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\(a,PTHH:Zn+2HCl\rightarrow ZnCl_2+H_2\\ b,n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\\ n_{HCl}=2\cdot0,15=0,3\left(mol\right)\)
Vì \(\dfrac{n_{Zn}}{1}>\dfrac{n_{HCl}}{2}\) nên sau p/ứ Zn dư
\(\Rightarrow n_{Zn}=\dfrac{1}{2}n_{HCl}=0,15\left(mol\right)\\ \Rightarrow m_{Zn}=0,15\cdot65=9,75\\ \Rightarrow m_{Zn\left(dư\right)}=13-9,75=3,25\left(g\right)\\ c,n_{H_2}=n_{Zn}=0,15\left(mol\right)\\ \Rightarrow V_{H_2}=0,15\cdot22,4=3,36\left(l\right)\)
\(n_{Cu}=\dfrac{32}{64}=0,5\left(mol\right);n_{O_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\\ PTHH:2Cu+O_2\rightarrow2CuO\\ TL:....2.....1.....2\\ BR:....0,2......0,1.....0,2\left(mol\right)\)
Vì \(\dfrac{n_{Cu}}{2}>\dfrac{n_{O_2}}{1}\) nên sau p/ứ Cu dư, O2 hết
\(a,m_{CuO}=0,2\cdot80=16\left(g\right)\)
\(m_{HCl}=\dfrac{200\cdot14,6\%}{100\%}=29,2\left(g\right)\\ \Rightarrow n_{HCl}=\dfrac{29,2}{36,5}=0,8\left(mol\right)\\ PTHH:CuO+2HCl\rightarrow CuCl_2+H_2O\\ TL:....1.....2.....1.....1\\ BR:....0,2.....0,4.....0,2.....0,2\left(mol\right)\)
Vì \(\dfrac{n_{CuO}}{1}< \dfrac{n_{HCl}}{2}\) nên sau p/ứ HCl dư, CuO hết
\(\Rightarrow n_{HCl\left(dư\right)}=0,8-0,4=0,4\left(mol\right)\\ \Rightarrow m_{HCl\left(dư\right)}=14,6\left(g\right)\)
\(m_{CuCl_2}=0,2\cdot135=27\left(g\right)\\ m_{HCl}=0,4\cdot36,5=14,6\left(g\right)\\ m_{CuO}=16\left(g\right)\\ m_{H_2O}=0,2\cdot18=3,6\left(g\right)\\ \Rightarrow m_{dd_{CuCl_2}}=16+14,6-3,6=27\left(g\right)\)
Vậy \(C\%_{dd_{CuCl_2}}=\dfrac{27}{200}\cdot100\%=13,5\%\)
\(n_{Fe_2O_3}=\dfrac{8}{160}=0,05\left(mol\right)\)
PTHH: Fe2O3 + 3H2SO4 --> Fe2(SO4)3 + 3H2O
______0,05------>0,15--------->0,05
=> mH2SO4 = 0,15.98 = 14,7(g)
=> \(C\%\left(H_2SO_4\right)=\dfrac{14,7}{100}.100\%=14,7\%\)
\(C\%\left(Fe_2\left(SO_4\right)_3\right)=\dfrac{0,05.400}{8+100}.100\%=18,52\%\)
PTHH: Fe2(SO4)3 + 6NaOH --> 2Fe(OH)3\(\downarrow\) + 3Na2SO4
________0,05----------------------->0,1
=> mFe(OH)3 = 0,1.107=10,7(g)
lượng oxit thu được bằng dung dịch HCl 2M thì phải dùng bao nhiêu ml dung dịch ?
Bài 3 :
\(n_{Fe\left(OH\right)3}=\dfrac{21,4}{107}=0,2\left(mol\right)\)
a) Pt : \(2Fe\left(OH\right)_3\underrightarrow{t^o}Fe_2O_3+3H_2O|\)
2 1 3
0,2 0,1
b) \(n_{Fe2O3}=\dfrac{0,2.1}{2}=0,1\left(mol\right)\)
⇒ \(m_{Fe2O3}=0,1.160=16\left(g\right)\)
c) Pt : \(Fe_2O_3+6HCl\rightarrow2FeCl_3+3H_2O|\)
1 6 2 3
0,1 0,6
\(n_{HCl}=\dfrac{0,1.6}{1}=0,6\left(mol\right)\)
\(V_{ddHCl}=\dfrac{0,6}{2}=0,3\left(l\right)=300\left(ml\right)\)
Chúc bạn học tốt
500ml = 0,5l
\(n_{HCl}=0,2.0,5=0,1\left(mol\right)\)
a) Pt : \(Fe+2HCl\rightarrow FeCl_2+H_2|\)
1 2 1 1
0,05 0,1 0,05 0,05
b) \(n_{Fe}=\dfrac{0,1.1}{2}=0,05\left(mol\right)\)
⇒ \(m_{Fe}=0,05.56=2,8\left(g\right)\)
c) \(n_{H2}=\dfrac{0,1.1}{2}=0,05\left(mol\right)\)
\(V_{H2\left(dktc\right)}=0,05.22,4=1,12\left(l\right)\)
d) \(n_{FeCl2}=\dfrac{0,05.1}{1}=0,05\left(mol\right)\)
⇒ \(m_{FeCl2}=0,05.127=6,35\left(g\right)\)
Chúc bạn học tốt
nH2 \(\approx\)0,2 (mol)
Mg + 2HCl \(\rightarrow\) MgCl2 + H2 (1)
0,2 <------------ 0,2 <----- 0,2 (mol)
MgO + 2HCl \(\rightarrow\) MgCl2 + H2O (2)
b) %mMg = \(\frac{0,2.24}{8,8}\) . 100% =54,55%
%mMgO = 45,45%
c) mMgO = 8,8 - 0,2 . 24 = 4(g)
=> nMgO=0,1 (mol)
Theo pt(2) nMgCl2 = nMg = 0,1 (mol)
=> \(\Sigma n_{MgCl_2}\) = 0,2 + 0,1 = 0,3 (mol)
mmuối = 0,3 . 95 = 28,5 (g)
PTHH: \(Fe_3O_4+8HCl\rightarrow FeCl_2+2FeCl_3+4H_2O\)
Ta có: \(\left\{{}\begin{matrix}n_{Fe_3O_4}=\dfrac{23,2}{232}=0,1\left(mol\right)\\n_{HCl}=\dfrac{300\cdot3,65\%}{36,5}=0,3\left(mol\right)\end{matrix}\right.\)
Xét tỉ lệ: \(\dfrac{0,1}{1}>\dfrac{0,3}{8}\) \(\Rightarrow\) Fe3O4 còn dư, HCl p/ứ hết
\(\Rightarrow\left\{{}\begin{matrix}n_{Fe_3O_4\left(dư\right)}=0,0625\left(mol\right)\\n_{FeCl_2}=0,0375\left(mol\right)\\m_{FeCl_3}=0,075\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{Fe_3O_4\left(dư\right)}=0,0625\cdot232=14,5\left(g\right)\\m_{muối}=0,0375\cdot127+0,075\cdot162,5=16,95\left(g\right)\end{matrix}\right.\)
nFe3O4= 23,2/232=0,1(mol); nHCl = (300.3,65%)/36,5= 0,3(mol)
a) PTHH: Fe3O4 + 8 HCl -> 2 FeCl3 + FeCl2 + 4 H2O
b) Ta có: 0,3/8 < 0,1/1
=> Fe3O4 dư, HCl hết, tính theo nHCl.
=> nFe3O4(p.ứ)= nFeCl2= nHCl/8=0,3/8= 0,0375(mol)
=> mFe3O4(dư)= (0,1- 0,0375).232=14,5(g)
c) nFeCl3= 2/8. 0,3= 0,075(mol)
=> mFeCl3= 0,075.162,5=12,1875(g)
mFeCl2= 0,0375. 127=4,7625(g)
=>m(muối)= 12,1875+ 4,7625= 16,95(g)