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a, \(n_{Zn}=\dfrac{19,5}{65}=0,3\left(mol\right)\)
\(m_{HCl}=200.14,6\%=29,2\left(g\right)\Rightarrow n_{HCl}=\dfrac{29,2}{36,5}=0,8\left(mol\right)\)
PT: \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
Xét tỉ lệ: \(\dfrac{0,3}{1}< \dfrac{0,8}{2}\), ta được HCl dư.
Theo PT: \(n_{H_2}=n_{Zn}=0,3\left(mol\right)\Rightarrow V_{H_2}=0,3.22,4=6,72\left(l\right)\)
b, \(n_{ZnCl_2}=n_{Zn}=0,3\left(mol\right)\Rightarrow m_{ZnCl_2}=0,3.136=40,8\left(g\right)\)
c, \(n_{HCl\left(pư\right)}=2n_{Zn}=0,6\left(mol\right)\Rightarrow n_{HCl\left(dư\right)}=0,2\left(mol\right)\)
Ta có: m dd sau pư = 19,5 + 200 - 0,3.2 = 218,9 (g)
\(\Rightarrow\left\{{}\begin{matrix}C\%_{HCl}=\dfrac{0,2.36,5}{218,9}.100\%\approx3,33\%\\C\%_{ZnCl_2}=\dfrac{40,8}{218,9}.100\%\approx18,64\%\end{matrix}\right.\)
\(a)n_{Zn}=\dfrac{19,5}{65}=0,3mol\\ n_{HCl}=\dfrac{200.14,6}{100.36,5}=0,8mol\\ Zn+2HCl\rightarrow ZnCl_2+H_2\\ \Rightarrow\dfrac{0,3}{1}< \dfrac{0,8}{2}\Rightarrow HCl.dư\\ n_{H_2}=n_{ZnCl_2}=n_{Zn}=0,3mol\\ V_{H_2}=0,3.22,4=6,72l\\ b)m_{ZnCl_2}=0,3.136=40,8g\\ c)n_{HCl.pư}=0,3.2=0,6mol\\ C_{\%ZnCl_2}=\dfrac{40,8}{200+19,5-0,3.2}\cdot100=18,64\%\\ C_{\%HCl.dư}=\dfrac{\left(0,8-0,6\right).36,5}{200+19,5-0,3.2}\cdot100=3,33\%\)
a) Fe + 2HCl --> FeCl2 + H2
b) \(n_{Fe}=\dfrac{22,4}{56}=0,4\left(mol\right)\)
PTHH: Fe + 2HCl --> FeCl2 + H2
_____0,4--->0,8------>0,4--->0,4
=> VH2 = 0,4.22,4 = 8,96(l)
c) mHCl = 0,8.36,5 = 29,2 (g)
=> \(m_{dd\left(HCl\right)}=\dfrac{29,2.100}{7,3}=400\left(g\right)\)
mdd (sau pư) = 22,4 + 400 - 0,4.2 = 421,6 (g)
=> \(C\%\left(FeCl_2\right)=\dfrac{127.0,4}{421,6}.100\%=12,05\%\)
\(n_{Al}=\dfrac{10,8}{27}=0,4(mol)\\ a,2Al+3H_2SO_4\to Al_2(SO_4)_3+3H_2\\ \Rightarrow n_{H_2}=n_{H_2SO_4}=0,6(mol);n_{Al_2(SO_4)_3}=0,2(mol)\\ b,V_{H_2}=0,6.22,4=13,44(l)\\ c,m_{dd_{H_2SO_4}}=\dfrac{0,6.98}{9,8\%}=600(g)\\ \Rightarrow C\%_{Al_2(SO_4)_3}=\dfrac{0,2.342}{10,8+600-0,6.2}.100\%=11,22\%\)
\(a,PTHH:2Na+2H_2O\rightarrow2NaOH+H_2\\ n_{Na}=\dfrac{2,3}{23}=0,1mol\\ n_{NaOH}=0,1.2=0,2mol\\ C_{M_{NaOH}}=\dfrac{0,2}{0,5}=0,4M\\ b,oxit.kl:RO\\ n_{RO}=\dfrac{2,4}{R+16}mol\\ n_{HCl}=\dfrac{30.7,3}{100.36,5}=0,06mol\\ RO+2HCl\rightarrow RCl_2+H_2O\\ \Rightarrow\dfrac{2,4}{R+16}=0,06:2\\ \Leftrightarrow R=64,Cu\)
\(a.n_{Mg}=\dfrac{4,8}{24}=0,2\left(mol\right)\\ n_{HCl}=0,2.1,5=0,3\left(mol\right)\\ Mg+2HCl\rightarrow MgCl_2+H_2\\ Vì:\dfrac{0,3}{2}< \dfrac{0,2}{1}\\ \Rightarrow Mgdư\\ n_{H_2}=n_{MgCl_2}=\dfrac{0,3}{2}=0,15\left(mol\right)\\ V_{H_2\left(đktc\right)}=0,15.22,4=3,36\left(l\right)\\ b.V_{ddsau}=V_{ddHCl}=0,2\left(l\right)\\ C_{MddMgCl_2}=\dfrac{0,15}{0,2}=0,75\left(M\right)\)
a) Mg + 2HCl → MgCl2 + H2
b) nMg =\(\dfrac{14,4}{24}\)=0,6 mol => nH2 = nMg= 0,6 mol <=> V H2 = 0,6.22,4 = 13,44 lít
c) nHCl = 2nMg = 1,2mol => mHCl = 1,2.36,5 = 43,8 gam
=> C%HCl = \(\dfrac{43,8}{200}.100\) =21,9%
a) $2Al +3 H_2SO_4 \to Al_2(SO_4)_3 + 3H_2$
b) $n_{Al} = \dfrac{5,4}{27} = 0,2(mol)$
Theo PTHH : $n_{H_2} = \dfrac{3}{2}n_{H_2} = 0,3(mol)$
$V_{H_2} = 0,3.22,4 = 6,72(lít)$
c) $n_{H_2SO_4} = n_{H_2} = 0,3(mol)$
$\Rightarrow m_{dd\ H_2SO_4} = \dfrac{0,3.98}{19,6\%} = 150(gam)$
$\Rightarrow m_{dd\ sau\ pư} = 5,4 + 150 - 0,3.2 = 154,8(gam)$
$C\%_{Al_2(SO_4)_3} = \dfrac{0,1.342}{154,8}.100\% = 22,09\%$
\(n_{Al}=\dfrac{5,4}{27}=0,2(mol)\\ a,PTHH:2Al+3H_2SO_4\to Al_2(SO_4)_3+3H_2\\ b,n_{H_2}=1,5.n_{Al}=0,3(mol)\\ \Rightarrow V_{H_2}=0,3.22,4=6,72(l)\\ c,n_{H_2SO_4}=n_{H_2}=0,3(mol)\\ \Rightarrow m_{dd_{H_2SO_4}}=\dfrac{0,3.98}{19,6\%}=150(g)\\ n_{Al_2(SO_4)_3}=0,5.n_{Al}=0,1(mol)\\ \Rightarrow C\%_{Al_2(SO_4)_3}=\dfrac{0,1.342}{5,4+150-0,3.2}.100\%=22,09\%\)
a, \(CaO+H_2O\rightarrow Ca\left(OH\right)_2\)
b, \(n_{CaO}=\dfrac{11,2}{56}=0,2\left(mol\right)\)
Theo PT: \(n_{Ca\left(OH\right)_2}=n_{CaO}=0,2\left(mol\right)\Rightarrow C_{M_{Ca\left(OH\right)_2}}=\dfrac{0,2}{0,2}=1\left(M\right)\)
c, \(Ca\left(OH\right)_2+H_2SO_4\rightarrow CaSO_4+2H_2O\)
Theo PT: \(n_{H_2SO_4}=n_{Ca\left(OH\right)_2}=0,2\left(mol\right)\)
\(\Rightarrow m_{ddH_2SO_4}=\dfrac{0,2.98}{15\%}=\dfrac{392}{3}\left(g\right)\)
\(\Rightarrow V_{ddH_2SO_4}=\dfrac{\dfrac{392}{3}}{1,05}\approx124,44\left(ml\right)\)
PTHH: \(Mg+2HCl\rightarrow MgCl_2+H_2\uparrow\)
a+b+c) Ta có: \(n_{HCl}=\dfrac{18,25}{36,5}=0,5\left(mol\right)\)
\(\Rightarrow n_{H_2}=0,25\left(mol\right)=n_{MgCl_2}\) \(\Rightarrow\left\{{}\begin{matrix}m_{MgCl_2}=0,25\cdot95=23,75\left(g\right)\\V_{H_2}=0,25\cdot22,4=5,6\left(l\right)\end{matrix}\right.\)
d) PTHH: \(CuO+H_2\xrightarrow[]{t^o}Cu+H_2O\)
Theo PTHH: \(n_{Cu}=n_{H_2}=0,25\left(mol\right)\) \(\Rightarrow m_{Cu}=0,25\cdot64=16\left(g\right)\)
Ta có: \(n_{Na}=\dfrac{2,3}{23}=0,1\left(mol\right)\)
a. PTHH: 2Na + 2H2O ---> 2NaOH + H2↑
b. Ta có: \(n_{H_2O}=\dfrac{97,8}{18}=5,43\left(mol\right)\)
Ta thấy: \(\dfrac{0,1}{2}< \dfrac{5,43}{2}\)
=> H2O dư.
Theo PT: \(n_{H_2}=\dfrac{1}{2}.n_{Na}=\dfrac{1}{2}.0,1=0,05\left(mol\right)\)
=> \(V_{H_2}=0,05.22,4=1,12\left(lít\right)\)
c. Ta có: \(m_{dd_{NaOH}}=2,3+97,8=100,1\left(g\right)\)
Theo PT: \(n_{NaOH}=n_{Na}=0,1\left(mol\right)\)
=> \(m_{NaOH}=0,1.40=4\left(g\right)\)
=> \(C_{\%_{NaOH}}=\dfrac{4}{100,1}.100\%=3,996\%\)