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a) Gọi số mol H2 là x
=> nH2O=x(mol)
Theo ĐLBTKL: mA+mH2=mB+mH2O
=> 200 + 2x = 156 + 18x
=> x = 2,75 (mol)
=> VH2=2,75.22,4=61,6(l)
b) Gọi nCuO=a(mol)
nFe2O3=1,5a(mol)
=> 80a + 240a + 102b = 200
=> 320a + 102b = 200
PTHH: CuO + H2 --to--> Cu + H2O
a---------------->a
Fe2O3 + 3H2 --to--> 2Fe + 3H2O
1,5a------------------>3a
=> 64a + 168a + 102b = 156
=> 232a + 102b = 156
=> a = 0,5; b = \(\dfrac{20}{15}\)
%mCuO=\(\dfrac{0,5.80}{200}\).100%=20%
%mFe2O3=\(\dfrac{0,75.160}{200}\).100%=60%
%mAl2O3=\(\dfrac{\dfrac{20}{15}102}{200}\).100%=20%
c) nH2=\(\dfrac{2,75}{5}\)=0,55(mol)
nFeO(tt)=\(\dfrac{36}{72}\)=0,5(mol)
Gọi số mol FeO phản ứng là t (mol)
PTHH: FeO + H2 --to--> Fe + H2O
t--------------->t
=> 56t + (0,5-t).72 = 29,6
=> t = 0,4 (mol)
=> H%=\(\dfrac{0,4}{0,5}\).100%=80%
Gọi \(\left\{{}\begin{matrix}n_{Fe_2O_3}=a\left(mol\right)\\n_{Al_2O_3}=2a\left(mol\right)\\n_{CuO}=3a\left(mol\right)\end{matrix}\right.\)
PTHH:
Fe2O3 + 3H2 --to--> 2Fe + 3H2O
a ---------> 3a
CuO + H2 --to--> Cu + H2O
3a ------> 3a
\(\rightarrow3a+3a=\dfrac{13,44}{22,4}=0,6\left(mol\right)\\ \Leftrightarrow a=0,1\left(mol\right)\\ \rightarrow m=0,1.160+0,1.2.102+0,1.3.80=60,4\left(g\right)\)
Gọi \(n_{Fe_2O_3}=x\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}n_{Al_2O_3}=2x\left(mol\right)\\n_{CuO}=3x\left(mol\right)\end{matrix}\right.\)
\(n_{H_2}=\dfrac{13,44}{22,4}=0,6mol\)
\(CuO+H_2\rightarrow Cu+H_2O\)
3x 3x
\(Al_2O_3+3H_2\rightarrow2Al+3H_2O\)
2x 6x
\(Fe_2O_3+3H_2\rightarrow2Fe+3H_2O\)
x 3x
\(\Rightarrow\Sigma n_{H_2}=3x+6x+3x=0,6\Rightarrow x=0,05mol\)
\(\Rightarrow m=m_{CuO}+m_{Al_2O_3}+m_{Fe_2O_3}\)
\(\Rightarrow m=3\cdot0,05\cdot80+2\cdot0,05\cdot102+0,05\cdot160=30,2g\)
a)
\(\left\{{}\begin{matrix}n_{Fe_3O_4}=3a\left(mol\right)\\n_{CuO}=2a\left(mol\right)\end{matrix}\right.\left(a,b>0\right)\\ m_{hh}=85,6\\ \Leftrightarrow232.3a+80.2a=85,6\\ \Leftrightarrow a=0,1\\ \Rightarrow n_{Fe_3O_4}=3a=3.0,1=0,3\left(mol\right)\\n_{CuO}=2.0,1=0,2\left(mol\right)\\ m_{Fe}=n_{Fe}.M_{Fe} =0,3.3.56=50,4\left(g\right)\\ m_{Cu}=n_{Cu}.M_{Cu}=0,1.64=6,4\left(g\right)\)
b) Sao lại có khí H2 ở đây em nhỉ?
PT: \(CuO+CO\underrightarrow{t^o}Cu+CO_2\)
\(Fe_3O_4+4CO\underrightarrow{t^o}3Fe+4CO_2\)
Giả sử: \(\left\{{}\begin{matrix}n_{CuO}=x\left(mol\right)\\n_{Fe_3O_4}=y\left(mol\right)\end{matrix}\right.\)
⇒ 80x + 232y = 39,2 (1)
Ta có: \(n_{CO}=\dfrac{13,44}{22,4}=0,6\left(mol\right)\)
Theo PT: \(n_{CO}=n_{CuO}+4n_{Fe_3O_4}=x+4y\left(mol\right)\)
⇒ x + 4y = 0,6 (2)
Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}x=0,2\left(mol\right)\\y=0,1\left(mol\right)\end{matrix}\right.\)
Theo PT: \(n_{Fe}=3n_{Fe_3O_4}=0,3\left(mol\right)\)
\(\Rightarrow m_{Fe}=0,3.56=16,8\left(g\right)\)
Bạn tham khảo nhé!
\(n_{CuO}=a\left(mol\right),n_{Fe_3O_4}=b\left(mol\right)\)
\(m_X=80a+232b=39.2\left(g\right)\left(1\right)\)
\(n_{H_2}=\dfrac{13.44}{22.4}=0.6\left(mol\right)\)
\(CuO+CO\underrightarrow{^{^{t^0}}}Cu+CO_2\)
\(Fe_3O_4+4CO\underrightarrow{^{^{t^0}}}3Fe+4CO_2\)
\(n_{H_2}=a+4b=0.6\left(mol\right)\left(2\right)\)
\(\left(1\right),\left(2\right):a=0.2,b=0.1\)
\(\%Fe=\dfrac{0.1\cdot3\cdot56}{0.2\cdot64+0.1\cdot3\cdot56}\cdot100\%=56.75\%\)
\(Fe_2O_3+3H_2\rightarrow\left(t^o\right)2Fe+3H_2O\\ CuO+H_2\rightarrow\left(t^o\right)Cu+H_2O\\ Đặt:n_{Fe}=a\left(mol\right);n_{Cu}=0,5a\left(mol\right)\\ m_{hhB}=17,6\\ \Leftrightarrow56a+64.0,5a=17,6\\ \Leftrightarrow a=0,2\left(mol\right)\\ \Rightarrow n_{Fe}=0,2\left(mol\right);n_{Cu}=0,1\left(mol\right)\\ a,n_{H_2}=\dfrac{3}{2}.n_{Fe}+n_{Cu}=\dfrac{3}{2}.0,2+0,1=0,4\left(mol\right)\\ \Rightarrow V_{H_2\left(đktc\right)}=0,4.22,4=8,96\left(l\right)\\ b,Fe+2HCl\rightarrow FeCl_2+H_2\\ n_{HCl}=\dfrac{18,25}{36,5}=0,5\left(mol\right)\\ Vì:\dfrac{0,2}{1}< \dfrac{0,5}{2}\Rightarrow HCldư\\ \Rightarrow ddC:FeCl_2,HCldư\\ n_{FeCl_2}=n_{Fe}=0,2\left(mol\right)\Rightarrow m_{FeCl_2}=0,2.127=25,4\left(g\right)\\ n_{HCl\left(dư\right)}=0,5-0,2.2=0,1\left(mol\right)\)
\(\Rightarrow m_{HCl\left(dư\right)}=0,1.36,5=3,65\left(g\right)\)
Cu + H2O
a. PTHH: CuO + H2 ---to---> Cu + H2O (1)
Fe2O3 + 3H2 ---to---> 2Fe + 3H2O (2)
Ta có: \(m_{hh}=62,4\left(g\right)\)
=> \(m_{Fe}=62,4-12,8=49,6\left(g\right)\)
b. Theo PT(1): \(n_{H_2}=n_{Cu}=\dfrac{12,8}{64}=0,2\left(mol\right)\)
Theo PT(2):\(n_{H_2}=3.n_{Fe}=3.\dfrac{49,6}{56}\approx2,7\left(mol\right)\)
=> \(n_{H_{2_{\left(2PT\right)}}}=0,2+2,7=2,9\left(mol\right)\)
=> \(V_{H_2}=2,9.22,4=64,96\left(lít\right)\)
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