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b)dd B là H2SO4 dư
số mol h2so4 là:
nH2SO4(dư) = 0,1 - 0,02 = 0,08 mol
Nồng độ phần trăm dd B là :
C%H2SO4 =\(\dfrac{0,08.98}{50+200-4,66}.100\%\)≈3,2 %
a) \(n_{H_2SO_4}=\dfrac{50.19,6}{100.98}=0,1\left(mol\right)\)
\(n_{Ba\left(OH\right)_2}=\dfrac{200.17,1}{100.171}=0,2\left(mol\right)\)
PTHH: Ba(OH)2 + H2SO4 --> BaSO4 + 2H2O
Xét \(\dfrac{0,1}{1}< \dfrac{0,2}{1}\) => Ba(OH)2 dư, H2SO4 hết
PTHH: Ba(OH)2 + H2SO4 --> BaSO4 + 2H2O
_______0,1<-----0,1--------->0,1
=> mBaSO4 = 0,1.233 = 23,3 (g)
b) mdd sau pư = 50 + 200 - 23,3 = 226,7 (g)
=> \(C\%=\dfrac{\left(0,2-0,1\right).171}{226,7}.100\%=7,543\%\)
\(n_{Na_2SO_4}=\dfrac{71.20}{100.142}=0,1\left(mol\right)\)
\(n_{BaCl_2}=\dfrac{100.10,4}{100.208}=0,05\left(mol\right)\)
PTHH: \(Na_2SO_4+BaCl_2\rightarrow BaSO_4\downarrow+2NaCl\)
Xét tỉ lệ: \(\dfrac{0,1}{1}>\dfrac{0,05}{1}\) => BaCl2 hết, Na2SO4 dư
PTHH: \(Na_2SO_4+BaCl_2\rightarrow BaSO_4\downarrow+2NaCl\)
0,05<--------0,05---->0,05------->0,1
=> \(\left\{{}\begin{matrix}m_{Na_2SO_4}=\left(0,1-0,05\right).142=7,1\left(g\right)\\m_{NaCl}=0,1.58,5=5,85\left(g\right)\end{matrix}\right.\)
mdd sau pư = 71 + 100 - 0,05.233 = 159,35(g)
=> \(\left\{{}\begin{matrix}C\%\left(Na_2SO_4\right)=\dfrac{7,1}{159,35}.100\%=4,456\%\\C\%\left(NaCl\right)=\dfrac{5,85}{159,35}.100\%=3,67\%\end{matrix}\right.\)
\(a,\left\{{}\begin{matrix}m_{H_2SO_4}=\dfrac{300\cdot9,8\%}{100\%}=29,4\left(g\right)\\m_{BaCl_2}=\dfrac{200\cdot26\%}{100\%}=52\left(g\right)\end{matrix}\right.\\ \Rightarrow\left\{{}\begin{matrix}n_{H_2SO_4}=\dfrac{29,4}{98}=0,3\left(mol\right)\\n_{BaCl_2}=\dfrac{52}{208}=0,25\left(mol\right)\end{matrix}\right.\\ PTHH:H_2SO_4+BaCl_2\rightarrow2HCl+BaSO_4\downarrow\)
Vì \(\dfrac{n_{H_2SO_4}}{1}>\dfrac{n_{BaCl_2}}{1}\) nên sau phản ứng \(H_2SO_4\) dư
\(\Rightarrow n_{BaSO_4}=0,25\left(mol\right)\\ \Rightarrow a=m_{BaSO_4}=0,25\cdot233=58,25\left(g\right)\)
\(b,n_{HCl}=2n_{BaCl_2}=0,5\left(mol\right)\\ \Rightarrow m_{CT_{HCl}}=0,5\cdot36,5=18,25\left(g\right)\\ m_{dd_{HCl}}=300+200-58,25=441,75\left(g\right)\\ \Rightarrow C\%_{HCl}=\dfrac{18,25}{441,75}\cdot100\%\approx4,13\%\)
Cho Ba(OH)2 vào muối Al sẽ có 2TH sau:
TH1: kết tủa Al(OH)3 chưa bị hòa tan
Al3+ + 3OH– → Al(OH)3↓
→ nAl(OH)3 = nAl3+ → nAl(OH)3 = xn + 0,04n
TH2: kết tủa Al(OH)3 bị hòa tan một phần
Al3+ + 3OH– → Al(OH)3↓
(xn + 0,04n)→ 3(xn + 0,04n) (xn + 0,04n)
Al(OH)3 + OH– → AlO2– + 2H2O
0,952 – 3(xn + 0,04n) ←0,952
→ nAl(OH)3 = 4xn + 0,16n – 0,952
C là \(BaSO_4\), D là \(HCl\)
\(a,PTHH:BaCl_2+H_2SO_4\rightarrow BaSO_4\downarrow+2HCl\\ n_{BaCl_2}=\dfrac{31,2}{208}=0,15\left(mol\right)\\ \Rightarrow n_{BaSO_4}=0,15\left(mol\right)\\ \Rightarrow m_{BaSO_4}=0,15\cdot233=34,95\left(g\right)\\ b,n_{HCl}=2n_{BaCl_2}=0,3\left(mol\right)\\ \Rightarrow m_{CT_{HCl}}=0,3\cdot36,5=10,95\left(g\right)\\ m_{dd_{HCl}}=31,2+100-34,95=96,25\left(g\right)\\ \Rightarrow C\%_{HCl}=\dfrac{10,95}{96,25}\cdot100\%\approx11,38\%\)
\(a,n_{Na_2CO_3}=\dfrac{106.10}{100.106}=0,1mol\\ BaCl_2+Na_2CO_3\rightarrow BaCO_3+2NaCl\\ n_{BaCO_3}=n_{Na_2CO_3}=0,1mol\\ m_A=m_{BaCO_3}=0,1.197=19,7g\\ b,n_{NaCl}=0,1.2=0,2mol\\ C_{\%B}=C_{\%NaCl}=\dfrac{0,2.58,5}{100+106-19,7}\cdot100=6,28\%\\ c.BaCO_3\xrightarrow[]{t^0}BaO+CO_2\\ n_{CO_2}=n_{BaCO_3}=0,1mol\\ n_{Ca\left(OH\right)_2}=0,08.1=0,08mol\\ T=\dfrac{0,08}{0,1}=0,8\\ \Rightarrow0,5< T< 1\)
Pứ tạo 2 muối
\(n_{CaCO_3}=a,n_{Ca\left(HCO_3\right)_2}=b\\ CO_2+Ca\left(OH\right)_2\rightarrow CaCO_3+H_2O\\ 2CO_2+Ca\left(OH\right)_2\rightarrow Ca\left(HCO_3\right)_2\\ \Rightarrow\left\{{}\begin{matrix}a+b=0,08\\a+2b=0,1\end{matrix}\right.\\ \Rightarrow a=0,06;b=0,02\\ m_{muối}=0,06.100+0,02.162=9,24g\)
\(a,\left\{{}\begin{matrix}m_{BaCl_2}=\dfrac{100\cdot10,4\%}{100\%}=10,4\left(g\right)\\m_{H_2SO_4}=\dfrac{200\cdot9,8\%}{100\%}=19,6\left(g\right)\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}n_{BaCl_2}=\dfrac{10,4}{208}=0,05\left(mol\right)\\n_{H_2SO_4}=\dfrac{19,6}{98}=0,2\left(mol\right)\end{matrix}\right.\)
\(PTHH:BaCl_2+H_2SO_4\rightarrow BaSO_4\downarrow+2HCl\)
Vì \(\dfrac{n_{BaCl_2}}{1}< \dfrac{n_{H_2SO_4}}{2}\) nên \(H_2SO_4\) dư
\(\Rightarrow n_{BaSO_4}=n_{BaCl_2}=0,05\left(mol\right)\\ \Rightarrow m_{BaSO_4}=0,05\cdot233=11,65\left(g\right)\)
\(b,n_{HCl}=n_{BaSO_4}=0,05\left(mol\right)\\ \Rightarrow m_{CT_{HCl}}=0,05\cdot36,5=1,825\left(g\right)\\ \Rightarrow m_{dd_{HCl}}=100+200-11,65=288,35\left(g\right)\\ \Rightarrow C\%_{HCl}=\dfrac{1,825}{288,35}\cdot100\%\approx0,63\%\)