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\(n_{Fe}=\dfrac{11.2}{56}=0.2\left(mol\right)\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
\(0.2...................0.2..........0.2\)
\(V_{H_2}=0.2\cdot22.4=4.48\left(l\right)\)
\(m_{FeCl_2}=0.2\cdot127=25.4\left(g\right)\)
\(m_{\text{dung dịch sau phản ứng}}=11.2+200-0.2\cdot2=210.8\left(g\right)\)
\(C\%_{FeCl_2}=\dfrac{25.4}{210.8}\cdot100\%=12.05\%\)
a, \(Fe_2O_3+3H_2\underrightarrow{t^o}2Fe+3H_2O\)
b, \(n_{Fe_2O_3}=\dfrac{24}{160}=0,15\left(mol\right)\)
Theo PT: \(n_{H_2}=3n_{Fe_2O_3}=0,45\left(mol\right)\)
\(\Rightarrow V_{H_2}=0,45.22,4=10,08\left(l\right)\)
c, n\(n_{Fe}=2n_{Fe_2O_3}=0,3\left(mol\right)\)
PT: \(Fe+2HCl\rightarrow FeCl_2+H_2\)
Theo PT: \(n_{HCl}=2n_{Fe}=0,6\left(mol\right)\Rightarrow V_{HCl}=\dfrac{0,6}{1,5}=0,4\left(M\right)\)
\(n_{Fe_3O_4}=\dfrac{24}{232}=\dfrac{3}{29}\left(mol\right)\)
PTHH :
\(Fe_3O_4+4H_2\underrightarrow{t^o}3Fe+4H_2O\)
3/29 9/29
\(Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\)
9/29 18/29
\(c,V_{HCl}=\dfrac{\dfrac{18}{29}}{1,5}=\dfrac{12}{29}\left(l\right)\)
$a\big)$
$Zn+2HCl\to ZnCl_2+H_2$
$CuO+H_2\xrightarrow{t^o}Cu+H_2O$
$b\big)$
$n_{Zn}=\dfrac{10,4}{65}=0,16(mol)$
Theo PT: $n_{Cu}=n_{Zn}=0,16(mol)$
$\to m_{Cu}=0,16.64=10,24(g)$
a, \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
b, \(n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\)
Theo PT: \(n_{HCl}=2n_{Zn}=0,4\left(mol\right)\Rightarrow C_{M_{HCl}}=\dfrac{0,4}{0,1}=4\left(M\right)\)
c, \(n_{H_2}=n_{Zn}=0,2\left(mol\right)\Rightarrow V_{H_2}=0,2.22,4=4,48\left(l\right)\)
\(n_{Fe}=\dfrac{2.8}{56}=0.05\left(mol\right)\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
\(0.05................................0.05\)
\(V_{H_2}=0.05\cdot22.4=1.12\left(l\right)\)
\(n_{CuO}=\dfrac{6}{80}=0.075\left(mol\right)\)
\(CuO+H_2\underrightarrow{^{^{t^0}}}Cu+H_2O\)
\(1............1\)
\(0.075......0.05\)
Chất khử : H2 . Chất OXH : CuO
\(LTL:\dfrac{0.075}{1}>\dfrac{0.05}{1}\Rightarrow CuOdư\)
\(m_{CuO\left(dư\right)}=\left(0.075-0.05\right)\cdot64=1.6\left(g\right)\)
a) PTHH: Zn + H2SO4 -> ZnSO4 + H2
H2 + CuO -to-> Cu + H2O
b) nH2=nZnSO4= nZn=0,3(mol)
nCuO=36/80=0,45(mol)
Ta có: 0,3/1 <0,45/1
=>H2 hết, CuO dư.
=> Sau phản ứng các chất thu được gồm có: ZnSO4, Cu và CuO(dư)
nCuO(P.ứ)=nCu=nH2=0,3(mol)
=> nCuO(dư)=0,45-0,3=0,15(mol)
mCuO(dư)=0,15.80=12(g)
mCu=0,3.64=19,2(g)
mZnSO4=0,3. 161= 48,3(g)
\(n_{Al}=\dfrac{5.4}{27}=0.2\left(mol\right)\)
\(2Al+6HCl\rightarrow2AlCl_3+3H_2\)
\(0.2........0.6.........0.2.........0.3\)
\(V_{dd_{HCl}}=\dfrac{0.6}{2}=0.3\left(l\right)\)
\(m_{AlCl_3}=0.2\cdot133.5=26.7\left(g\right)\)
\(V_{H_2}=0.3\cdot22.4=6.72\left(l\right)\)
\(n_{Fe_2O_3}=\dfrac{32}{160}=0.2\left(mol\right)\)
\(Fe_2O_3+3H_2\underrightarrow{^{t^0}}2Fe+3H_2O\)
\(1..............3\)
\(0.2............0.3\)
\(LTL:\dfrac{0.2}{1}>\dfrac{0.3}{3}\Rightarrow Fedư\)
\(m_{Cr}=m_{Fe_2O_3\left(dư\right)}+m_{Fe}=\left(0.2-0.1\right)\cdot160+0.2\cdot56=27.2\left(g\right)\)
a) 2Al + 6HCl $\to$ 2AlCl3 + 3H2
b)
n Al = 5,4/27 = 0,2(mol)
Theo PTHH : n HCl = 3n Al = 0,6(mol)
=> V = 0,6/2 = 0,3(lít)
n AlCl3 = n Al = 0,2(mol)
=> m = 0,2.133,5 = 26,7(gam)
c) n H2 = 1/2 n HCl = 0,3(mol)
n Fe2O3 = 32/160 = 0,2(mol)
$Fe_2O_3 + 3H_2 \xrightarrow{t^o} 2Fe + 3H_2O$
Ta thấy : n Fe2O3 /1 = 0,2 > n H2 /3 = 0,1 => Fe2O3 dư
Theo PTHH : n H2O = n H2 = 0,3(mol)
Bảo toàn khối lượng :
m Fe2O3 + m H2 = m chất rắn + m H2O
=> m chất rắn = 32 + 0,3.2 - 0,3.18 = 27,2 gam
Zn+2HCl->ZnCl2+H2
0,05--------------------0,05
CuO+H2-to>Cu+H2O
0,05----0,05
n Zn=\(\dfrac{3,25}{65}=0,05mol\)
=>n CuO=\(\dfrac{6}{80}=0,075mol\)
=>CuO dư
=>m Cu=0,05.64=3,2g
=>m CuO dư=0,025.80=2g
\(a,PTHH:\\ Zn+2HCl\rightarrow ZnCl_2+H_2\uparrow\left(1\right)\\ CuO+H_2\underrightarrow{t^o}Cu+H_2O\left(2\right)\\ b,n_{Zn}=\dfrac{3,25}{65}=0,05\left(mol\right)\\ Theo.pt\left(1\right):n_{H_2}=n_{Zn}=0,05\left(mol\right)\\ n_{CuO}=\dfrac{6}{80}=0,075\left(mol\right)\\ LTL.pt\left(2\right):0,075>0,05\Rightarrow CuO,dư\\ Theo.pt\left(2\right):n_{Cu}=n_{CuO\left(pư\right)}=n_{H_2}=0,05\left(mol\right)\\ m_{Cu}=0,05.64=3,2\left(g\right)\\ c,m_{CuO\left(dư\right)}=\left(0,075-0,05\right).80=2\left(g\right)\)
3/
nFe= 8.4/56=0.15mol
Fe +2HCl --> FeCl2 + H2
0.15__0.3____________0.15
VH2= 0.15*22.4=3.36l
mHCl= 0.3*36.5=10.95g
mddHCl= 10.96*100/10.95=100g
4/ nZn= 3.25/65=0.05 mol
Zn + 2HCl --> ZnCl2 + H2
0.05_______________0.05
nCuO= 12/80=0.15 mol
CuO + H2 -to-> Cu + H2O
Bđ: 0.15___0.05
Pư: 0.05___0.05___0.05
Kt: 0.1_____0_____0.05
mCu= 0.05*64=3.2g