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![](https://rs.olm.vn/images/avt/0.png?1311)
\(m_{C_2H_5OH\left(nguyên.chất\right)}=\dfrac{0,5.30}{100}=0,15l=150ml\)
\(\rightarrow m_{H_2O}=500-150=350ml\)
\(m_{C_2H_5OH}=150.0,8=120g\)
\(m_{H_2O}=350.1=350g\)
\(\left\{{}\begin{matrix}n_{C_2H_5OH}=\dfrac{120}{46}=2,6mol\\n_{H_2O}=\dfrac{350}{18}=19,44mol\end{matrix}\right.\)
\(2C_2H_5OH+2Na\rightarrow2C_2H_5ONa+H_2\)
2,6 1,3 ( mol )
\(2Na+2H_2O\rightarrow2NaOH+H_2\)
19,44 9,72 ( mol )
\(V_{H_2}=\left(1,3+9,72\right).22,4=246,848l\)
\(0,5lít=500ml\)
\(m_{C_2H_5OH}=500.0,8=400g\)
\(n_{C_2H_5OH}=\dfrac{400}{46}=8,69mol\)
\(n_{Na}=\dfrac{300}{23}=12,04mol\)
\(2C_2H_5OH+2Na\rightarrow2C_2H_5ONa+H_2\)
8,69 < 12,04 ( mol )
8,69 8,69 ( mol )
\(V_{H_2}=8,96.22,4=200,704l\)
từ 36g glucozo lên men rượu thì thu đc bao nhieu lít đ rượu 5,75 độ,biết hiệu suất pứ=80%,d rượu=0,8
![](https://rs.olm.vn/images/avt/0.png?1311)
\(n_{C_6H_{12}O_6}=\dfrac{36}{180}=0,2\left(mol\right)\)
PTHH: C6H12O6 \(\xrightarrow{ \text{men rượu} } \) 2CO2 + 2C2H5OH
0,2 ----------------------------> 0,4
\(\rightarrow m_{C_2H_5OH}=0,4.80\%.46=14,72\left(g\right)\\ \rightarrow V_{C_2H_5OH}=\dfrac{14,72}{0,8}=18,4\left(g\right)\\ \rightarrow V_{ddC_2H_5OH}=\dfrac{18,4}{5,75\%}=320\left(ml\right)\)
\(n_{C_6H_{12}O_6}=\dfrac{36}{180}=0,2mol\)
\(C_6H_{12}O_6\underrightarrow{lênmen}2C_5H_{12}OH+2CO_2\)
0,2 0,4
Thực tế: \(n_{C_5H_{12}OH}=0,4\cdot80\%=0,32mol\)
\(\Rightarrow m_{rượu}\)(nguyên chất)=\(0,32\cdot46=14,72g\)
\(V_{rượu}=\dfrac{m}{D}=\dfrac{14,72}{0,8}=18,4ml\)
Độ rượu: \(5,75^o=\dfrac{18,4}{V_{ddrượu}}\cdot100\%\Rightarrow V_{ddrượu}=320ml\)
![](https://rs.olm.vn/images/avt/0.png?1311)
Đáp án: A
Vì dung dịch rượu gồm rượu etylic và nước nên ta gọi:
n H 2 O = x m o l và n C 2 H 5 O H = y m o l
PTHH:
2 N a + 2 H 2 O → 2 N a O H + H 2 ↑ ( 1 )
x mol → 0,5.x mol
2 N a + 2 C 2 H 5 O H → 2 C 2 H 5 O N a + H 2 ↑
y mol → 0,5.y mol
Ta có hệ phương trình:
18 x + 46 y = 10 , 1 0 , 5 x + 0 , 5 y = 0 , 125 ⇒ x = 0 , 05 y = 0 , 2
V C 2 H 5 O H nguyên chất = m D = 0 , 2 . 46 0 , 8 = 11 , 5 m l
V H 2 O = m D = 10 , 1 - 9 , 2 1 = 0 , 9 m l
=> V d d r ư ợ u = V H 2 O + V C 2 H 5 O H = 0,9 + 11,5 = 12,4 ml
=> Độ rượu D 0 = V C 2 H 5 O H V d d r u o u . 100 = 11 , 5 12 , 4 . 100 = 92 , 74 0
![](https://rs.olm.vn/images/avt/0.png?1311)
nH2 = 85,12 : 22,4 = 3,8 (mol) ; nH2O = VH2O.D = 108 (g) => nH2O = 108/18 = 6 (mol)
PTHH:
2Na + 2C2H5OH → 2C2H5ONa + H2↑
x → 0,5x (mol)
2Na + 2H2O → 2NaOH + H2↑
6 → 3 (mol)
Ta có: nH2 = 0,5x + 3 = 3,8
=> x = 1,6 (mol) = nC2H5OH
mC2H5OH = 1,6.46 = 73,6 (g)
![](https://rs.olm.vn/images/avt/0.png?1311)
Gọi \(\left\{{}\begin{matrix}n_{C_2H_5OH}=a\left(mol\right)\\n_{H_2O}=b\left(mol\right)\end{matrix}\right.\)
\(n_{H_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\)
PTHH:
2C2H5OH + 2Na ---> 2C2H5ONa + H2
a --------------------------------------------> 0,5a
2H2O + 2Na ---> 2NaOH + H2
b --------------------------------> 0,5b
Hệ pt \(\left\{{}\begin{matrix}46a+18b=20,2\\0,5a+0,5b=0,25\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,4\left(mol\right)\\b=0,1\left(mol\right)\end{matrix}\right.\)
\(\rightarrow\left\{{}\begin{matrix}m_{C_2H_5OH}=0,4.46=18,4\left(g\right)\\m_{H_2O}=0,1.18=1,8\left(g\right)\end{matrix}\right.\rightarrow\left\{{}\begin{matrix}V_{C_2H_5OH}=\dfrac{18,4}{0,8}=23\left(ml\right)\\V_{H_2O}=\dfrac{1,8}{1}=1,8\left(ml\right)\end{matrix}\right.\)
=> Độ rượu là: \(\dfrac{23}{23+1,8}=92,74^o\)
![](https://rs.olm.vn/images/avt/0.png?1311)
nC2H5OH=0,3(mol)
PTHH: C2H5OH + Na -> C2H5ONa + 1/2 H2
nH2=nC2H5OH/2=0,3/2=0,15(mol)
=>V(H2,đktc)=0,15.22,4=3,36(l)
![](https://rs.olm.vn/images/avt/0.png?1311)
a, \(C_2H_6O+3O_2\underrightarrow{t^o}2CO_2+3H_2O\)
b, \(n_{C_2H_6O}=\dfrac{23}{46}=0,5\left(mol\right)\)
Theo PT: \(n_{O_2}=3n_{C_2H_6O}=1,5\left(mol\right)\)
\(\Rightarrow V_{O_2}=1,5.22,4=33,6\left(l\right)\)
c, \(V_{C_2H_6O}=\dfrac{100.46}{100}=46\left(ml\right)\)
\(\Rightarrow m_{C_2H_6O}=46.0,8=36,8\left(g\right)\)
\(\Rightarrow n_{C_2H_6O}=\dfrac{36,8}{46}=0,8\left(mol\right)\)
PT: \(C_2H_5OH+Na\rightarrow C_2H_5ONa+\dfrac{1}{2}H_2\)
Theo PT: \(n_{H_2}=\dfrac{1}{2}n_{C_2H_5ONa}=0,4\left(mol\right)\)
\(\Rightarrow V_{H_2}=0,4.22,4=8,96\left(l\right)\)
\(V_{C_2H_5OH\left(nguyên.chất\right)}=\dfrac{0,5.30}{100}=0,15l\)
\(0,15lít=150ml\)
\(V_{H_2O}=500-150=350ml\)
\(m_{C_2H_5OH\left(nguyên.chất\right)}=150.0,8=120g\)
\(m_{H_2O}=350.1=350g\)
\(n_{C_2H_5OH}=\dfrac{120}{46}=2,6mol\)
\(n_{H_2O}=\dfrac{350}{18}=19,44mol\)
\(2C_2H_5OH+2Na\rightarrow2C_2H_5ONa+H_2\)
2,6 1,3 ( mol )
\(2Na+2H_2O\rightarrow2NaOH+H_2\)
19,44 9,72 ( mol )
\(V_{H_2}=\left(1,3+9,72\right).22,4=246,848l\)