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\(a) n_{K_2CO_3} = \dfrac{5,52}{138}=0,04(mol)\\ K_2CO_3 + 2CH_3COOH \to 2CH_3COOK + CO_2 + H_2O\\ n_{CH_3COOH} = 2n_{K_2CO_3} = 0,08(mol)\\ m_{dd\ CH_3COOH} = \dfrac{0,08.60}{12\%} = 40(gam)\\ b) CO_2 + Ca(OH)_2 \to CaCO_3 + H_2O\\ n_{CaCO_3} = n_{CO_2} = n_{K_2CO_3} = 0,04(mol)\\ m_{CaCO_3} = 0,04.100 = 4(gam)\)
Sửa đề: 44,4 → 4,44
a, \(CH_3COOH+Na\rightarrow CH_3COONa+\dfrac{1}{2}H_2\)
\(C_nH_{2n+1}COOH+Na\rightarrow C_nH_{2n+1}COONa+\dfrac{1}{2}H_2\)
b, Gọi: nCH3COOH = 2x (mol) ⇒ nCnH2n+1COOH = x (mol)
\(n_{H_2}=\dfrac{0,672}{22,4}=0,03\left(mol\right)\)
Theo PT: \(n_{H_2}=\dfrac{1}{2}n_{CH_3COOH}+\dfrac{1}{2}n_{C_nH_{2n+1}COOH}=x+\dfrac{1}{2}x=0,03\)
⇒ x = 0,02 (mol)
⇒ nCH3COOH = 0,04 (mol), nCnH2n+1COOH = 0,02 (mol)
\(\Rightarrow0,04.60+0,02.\left(14n+46\right)=4,44\Rightarrow n=4\)
Vậy: B là C4H9COOH.
c, \(\left\{{}\begin{matrix}\%m_{CH_3COOH}=\dfrac{0,04.60}{4,44}.100\%\approx54,05\%\\\%m_{C_4H_9COOH}\approx45,95\%\end{matrix}\right.\)
Pt: \(2CH_3COOH+Zn\rightarrow\left(CH_3COO\right)_2Zn+H_2\)
\(n_{\left(CH_3COO\right)_2Zn}=\dfrac{14,2}{183}\approx0.077mol\)
Theo pt: nH2 = n(CH3COO)2Zn = 0,077mol
=> VH2 = 1,7248l
b) Theo pt: nCH3COOH = 2n(CH3COO)2Zn = 0,154 mol
=> CMCH3COOH = 0,154 : 0,25 = 0,616M
\(a) n_{CH_3COOH} = \dfrac{200.12\%}{60} = 0,4(mol)\\ 2CH_3COOH + CaCO_3 \to (CH_3COO)_2Ca + CO_2 + H_2O\\ n_{CaCO_3} = n_{CO_2} = \dfrac{1}{2}n_{CH_3COOH} = 0,2(mol)\\ \Rightarrow a = \dfrac{0,2.100}{100\%-20\%} =25(gam)\\ V_B = 0,2.22,4 = 4,48(lít)\\ b) m_{dd\ sau\ pư} = m_{CaCO_3} + m_{dd\ CH_3COOH} - m_{CO_2} = 0,2.100 + 200 - 0,2.2 = 219,6(gam)\\ C\%_{(CH_3COO)_2Ca} = \dfrac{0,2.158}{219,6}.100\% = 36\%\)
\(n_{Fe}=\dfrac{5,6}{56}=0,1\left(mol\right)\)
PT: \(Fe+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Fe+H_2\)
a, Theo PT: \(n_{CH_3COOH}=2n_{Fe}=0,2\left(mol\right)\Rightarrow m_{CH_3COOH}=0,2.60=12\left(g\right)\)
\(\Rightarrow m_{ddCH_3COOH}=\dfrac{12}{10\%}=120\left(g\right)\)
\(n_{H_2}=n_{Fe}=0,1\left(mol\right)\Rightarrow V_{H_2}=0,1.22,4=2,24\left(l\right)\)
b, Theo PT: \(n_{\left(CH_3COO\right)_2Fe}=n_{Fe}=0,1\left(mol\right)\)
Ta có: m dd sau pư = 5,6 + 120 - 0,1.2 = 125,4 (g)
\(\Rightarrow C\%_{\left(CH_3COO\right)_2Fe}=\dfrac{0,1.174}{125,4}.100\%\approx13,88\%\)
a)
\(n_{Na_2CO_3}=\dfrac{10,6}{106}=0,1\left(mol\right)\)
PTHH: Na2CO3 + 2CH3COOH --> 2CH3COONa + CO2 + H2O
0,1--------->0,2------------->0,2------------>0,1
=> mCH3COOH = 0,2.60 = 12 (g)
\(C_{M\left(dd.CH_3COOH\right)}=\dfrac{0,2}{0,4}=0,5M\)
b) \(n_{C_2H_5OH}=\dfrac{13,8}{46}=0,3\left(mol\right)\)
PTHH: CH3COOH + C2H5OH --H2SO4,to--> CH3COOC2H5 + H2O
Xét tỉ lệ: \(\dfrac{0,2}{1}< \dfrac{0,3}{1}\) => Hiệu suất tính theo CH3COOH
\(n_{CH_3COOH\left(pư\right)}=\dfrac{0,2.80}{100}=0,16\left(mol\right)\)
PTHH: CH3COOH + C2H5OH --H2SO4,to--> CH3COOC2H5 + H2O
0,16------------------------------------->0,16
=> \(m_{CH_3COOC_2H_5}=0,16.88=14,08\left(g\right)\)
Bài 5
Fe + 2CH3COOH \(\rightarrow\) (CH3COO)2Fe + H2(1)
nCH3COOH = \(\dfrac{4,5}{60}=0,075mol\)
a) THeo pt: n(CH3COO)2Fe = \(\dfrac{1}{2}.nCH_3COOH=0,0375mol\)
=> m = 6,525g
c) Theo pt (1) nH2 = 1/2nCH3COOH = 0,0375 mol
2H2 + O2 \(\xrightarrow[]{t^o}\) 2H2O
Theo pt: nO2 = 0,5nH2 = 0,01875mol
=> VO2 = 0,42 lít
=> Vkk = 0,42.5 = 2,1 lít
C
A