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\(2Al+3H_2SO_4 \to Al_2(SO_4)_3+3H_2\\ n_{Al}=0,4(mol)\\ a/\\ n_{H_2}=\frac{3}{2}.0,4=0,6(mol)\\ V_{H_2}=0,6.22,4=13,44(l)\\ b/\\ n_{H_2SO_4}=n_{H_2}=0,6(mol)\\ n_{ddH_2SO_4}=\frac{0,6.98.100}{20}=294(g)\\ c/\\ n_{Al_2(SO_4)_3}=0,2(mol)\\ C\%_{Al_2(SO_4)_3}=\frac{0,2.342}{10,8+294-0,6.2}.100\%=22,52\%\)
\(n_{Fe}=\dfrac{11.2}{56}=0.2\left(mol\right)\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
\(0.2......0.4........0.2.............0.2\)
\(V_{H_2}=0.2\cdot22.4=4.48\left(l\right)\)
\(m_{FeCl_2}=0.2\cdot127=25.4\left(g\right)\)
\(m_{HCl}=0.4\cdot36.5=14.6\left(g\right)\)
Câu c và câu d không liên quan tới dữ liệu đề bài cho !
nZn= 19,5/65=0,3(mol); nFe2O3=19,2/160=0,12(mol)
PTHH: Zn + 2 HCl -> ZnCl2 + H2
Fe2O3 + 3 H2 -to-> 2 Fe +3 H2O
nH2=nZnCl2= nZn=0,3(mol) => V(H2,đktc)=0,3.22,4= 6,72(l)
b) nHCl= 2.0,3=0,6(mol) => mHCl=0,6.36,5=21,9(g)
=>mddHCl=(21,9.100)/20=109,5(g)
=>m=109,5(g)
c) mH2=0,3.2=0,6(mol)
mddZnCl2=19,5+109,5 - 0,6= 128,4(g)
mZnCl2=0,3. 136= 40,8(g)
=>C%ddZnCl2= (40,8/128,4).100=31,776%
d) Ta có: 0,3/3 < 0,12/1
=> H2 hết, Fe2O3 dư, tính theo nH2
=> nFe= 2/3. nH2= 2/3. 0,3= 0,2(mol)
=>mFe=0,2.56=11,2(g)
a, nZn = 19,5/65=0,3 (mol)
PTHH: Zn + 2HCl → ZnCl2 + H2
Mol: 0,3 0,15 0,3 0,3
=> \(V_{H_2}=0,3.22,4=6,72\left(l\right)\)
b,mHCl=0,15.36,5=5,475 (g)
=> m=mddHCl=5,475:20%=27,375 (g)
c,mdd sau pứ =19,5+27,375=46,875 (g)
\(m_{ZnCl_2}=0,3.136=40,8\left(g\right)\)
\(\Rightarrow C\%_{ZnCl_2}=\dfrac{40,8}{46,875}.100\%=87,04\%\)
d,\(n_{Fe_2O_3}=\dfrac{19,2}{160}=0,12\left(mol\right)\)
PTHH: Fe2O3 + 3H2 → 2Fe + 3H2O
Mol: 0,3 0,2
Tỉ lệ: 0,12/1>0,3/3 ⇒ Fe2O3 dư,H2 pứ hết
=> mFe=0,2.56=11,2 (g)
\(a,n_{H_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)
\(PTHH:Zn+H_2SO_4\rightarrow ZnSO_4+H_2\\ ..........0,15.......0,15.......0,15.......0,15\left(mol\right)\)
\(m_{Zn}=65\cdot0,15=9,75\left(g\right)\)
\(b,m_{H_2SO_4}=98\cdot0,15=14,7\left(mol\right)\\ c,m_{dd_{H_2SO_4}}=\dfrac{14,7\cdot100}{20}=\dfrac{147}{2}\left(g\right)\\ d,C\%_{dd_{ZnSO_4}}=\dfrac{0,15\cdot161}{\dfrac{147}{2}}\cdot100\approx32,86\%\)
a)
$n_{Al} = \dfrac{8,1}{27} = 0,3(mol)$
$2Al + 6HCl \to 2AlCl_3 + 3H_2$
Theo PTHH :
$n_{H_2} = \dfrac{3}{2}n_{Al} = 0,45(mol)$
$V_{H_2} = 0,45.22,4 = 10,08(lít)$
b) $n_{HCl} = 3n_{Al} = 0,9(mol)$
$\Rightarrow m_{dd\ HCl} = \dfrac{0,9.36,5}{3,65\%} = 900(gam)$
c)
$m_{dd\ sau\ pư}= 8,1 + 900 - 0,45.2 = 907,2(gam)$
$n_{Al_2(SO_4)_3} = \dfrac{1}{2}n_{Al} = 0,15(mol)$
$C\%_{Al_2(SO_4)_3} = \dfrac{0,15.342}{907,2}.100\% = 5,65\%$
\(n_{Fe}=\dfrac{84}{56}=1,5\left(mol\right)\\ PTHH:Fe+2HCl\rightarrow FeCl_2+H_2\\ n_{H_2}=n_{FeCl_2}=n_{Fe}=1,5\left(mol\right)\\ V_{H_2}=1,5.22,4=33,6\left(l\right)\\ C\%_{ddFeCl_2}=\dfrac{127.1,5}{84+300-1,5.2}.100\%=\dfrac{190,5}{381}.100\%=50\%\)
Kalicacbonat mà CaCo3 đâu ra vậy????