT: \(n_{CuO}=n_{Cu\left(OH\right)_2}=n_{CuCl_2}=0,2\left(mol\right)\)
\(\Rightarrow m_{CuO}=0,2.80=16\left(g\right)\)
c, \(n_{NaOH}=2n_{CuCl_2}=0,4\left(mol\right)\)
\(\Rightarrow C\%_{NaOH}=\dfrac{0,4.40}{200}.100\%=8\%\)
\(a,PTHH:CuCl_2+2NaOH\rightarrow Cu\left(OH\right)_2+2NaCl\\ Cu\left(OH\right)_2\rightarrow^{t^0}CuO+H_2O\\ b,n_{CuCl_2}=n_{Cu\left(OH\right)_2}=n_{CuO}=0,2\left(mol\right)\\ \Rightarrow m_{CuO}=0,2\cdot80=16\left(g\right)\\ c,n_{NaCl}=2n_{CuCl_2}=0,4\left(mol\right)\\ \Rightarrow m_{NaCl}=0,4\cdot58,5=23,4\left(g\right)\\ \Rightarrow C\%_{NaCl}=\dfrac{23,4}{200}\cdot100\%=11,7\%\)
\(n_{CuCl_2}=\dfrac{1,35}{135}=0,01(mol)\\ n_{KOH}=\dfrac{28.10}{100.56}=0,05(mol)\\ a,CuCl_2+2KOH\to Cu(OH)_2\downarrow+2KCl\\ Cu(OH)_2\xrightarrow{t^o}CuO+H_2O\\ \dfrac{n_{CuCl_2}}{1}<\dfrac{n_{KOH}}{2}\Rightarrow KOH\text{ dư}\\ b,n_{CuO}=n_{Cu(OH)_2}=0,01(mol)\\ \Rightarrow m_{CuO}=0,01.80=0,8(g)\)
\(c,n_{KCl}=0,02(mol);n_{KOH(dư)}=0,05-0,01.2=0,03(mol)\\ \Rightarrow m_{Cu(OH)_2}=0,01.98=0,98(g);m_{KCl}=0,02.74,9=1,49(g)\\ \Rightarrow \begin{cases} C\%_{KCl}=\dfrac{1,49}{1,35+28-0,98}.100\%=5,25\%\\ C\%_{KOH(dư)}=\dfrac{0,03.56}{1,35+28-0,98}.100=5,92\% \end{cases}\)
\(n_{CuCl2}=\dfrac{1,35}{135}=0,01\left(mol\right)\)
\(m_{ct}=\dfrac{10.28}{100}=2,8\left(g\right)\)
\(n_{KOH}=\dfrac{2,8}{56}=0,05\left(mol\right)\)
a) Pt : \(CuCl_2+2KOH\rightarrow Cu\left(OH\right)_2+2KCl|\)
1 2 1 2
0,01 0,05 0,01 0,02
\(Cu\left(OH\right)_2\underrightarrow{t^o}CuO+H_2O|\)
1 1 1
0,01 0,01
b) Lập tỉ số so sánh : \(\dfrac{0,01}{1}< \dfrac{0,05}{2}\)
⇒ CuCl2 phản ứng hết , KOH dư
⇒ Tính toán dựa vào số mol của CuCl2
\(n_{CuO}=\dfrac{0,01}{1}=0,01\left(mol\right)\)
⇒ \(m_{CuO}=0,01.80=0,8\left(g\right)\)
c) \(n_{KCl}=\dfrac{0,01.2}{1}=0,02\left(mol\right)\)
⇒ \(m_{KCl}=0,02.74,5=1,49\left(g\right)\)
\(n_{KOH\left(dư\right)}=0,05-\left(0,01.2\right)=0,03\left(mol\right)\)
⇒ \(m_{KOH\left(dư\right)}=0,03.56=1,68\left(g\right)\)
\(m_{ddspu}=1,35+28=29,35\left(g\right)\)
\(C_{KCl}=\dfrac{1,49.100}{29,35}=5,08\)0/0
\(C_{ddKOH\left(dư\right)}=\dfrac{1,68.100}{29,35}=5,72\)0/0
Chúc bạn học tốt
\(n_{NaOH}=\dfrac{20}{40}=0,5\left(mol\right)\)
a) \(CuCl_2+2NaOH\rightarrow Cu\left(OH\right)_2+2NaCl\left(1\right)\)
\(Cu\left(OH\right)_2\xrightarrow[t^o]{}CuO+H_2O\left(2\right)\)
b) \(Pt\left(1\right):n_{Cu\left(OH\right)2}=\dfrac{1}{2}n_{NaOH}=0,25\left(mol\right)\)
\(Pt\left(2\right):n_{Cu\left(OH\right)2}=n_{CuO}=0,25\left(mol\right)\Rightarrow m_{Cu}=0,25.64=16\left(g\right)\)
c) Pt(1) : \(n_{NaOH}=n_{NaCl}=0,5\left(mol\right)\Rightarrow m_{NaCl}=0,5.58,5=29,25\left(g\right)\)
\(n_{CuSO_4}=0,5mol\)
\(n_{KOH}=0,3mol\)
a) \(CuSO_4+2KOH\rightarrow Cu\left(OH\right)_2+K_2SO_4\)
0,5 0,3 0,3 0,3
\(Cu\left(OH\right)_2\underrightarrow{t^O}CuO+H_2O\)
0,3 0,3
b)\(m_{CuO}=0,3\cdot80=24\left(g\right)\)
c) \(m_{K_2SO_4}=0,3\cdot174=52,2\left(g\right)\)