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a, \(n_{CO_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
PTHH: CO2 + 2KOH → K2CO3 + H2O
Mol: 0,1 0,2 0,1
b, \(C_{M_{ddKOH}}=\dfrac{0,2}{0,1}=2M\)
c, \(m_{K_2CO_3}=0,1.138=13,8\left(g\right)\)
`a)PTHH:`
`2Al + 6HCl -> 2AlCl_3 + 3H_2`
`0,2` `0,6` `0,3` `(mol)`
`n_[Al]=[5,4]/27=0,2(mol)`
`b)V_[H_2]=0,3.22,4=6,72(l)`
`c)m_[dd HCl]=[0,6.36,5]/10 . 100 =219(g)`
\(n_{Fe}=\dfrac{14}{56}=0,25\left(mol\right)\\
pthh:Fe+H_2SO_4\rightarrow FeSO_4+H_2\)
0,25 0,25 0,25
=> \(V_{H_2}=0,25.22,4=5,6\left(l\right)\)
\(m_{FeSO_4}=152.0,25=38\left(g\right)\)
\(pthh:CuO+H_2\underrightarrow{t^o}H_2O+Cu\)
0,25 0,25 0,25
=> \(m_{Cu}=0,25.64=16\left(g\right)\)
nFe = 14/56 =0,25 mol
PTHH : Fe + H2SO4 => FeSO4 + H2 (1)
Theo pt(1) : nH2 = nFe = 0,25 mol
VO2 = 0,25 x 22,4 = 5,6 l
Theo pt(1): nFeSO4 = nFe = 0,25 mol
mFeSO4= 0,25 x 152 = 38 g
PTHH : H2 + CuO => Cu + H2O(2)
theo pt (2) => nH2 = nCu = 0,25 mol
mCu = 0,25 x 64 = 16 g
\(n_{Zn}=\dfrac{3,9}{65}=0,06mol\)
\(Zn+2HCl\rightarrow ZnCl_2+H_2\uparrow\)
0,06 0,12 0,06 0,06
\(V_{H_2}=0,06\cdot22,4=1,344l\)
\(d_{H_2}\)/CO2=\(\dfrac{M_{H_2}}{M_{CO_2}}=\dfrac{2}{44}=\dfrac{1}{22}\)
\(m_{HCl}=0,12\cdot36,5=4,38g\)
\(m_{ZnCl_2}=0,06\cdot136=8,16g\)
a) Zn + 2HCl ---> ZnCl2 + H2
b) nZn = 3,9:65= 0,06 ( mol)
theo pt , nH2 =nZn= 0,06 (mol)
=> VH2(ĐKTC) = 0,06.22,4=1,344(l)
H2/CO2 = MH2/MCO2 =2/44=1/22
c) theo pt nHCl = 2nZn = 2.0,06=0,12(mol)
=> mHCl= 0,12 . 36,5=4,38(g)
d) theo pt , nZnCl2= nZn = 0,06(mol)
=> m ZnCl2 = 0,06.136=8,16 (g)
a, \(n_{Zn}=\dfrac{6,5}{65}=0,1\left(mol\right)\)
PT: \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
____0,1_____0,2______0,1_____0,1 (mol)
\(V_{H_2}=0,1.24,79=2,479\left(l\right)\)
\(m_{ZnCl_2}=0,1.136=13,6\left(g\right)\)
b, \(C_{M_{HCl}}=\dfrac{0,2}{0,1}=1\left(M\right)\)
c, \(n_{CuO}=\dfrac{12}{80}=0,15\left(mol\right)\)
PT: \(CuO+H_2\underrightarrow{t^o}Cu+H_2O\)
Xét tỉ lệ: \(\dfrac{0,15}{1}>\dfrac{0,1}{1}\), ta được CuO dư.
Theo PT: \(n_{CuO\left(pư\right)}=n_{Cu}=n_{H_2}=0,1\left(mol\right)\Rightarrow n_{CuO\left(dư\right)}=0,05\left(mol\right)\)
⇒ m chất rắn = mCuO (dư) + mCu = 0,05.80 + 0,1.64 = 10,4 (g)
\(n_{Zn}=\dfrac{6,5}{65}=0,1\left(mol\right)\\ a,PTHH:Zn+2HCl\rightarrow ZnCl_2+H_2\\ b,n_{ZnCl_2}=n_{H_2}=n_{Zn}=0,1\left(mol\right)\\ m_{muối}=m_{ZnCl_2}=0,1.136=13,6\left(g\right)\\ V_{khí\left(đktc\right)}=V_{H_2\left(đkc\right)}=0,1.24,79=2,479\left(l\right)\\ c,n_{CuO}=\dfrac{7,6}{80}=0,095\left(mol\right)\\ PTHH:CuO+H_2\rightarrow\left(t^o\right)Cu+H_2O\\ Vì:\dfrac{0,095}{1}< \dfrac{0,1}{1}\Rightarrow H_2dư\\ n_{Cu}=n_{CuO}=0,095\left(mol\right)\\ m_{Cu}=0,095.64=6,08\left(g\right)\)
\(n_{Fe}=\dfrac{11,2}{56}=0,2\left(mol\right)\\a, PTHH:Fe+H_2SO_4\rightarrow FeSO_4+H_2\\ b,n_{H_2}=n_{H_2SO_4}=n_{Fe}=0,2\left(mol\right)\\ V_{H_2\left(đkc\right)}=0,2.24,79=4,958\left(l\right)\\ c,C_{MddH_2SO_4}=\dfrac{0,2}{0,4}=0,5\left(M\right)\)
a, \(CaCO_3+2HCl\rightarrow CaCl_2+CO_2+H_2O\)
b, \(n_{CaCO_3}=\dfrac{10}{100}=0,1\left(mol\right)\Rightarrow n_{CO_2}=n_{CaCO_3}=0,1\left(mol\right)\)
\(\Rightarrow V_{CO_2}=0,1.22,4=2,24\left(l\right)\)
c, \(n_{HCl}=2n_{CaCO_3}=0,2\left(mol\right)\Rightarrow C_{M_{HCl}}=\dfrac{0,2}{0,1}=2\left(M\right)\)
d, \(m_{NaOH}=550.10\%=55\left(g\right)\Rightarrow n_{NaOH}=\dfrac{55}{40}=1,375\left(mol\right)\)
\(\Rightarrow\dfrac{n_{NaOH}}{n_{CO_2}}=\dfrac{1,375}{0,1}=13,75>2\)
→ Pư tạo muối trung hòa Na2CO3.
PT: \(CO_2+2NaOH\rightarrow Na_2CO_3+H_2O\)
\(n_{Na_2CO_3}=n_{CO_2}=0,1\left(mol\right)\Rightarrow m_{Na_2CO_3}=0,1.106=10,6\left(g\right)\)