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![](https://rs.olm.vn/images/avt/0.png?1311)
a) nFe=0,4(mol); nH2SO4=0,5(mol)
PTHH: Fe + H2SO4 -> FeSO4 + H2
Ta có: 0,4/1 < 0,5/1
=> Fe hết, H2SO4 dư. tính theo nFe.
=> nH2= nH2SO4(p.ứ)=nFe=0,4(mol)
=>nH2SO4(dư)=0,5-0,4=0,1(mol)
=>H2SO4(dư)=0,1.98=9,8(g)
b) V(H2,dktc)=0,4.22,4=8,96(l)
![](https://rs.olm.vn/images/avt/0.png?1311)
a) \(Pt:Fe+H_2SO_4\rightarrow FeSO_4+H_2\)
\(n_{Fe}=\dfrac{22,4}{56}=0,4mol\)
\(n_{H_2SO_4}=\dfrac{24,5}{98}=0,25mol\)
Lập tỉ lệ
\(n_{Fe}:n_{H_2SO_4}=\dfrac{0,4}{1}:\dfrac{0,25}{1}=0,4:0,25\)
Do 0,4>0,25
=> Fe dư
Theo pt: \(n_{H_2}=n_{H_2SO_4}=0,25mol\)
=> \(V_{H_2}=0,25.22,4=5,6lít\)
b) Fe là chất dư sau phản ứng
\(n_{Fe}dư=0,4-0,25=0,15mol\)
\(m_{Fe}dư=0,15.56=8,4g\)
\(a) Fe + H_2SO_4 \to FeSO_4 + H_2\\ n_{Fe} = \dfrac{22,4}{56} = 0,4 > n_{H_2SO_4} = \dfrac{24,5}{98} = 0,25(mol) \to Fe\ dư\\ n_{H_2} = n_{H_2SO_4} = 0,25(mol)\\ V_{H_2} = 0,25.22,4 = 5,6(lít)\\ b) n_{Fe\ pư} = n_{H_2SO_4} = 0,25(mol)\\ \Rightarrow m_{Fe\ dư} = 22,4 - 0,25.56 = 8,4(gam)\)
![](https://rs.olm.vn/images/avt/0.png?1311)
a, \(Fe+2HCl\rightarrow FeCl_2+H_2\)
b, \(n_{H_2}=\dfrac{9,916}{24,79}=0,4\left(mol\right)\)
\(n_{Fe}=n_{H_2}=0,4\left(mol\right)\Rightarrow m_{Fe}=0,4.56=22,4\left(g\right)\)
c, \(n_{HCl}=2n_{H_2}=0,8\left(mol\right)\Rightarrow C_{M_{HCl}}=\dfrac{0,8}{0,2}=4\left(M\right)\)
![](https://rs.olm.vn/images/avt/0.png?1311)
a, \(n_{Fe}=\dfrac{11,2}{56}=0,2\left(mol\right)\)
\(n_{H_2SO_4}=\dfrac{29,4}{98}=0,3\left(mol\right)\)
PT: \(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)
Xét tỉ lệ: \(\dfrac{0,2}{1}< \dfrac{0,3}{1}\), ta được H2SO4 dư.
Theo PT: \(n_{H_2SO_4\left(pư\right)}=n_{Fe}=0,2\left(mol\right)\Rightarrow n_{H_2SO_4\left(dư\right)}=0,3-0,2=0,1\left(mol\right)\)
\(\Rightarrow m_{Fe}=0,1.98=9,8\left(g\right)\)
b, \(n_{H_2}=n_{Fe}=0,2\left(mol\right)\Rightarrow n_{H_2}=0,2.22,4=4,48\left(l\right)\)
c, \(n_{CuO}=\dfrac{24}{80}=0,3\left(mol\right)\)
PT: \(CuO+H_2\underrightarrow{t^o}Cu+H_2O\)
Xét tỉ lệ: \(\dfrac{0,3}{1}>\dfrac{0,2}{1}\), ta được CuO dư.
Theo PT: \(n_{Cu}=n_{H_2}=0,2\left(mol\right)\Rightarrow m_{Cu}=0,2.64=12,8\left(g\right)\)
![](https://rs.olm.vn/images/avt/0.png?1311)
\(n_{Zn}=\dfrac{8,125}{65}=0,125\left(mol\right)\\ m_{HCl}=\dfrac{100.18,25}{100}=18,25\left(g\right)\\
n_{HCl}=\dfrac{18,25}{36,5}=0,5\\ pthh:Zn+2HCl\rightarrow ZnCl_2+H_2\uparrow\)
0,125 0,125 (mol )
\(\Rightarrow V_{H_2}=0,125.22,4=2,8\left(l\right)\\
\)
\(C\%=\dfrac{8,125}{8,125+18,25}.100\%=30,8\%\)
Bài 18:
Ta có: \(n_{Zn}=\dfrac{8,125}{65}=0,125\left(mol\right)\)
\(m_{HCl}=100.18,25\%=18,25\left(g\right)\Rightarrow n_{HCl}=\dfrac{18,25}{36,5}=0,5\left(mol\right)\)
a, PT: \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
b, Xét tỉ lệ: \(\dfrac{0,125}{1}< \dfrac{0,5}{2}\), ta được HCl dư.
Theo PT: \(n_{H_2}=n_{Zn}=0,125\left(mol\right)\)
\(\Rightarrow V_{H_2}=0,125.22,4=2,8\left(g\right)\)
\(m_{H_2}=0,125.2=0,25\left(g\right)\)
c, Theo PT: \(\left\{{}\begin{matrix}n_{ZnCl_2}=n_{Zn}=0,125\left(mol\right)\\n_{HCl\left(pư\right)}=2n_{Zn}=0,25\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow n_{HCl\left(dư\right)}=0,25\left(mol\right)\)
Có: m dd sau pư = 8,125 + 100 - 0,25 = 107,875 (g)
\(\Rightarrow\left\{{}\begin{matrix}C\%_{ZnCl_2}=\dfrac{0,125.136}{107,875}.100\%\approx15,76\%\\C\%_{HCl\left(dư\right)}=\dfrac{0,25.36,5}{107,875}.100\%\approx8,46\%\end{matrix}\right.\)
Bạn tham khảo nhé!
![](https://rs.olm.vn/images/avt/0.png?1311)
\(n_{Fe}=\dfrac{11,2}{56}=0,2mol\)
\(n_{HCl}=2,5.0,2=0,5mol\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
0,2 < 0,5 ( mol )
0,2 0,4 0,2 0,2 ( mol )
Chất dư là HCl
\(m_{HCl\left(dư\right)}=\left(0,5-0,4\right).36,5=3,65g\)
\(V_{H_2}=0,2.22,4=4,48l\)
\(C_{M_{FeCl_2}}=\dfrac{0,2}{0,2}=1M\)
![](https://rs.olm.vn/images/avt/0.png?1311)
nHCl=0,6 mol
FeO+2HCl-->FeCl2+ H2O
x mol x mol
Fe2O3+6HCl-->2FeCl3+3H2O
x mol 2x mol
72x+160x=11,6 =>x=0,05 mol
A/ CFeCl2=0,05/0,3=1/6 M
CFeCl3=0,1/0,3=1/3 M
CHCl du=(0,6-0,4)/0,3=2/3 M
B/
NaOH+ HCl-->NaCl+H2O
0,2 0,2
2NaOH+FeCl2-->2NaCl+Fe(OH)2
0,1 0,05
3NaOH+FeCl3-->3NaCl+Fe(OH)3
0,3 0,1
nNaOH=0,6
CNaOH=0,6/1,5=0,4M
Theo gt ta có: $n_{Fe}=0,4(mol);n_{H_2SO_4}=0,25(mol)$
$Fe+H_2SO_4\rightarrow FeSO_4+H_2$
b, Ta có: $n_{H_2}=n_{H_2SO_4}=0,25(mol)\Rightarrow V_{H_2}=5,6(l)$
c, Sau phản ứng còn dư $n_{Fe}=0,4-0,25=0,15(mol)\Rightarrow m_{Fe}=8,4(g)$
(Các trường hợp nào bạn nhỉ?)
\(n_{Fe}=\dfrac{22.4}{56}=0.4\left(mol\right)\)
\(n_{H_2SO_4}=\dfrac{24.5}{98}=0.25\left(mol\right)\)
\(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)
\(1............1\)
\(0.4.........0.25\)
\(LTL:\dfrac{0.4}{1}>\dfrac{0.25}{1}\Rightarrow Fedư\)
\(V_{H_2}=0.25\cdot22.4=5.6\left(l\right)\)
\(m_{Fe\left(dư\right)}=\left(0.4-0.25\right)\cdot56=8.4\left(g\right)\)