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Đổi 6,72m3 = 6720dm3 = 6720 lít
Ta có: \(n_{Cl_2}=\dfrac{6720}{71}\left(mol\right)\)
PTHH: \(2NaCl+2H_2O\xrightarrow[có.màng.ngăn]{điện.phân}Cl_2+H_2+2NaOH\)
Theo PT: \(n_{NaCl}=2.n_{Cl_2}=2.\dfrac{6720}{71}=\dfrac{13440}{71}\left(mol\right)\)
\(\Rightarrow m_{NaCl}=\dfrac{13440}{71}.58,5=11073,80282\left(g\right)\)
\(2NaCl+2H_2O\rightarrow2NaOH+Cl_2+H_2\\ n_{NaCl}=\dfrac{117}{58,5}=2\left(mol\right)\\n_{NaOH}=n_{NaCl}=2\left(mol\right)\\ n_{Cl_2}=\dfrac{1}{2}n_{NaCl}=1\left(mol\right)\\ VìH=80\%\\ \Rightarrow m_{NaOH}=2.40.80\%=64\left(g\right)\\ \Rightarrow V_{Cl_2}=1.22,4.80\%=17,92\left(m^3\right)\)
\(n_{KClO_3}=\dfrac{24,5}{122,5}=0,2\left(mol\right)\\ 2KClO_3\underrightarrow{^{to}}2KCl+3O_2\\ n_{O_2\left(LT\right)}=\dfrac{3}{2}.0,2=0,3\left(mol\right)\\ Vì:H=90\%\Rightarrow n_{O_2\left(TT\right)}=90\%.0,3=0,27\left(mol\right)\\ V_{O_2\left(đktc,thực.tế\right)}=0,27.22,4=6,048\left(l\right)\)
mC2H5OH(bd) = 0,8.23 = 18,4 (g)
=> \(n_{C_2H_5OH\left(bd\right)}=\dfrac{18,4}{46}=0,4\left(mol\right)\)
=> \(n_{C_2H_5OH\left(pư\right)}=\dfrac{0,4.75}{100}=0,3\left(mol\right)\)
PTHH: C2H5OH --H2SO4,170oC--> C2H4 + H2O
0,3------------------------->0,3
=> VC2H4 = 0,3.22,4 = 6,72 (l)
Câu 1 :
\(n_C = \dfrac{1 000 000.92\%}{12} = \dfrac{230000}{3}(mol)\\ \Rightarrow n_{CO} = n_C.H\% = \dfrac{230000}{3}.85\% = \dfrac{195500}{3}(mol) \\ V_{CO} = \dfrac{195500}{3}.22,4 = 1459733,33(lít)\)
Câu 2 :
\(n_{C\ pư} = n_{CO} = \dfrac{1428.1000}{22,4} = 63750(mol)\\ n_{C\ đã\ dùng} = \dfrac{63750}{80\%} = 79687,5(mol)\\ m_{than} = \dfrac{m_C}{92\%} = \dfrac{79687,5.12}{92\%} = 1039402,1(gam)\)
\(n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\\ n_{CuO}=\dfrac{16}{80}=0,2\left(mol\right)\\ CuO+H_2\underrightarrow{^{to}}Cu+H_2O\\ Vì:\dfrac{0,3}{1}>\dfrac{0,2}{1}\\ \Rightarrow H_2dư\\ n_{Cu\left(LT\right)}=n_{CuO}=0,2\left(mol\right)\\ n_{Cu\left(TT\right)}=\dfrac{8,96}{64}=0,14\left(mol\right)\\ H=\dfrac{0,14}{0,2}.100=70\%\)
2NaCl + 2H2O điện phân dd có màng ngăn --> 2NaOH + Cl2 + H2
nCl2 =\(\dfrac{8,96}{22,4}\)= 0,4 mol . Hiệu suất phản ứng = 80% => nNaCl = \(\dfrac{0,4.2}{80\%}\)=1 mol
=> mNaCl = 1.58,5 = 58,5 gam
2KMnO4-to>K2MnO4+MnO2+O2
1,2-------------------------------------0,6 mol
n O2=13,44\22,4=0,6 mol
H =75%
=>m KMnO4 tt= 1,2.158 .100\75=252,8g
\(n_{O_2}=\dfrac{13,44}{22,4}=0,6\left(mol\right)\)
PTHH: 2KMnO4 ---to→ K2MnO4 + MnO2 + O2
Mol: 1,2 0,6
\(m_{KMnO_4\left(lt\right)}=1,2.158=189,6\left(g\right)\Rightarrow m_{KMnO_4\left(tt\right)}=\dfrac{189,6}{75}.100=252,8\left(g\right)\)
Đổi 6,72m3 = 6720dm3 = 6720 lít
Ta có: \(n_{Cl_2}=\dfrac{6720}{71}\left(mol\right)\)
PTHH: \(2NaCl+2H_2O\xrightarrow[có.màng.ngăn]{điện.phân}Cl_2+H_2+2NaOH\)
Theo PT: \(n_{NaCl}=2.n_{Cl_2}=2.\dfrac{6720}{71}=\dfrac{13440}{71}\left(mol\right)\)
\(\Rightarrow m_{NaCl}=\dfrac{13440}{71}.58,5=11073,80282\left(g\right)\)
Mà hiệu suất là 80%, nên:
\(m_{NaCl_{PỨ}}=11073,80282.\dfrac{80\%}{100\%}\approx8859\left(g\right)\)