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a) \(n_{Fe}=\dfrac{12}{56}=\dfrac{3}{14}\left(mol\right)\)
PTHH: \(Fe+2HCl\rightarrow FeCl_2+H_2\)
\(\dfrac{3}{14}\)---------------------->\(\dfrac{3}{14}\)
\(\Rightarrow V_{H_2}=\dfrac{3}{14}.22,4=4,8\left(l\right)\)
b) \(n_{ZnO}=\dfrac{8,1}{81}=0,1\left(mol\right)\)
PTHH: \(ZnO+H_2\xrightarrow[]{t^o}Zn+H_2O\)
Xét tỉ lệ: \(0,1< \dfrac{3}{14}\Rightarrow H_2\) dư
Theo PT: \(n_{Zn}=n_{ZnO}=0,1\left(mol\right)\Rightarrow m_{Zn}=0,1.65=6,5\left(g\right)\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
\(1mol\) \(1mol\)
\(\dfrac{3}{14}mol\) \(\dfrac{3}{14}mol\)
\(a)n_{Fe}=\dfrac{m}{M}=\dfrac{12}{56}\approx0,21=\dfrac{3}{14}\left(mol\right)\)
\(V_{H_2}=n.22,4=\dfrac{3}{14}.22,4=4,8\left(l\right)\)
\(b)n_{ZnO}=\dfrac{m}{M}=\dfrac{8,1}{81}=0,1\left(mol\right)\)
\(ZnO+H_2\rightarrow Zn+H_2O\)
\(1mol\) \(1mol\) \(1mol\)
\(0,1mol\) \(0,1mol\) \(0,1mol\)
\(\text{Ta thấy }H_2\text{ dư,ZnO phản ứng hết.Bài toán tính theo ZnO}\)
\(m_{Zn}=n.M=0,1.65=6,5\left(g\right)\)
\(Zn+2HCl->ZnCl_2+H_2\\ m_{Zn}=\dfrac{7,437}{24,79}\cdot65=19,5g\\ m_{HCl}=\dfrac{7,437}{24,79}\cdot2\cdot36,5=21,9g\)
\(n_{H_2}=\dfrac{17.92}{22.4}=0.8\left(mol\right)\)
\(n_{Fe_3O_4}=\dfrac{69.6}{232}=0.3\left(mol\right)\)
\(Fe_3O_4+4H_2\underrightarrow{t^0}3Fe+4H_2O\)
\(0.2..............0.8\)
\(m_{Fe_3O_4\left(dư\right)}=\left(0.3-0.2\right)\cdot232=23.2\left(g\right)\)
\(Zn+2HCl\rightarrow ZnCl_2+H_2\)
\(0.8......................................0.8\)
\(m_{Zn}=0.8\cdot65=52\left(g\right)\)
a, \(Mg+2HCl\rightarrow MgCl_2+H_2\)
b, \(n_{Mg}=\dfrac{4,8}{24}=0,2\left(mol\right)\)
Theo PT: \(n_{HCl}=2n_{Mg}=0,4\left(mol\right)\Rightarrow m_{HCl}=0,4.36,5=14,6\left(g\right)\)
c, \(n_{H_2}=n_{Mg}=0,2\left(mol\right)\)
PT: \(CuO+H_2\underrightarrow{t^o}Cu+H_2O\)
Ta có: \(n_{CuO}=\dfrac{24}{80}=0,3\left(mol\right)\)
Xét tỉ lệ: \(\dfrac{0,3}{1}>\dfrac{0,2}{1}\), ta được CuO dư.
Theo PT: \(n_{Cu}=n_{H_2}=0,2\left(mol\right)\Rightarrow m_{Cu}=0,2.64=12,8\left(g\right)\)
\(n_{Mg}=\dfrac{4,8}{24}=0,2\left(mol\right)\\ a,PTHH:Mg+2HCl\rightarrow MgCl_2+H_2\\ n_{HCl}=2.0,2=0,4\left(mol\right);n_{H_2}=n_{Mg}=0,2\left(mol\right)\\ b,m_{HCl}=0,4.36,5=14,6\left(g\right)\\ c,n_{CuO}=\dfrac{24}{80}=0,3\left(mol\right)\\ CuO+H_2\rightarrow\left(t^o\right)Cu+H_2O\\ Vì:\dfrac{0,2}{1}< \dfrac{0,3}{1}\Rightarrow CuOdư\\ n_{Cu}=n_{H_2}=0,2\left(mol\right)\\ m_{Cu}=0,2.64=12,8\left(g\right)\)
a, nH2=5,6/22,4=0,25 mol
Zn+2HCl->ZnCl2+H2
0,25 0,5 0,25 0,25
mZn pư=0,25.65=16,25 g
b, C%HCl=0,5.36,5.100/200=9,125%
\(n_{H_2}=\frac{6,72}{22,4}=0,3mol\)
PTHH:
\(Mg+2HCl\rightarrow MgCl_2+H_2\uparrow\)
\(Zn+2HCl\rightarrow ZnCl_2+H_2\uparrow\)
Theo PTHH: \(n_{HCl}=2.n_{H_2}=2.0,3=0,6mol\)
HCl lấy dư 10%
\(\rightarrow V_{HCl}=\frac{0,6}{1}\left(100\%+10\%\right)=0,66l\)
1) PTHH: Zn+2HCl→ZnCl2+H2
n\(_{H_2}\)=\(\dfrac{6,72}{22,4}\)=0,3(mol)
Theo PTHH ta có: nZn=n\(_{H_2}\)=0,3(mol)⇒mZn=0,3.65=19,5(g)
_Phản ứng thế
1.c)Theo PTHH(a) ta có:
nZn=n\(_{H_2}\)=0,3(mol)⇒mZn=0,3.6519,5(g)
nHCl=2n\(_{H_2}\)=2.0,3=0,6(mol)⇒mHCl=0,6.36,5=21,9(g)