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Câu 1:
PTHH: \(Na+\dfrac{1}{2}Cl_2\xrightarrow[]{t^o}NaCl\)
Ta có: \(n_{NaCl}=2n_{Cl_2}=2\cdot\dfrac{2,24}{22,4}=0,2\left(mol\right)\)
\(\Rightarrow m_{NaCl}=0,2\cdot58,5=11,7\left(g\right)\)
Câu 2:
Ta có: \(n_{H_2}=\dfrac{0,896}{22,4}=0,04\left(mol\right)\) \(\Rightarrow m_{H_2}=0,04\cdot2=0,08\left(g\right)\)
Bảo toàn nguyên tố: \(n_{HCl}=2n_{H_2}=0,08\left(mol\right)\) \(\Rightarrow m_{HCl}=0,08\cdot36,5=2,92\left(g\right)\)
Bảo toàn khối lượng: \(m_{muối}=m_{KL}+m_{HCl}-m_{H_2}=4,29\left(g\right)\)
a, Ta có: 24nMg + 56nFe = 9,2 (g) (1)
\(n_{H_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\)
BT e, có: 2nMg + 2nFe = 2nH2 = 0,5 (2)
Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}n_{Mg}=0,15\left(mol\right)\\n_{Fe}=0,1\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{Mg}=\dfrac{0,15.24}{9,2}.100\%\approx39,13\%\\\%m_{Fe}\approx60,87\%\end{matrix}\right.\)
b, BTNT H, có: \(n_{HCl}=2n_{H_2}=0,5\left(mol\right)\Rightarrow C_{M_{HCl}}=\dfrac{0,5}{0,2}=2,5\left(M\right)\)
\(n_{Fe}=a\left(mol\right),n_{Mg}=b\left(mol\right)\)
\(m_{hh}=56a+24b=10.16\left(g\right)\)
\(n_{H_2}=\dfrac{5.6}{22.4}=0.25\left(mol\right)\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
\(Mg+2HCl\rightarrow MgCl_2+H_2\)
\(n_{H_2}=a+b=0.25\left(mol\right)\left(2\right)\)
\(\left(1\right),\left(2\right):a=0.13,b=0.12\)
\(m_{Fe}=0.13\cdot56=7.28\left(g\right)\)
\(m_{Mg}=0.12\cdot24=2.88\left(g\right)\)
\(n_{HCl}=2\cdot n_{H_2}=2\cdot0.25=0.5\left(mol\right)\)
\(C_{M_{HCl}}=\dfrac{0.5}{0.5}=1\left(M\right)\)
a) Gọi số mol Zn, Fe là a, b (mol)
=> 65a + 56b = 8,56 (1)
\(n_{H_2}=\dfrac{3,136}{22,4}=0,14\left(mol\right)\)
PTHH: Zn + 2HCl --> ZnCl2 + H2
a--->2a-------->a----->a
Fe + 2HCl --> FeCl2 + H2
b----->2b------->b------>b
=> a + b = 0,14 (2)
(1)(2) => a = 0,08; b = 0,06
=> \(\left\{{}\begin{matrix}\%m_{Zn}=\dfrac{0,08.65}{8,56}.100\%=60,748\%\\\%m_{Fe}=\dfrac{0,06.56}{8,56}.100\%=39,252\%\end{matrix}\right.\)
b)
nKOH = 0,2.0,1 = 0,02 (mol)
PTHH: KOH + HCl --> KCl + H2O
0,02-->0,02
=> nHCl = 0,02 + 2a + 2b = 0,3 (mol)
=> \(C_{M\left(HCl\right)}=xM=\dfrac{0,3}{0,15}=2M\)
c) m = 0,08.136 + 0,06.127 = 18,5(g)
\(n_{H_2}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\\ Fe+2HCl\rightarrow FeCl_2+H_2\\ Zn+2HCl\rightarrow ZnCl_2+H_2\\ Đặt:n_{Fe}=a\left(mol\right);n_{Zn}=b\left(mol\right)\left(a,b>0\right)\\ \Rightarrow\left\{{}\begin{matrix}56a+65b=23,3\\a+b=0,4\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,3\\b=0,1\end{matrix}\right.\\ \Rightarrow\%m_{Zn}=\dfrac{0,1.65}{23,3}.100\approx27,897\%\\ \Rightarrow\%m_{Fe}\approx72,103\%\)
Fe+2HCl--->FeCl2+H2
Zn+2HCl-->ZnCl2+H2
Gọi số mol của Fe và Zn lần lượt là x,y mol
=> ta có hpt {56x+65y=23,3
{x+y=8,96/22,4
<=>{x=0,3=>mFe=16,8g
{y=0,1=>mZn=6,5g
nHCl=2nH2=2.8,96/22,4=0,8 mol
=>mHCl=29,2g
%mFe=16,8/23,3.100=72,10300429%
=>%mZn=27,89699571%
Chúc bn học giỏi
1.
Mg + 2HCl -> MgCl2 + H2 (1)
Fe + 2HCl -> FeCl2 + H2 (2)
nH2=0,08(mol)
Đặt nMg=a
nFe=b
Ta có hệ:
\(\left\{{}\begin{matrix}24a+56b=2,56\\a+b=0,08\end{matrix}\right.\)
=>a=0,06
b=0,02
mMg=0,06.24=1,44(g)
%mMg=\(\dfrac{1,44}{2,56}.100\%=56,25\%\)
%mFe=100-56,25=43,75%
b;
Ta có:
nHCl=2nH2=0,16(mol)
CM dd HCl=\(\dfrac{0,16}{0,1}=1,6M\)
a) Gọi số mol Zn, Fe là a, b (mol)
=> 65a + 56b = 7,35 (1)
PTHH: Zn + 2HCl --> ZnCl2 + H2
a---->2a------->a------>a
Fe + 2HCl --> FeCl2 + H2
b------>2b----->b------>b
=> \(a+b=\dfrac{2,688}{22,4}=0,12\left(mol\right)\)
=> a + b = 0,12 (2)
(1)(2) => a = 0,07; b = 0,05
=> \(\left\{{}\begin{matrix}\%m_{Zn}=\dfrac{0,07.65}{7,35}.100\%=61,9\%\\\%m_{Fe}=\dfrac{0,05.56}{7,35}.100\%=38,1\%\end{matrix}\right.\)
b) nHCl(dư) = 0,3.1 - 0,07.2 - 0,05.2 = 0,06 (mol)
PTHH: Ca(OH)2 + 2HCl --> CaCl2 + 2H2O
0,03<-----0,06
=> \(x=C_{M\left(ddCa\left(OH\right)_2\right)}=\dfrac{0,03}{0,1}=0,3M\)
c) Chất rắn thu được là Fe2O3
Bảo toàn Fe: \(n_{Fe_2O_3}=0,025\left(mol\right)\)
=> \(a=m_{Fe_2O_3}=0,025.160=4\left(g\right)\)
Kết tủa thu được là Fe(OH)2
Bảo toàn Fe: \(n_{Fe\left(OH\right)_2}=0,05\left(mol\right)\)
=> \(m=m_{Fe\left(OH\right)_2}=0,05.90=4,5\left(g\right)\)
a) Gọi số mol Mg, Fe là a, b (mol)
=> 24a + 56b = 11,84
\(n_{HCl}=\dfrac{146.14\%}{36,5}=0,56\left(mol\right)\)
PTHH: Mg + 2HCl --> MgCl2 + H2
a--->2a--------->a----->a
Fe + 2HCl --> FeCl2 + H2
b-->2b-------->b------>b
=> 2a + 2b = 0,56
=> a = 0,12; b = 0,16
=> \(\left\{{}\begin{matrix}\%Mg=\dfrac{0,12.24}{11,84}.100\%=24,324\%\\\%Fe=\dfrac{0,16.56}{11,84}.100\%=75,676\%\end{matrix}\right.\)
b) \(n_{H_2}=a+b=0,28\left(mol\right)\)
=> \(V_{H_2}=0,28.22,4=6,272\left(l\right)\)
c) mdd sau pư = 11,84 + 146 - 0,28.2 = 157,28 (g)
=> \(\left\{{}\begin{matrix}C\%_{MgCl_2}=\dfrac{0,12.95}{157,28}.100\%=7,25\%\\C\%_{FeCl_2}=\dfrac{0,16.127}{157,28}.100\%=12,92\%\end{matrix}\right.\)
Fe+2HCl→FeCL\(_2\)+H\(_2\)
a 2a a a (mol)
Zn+2HCl→ZnCl\(_2\)+H\(_2\)
b 2b b b (mol)
n\(_{H_2}\)=\(\dfrac{0,896}{22,4}\)=0,04(mol)
a/
gọi số mol của Fe là a;của Fe là b.ta có hệ:
a+b=0,04
56a+65b=2,42
→a=0,02
b=0,02
vậy n\(_{Fe}\)=n\(_{Zn}\)=0,02(mol)
→m\(_{Fe}\)=56.0,02=1,12(g)
⇔%m\(_{Fe}\)=\(\dfrac{1,12}{2,42}.100\%\)≃46,7%
→%m\(_{Zn}\)=100%-46,7%=53,3%
b/
nHCl=0,2.2+0,2.2=0,8(mol)
C\(_{M_{HCl}}\)=\(\dfrac{0,8}{0,1}\)=8M