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![](https://rs.olm.vn/images/avt/0.png?1311)
a/nH2= 0,1(mol)
Fe + H2SO4 -> FeSO4 + H2
0,1_________________0,1(mol)
=> mFe=0,1.56=5,6(g)
=> %mFe= (5,6/12).100\(\approx\) 46,667%
=> %mCu \(\approx\) 100% - 46,667% \(\approx\) 53,333%
b) mCu= 12-5,6=6,4(g) -> nCu= 0,1(mol)
Cu + 2 H2SO4(đ) -to-> CuSO4 + SO2 + 2 H2O
0,1___0,2__________________0,1(mol)
V=V(SO2,đktc)=0,1.22,4=2,24(l)
mH2SO4(p.ứ)=0,2.98=19,6(g)
=> mH2SO4(bđ)= 19,6 x 100/90 \(\approx21,778\left(g\right)\)
=> mddH2SO4 \(\approx\) (21,778 x 100)/98\(\approx22,222\left(g\right)\)
![](https://rs.olm.vn/images/avt/0.png?1311)
a) Do sản phẩm thu được sau khi nung khi hòa tan vào dd HCl thu được hỗn hợp khí => Sản phẩm chứa Fe dư
\(n_{Fe}=\dfrac{5,6}{56}=0,1\left(mol\right)\); \(n_S=\dfrac{1,6}{32}=0,05\left(mol\right)\)
PTHH: Fe + S --to--> FeS
0,05<-0,05-->0,05
Fe + 2HCl --> FeCl2 + H2
0,05-->0,1---------->0,05
FeS + 2HCl --> FeCl2 + H2S
0,05-->0,1------------->0,05
=> \(\%V_{H_2}=\%V_{H_2S}=\dfrac{0,05}{0,05+0,05}.100\%=50\%\)
b)
nNaOH = 0,2.1 = 0,2 (mol)
PTHH: NaOH + HCl --> NaCl + H2O
0,2-->0,2
=> nHCl = 0,1 + 0,1 + 0,2 = 0,4 (mol)
=> \(C_{M\left(dd.HCl\right)}=\dfrac{0,4}{0,5}=0,8M\)
![](https://rs.olm.vn/images/avt/0.png?1311)
\(n_{Mg}=\dfrac{6}{24}=0,25\left(mol\right)\\ PTHH:Mg+2HCl\rightarrow MgCl_2+H_2\uparrow\)
0,25 ---> 0,5 ---> 0,25 ---> 0,25
\(V_{H_2}=0,25.22,4=5,6\left(l\right)\\ m_{MgCl_2}=0,25.95=23,75\left(g\right)\\ m_{HCl}=0,5.36,5=18,25\left(g\right)\\ m_{ddHCl}=\dfrac{18,25}{18,25\%}=100\left(g\right)\\ m_{H_2}=0,25.2=0,5\left(g\right)\\ m_{dd}=100+6-0,5=105,5\left(g\right)\\ C\%_{MgCl_2}=\dfrac{23,75}{105,5}=22,51\%\)
![](https://rs.olm.vn/images/avt/0.png?1311)
1)2Al+6HCl ->2Al2Cl3+3H2
Fe+2HCl->FeCl2+H2
Gọi số mol của Al là x;Fe là y
ta có 2x*23+56y=8.3
3x+y=5.6/22.4
giải ra là xong hết bài 1 r nha
![](https://rs.olm.vn/images/avt/0.png?1311)
\(n_{Cu}=0,06mol\). Bỏa toàn e : \(2n_{Cu}=3n_{NO}\Rightarrow n_{NO}=0,04mol\)
Xét pư tổng :
\(2NO+1,5O_2+H_2O\rightarrow2HNO_3\)
\(\Rightarrow\)\(n_{O_2}=0,03mol\Rightarrow V_{O_2}=0,672l\)
\(n_{Cu}=\frac{2,84}{64}=0,06\left(l\right)\)
bảo toàn e : \(2n_{Cu}=3n_{NO}\)
=> \(n_{NO}=\frac{2}{3}n_{Cu}=0,04\left(mol\right)\)
\(2NO+1,5O_2+H_2O->2HNO_3\left(1\right)\)
theo (1) \(n_{O_2}=\frac{1,5}{2}n_{NO}=0,03\left(mol\right)\)
=> \(V_{O_2}=0,03.22,4=0,672\left(l\right)\)
![](https://rs.olm.vn/images/avt/0.png?1311)
`1)`
`n_{Al}={2,7}/{27}=0,1(mol)`
`2Al+3H_2SO_4->Al_2(SO_4)_3+3H_2`
`0,1->0,15->0,05->0,15(mol)`
`V_{dd\ H_2SO_4}={0,15}/1=0,15(l)=150(ml)`
`->V=150`
`V'=V_{H_2}=0,15.22,4=3,36(l)`
`C_{M\ X}=C_{M\ Al_2(SO_4)_3}={0,05}/{0,15}=1/3M`
`2)`
`n_{Fe}={2,8}/{56}=0,05(mol)`
`Fe+2HCl->FeCl_2+H_2`
`0,05->0,1->0,05->0,05(mol)`
`V_{dd\ HCl}={0,1}/1=0,1(l)=100(ml)`
`->V=100`
`V_{H_2}=0,05.22,4=1,12(l)`
`C_{M\ FeCl_2}={0,05}/{0,1}=0,5M`
Bài 1:
Ta có: \(n_{Fe}=0,1\left(mol\right)\)
PT: \(Fe+4HNO_3\underrightarrow{t^o}Fe\left(NO_3\right)_3+NO+2H_2O\)
___0,1_____0,4_____0,1_______0,1 (mol)
\(\Rightarrow m_{HNO_3}=0,4.63=25,2\left(g\right)\)
\(\Rightarrow m_{ddHNO_3}=\dfrac{25,2}{6,3\%}=400\left(g\right)\)
Ta có: m dd sau pư = mFe + m dd HNO3 - mNO = 5,6 + 400 - 0,1.30 = 402,6 (g)
\(\Rightarrow C\%_{Fe\left(NO_3\right)_3}=\dfrac{0,1.242}{402,6}.100\%\approx6,01\%\)
Bạn tham khảo nhé!
Bài 2 :
n KMnO4 = 0,2(mol)
$Mn^{+7} + 5e \to Mn^{+2}$
$Fe^{+2} \to Fe^{+3} + 1e$
Bảo toàn electron :
n FeSO4 = 5n KMnO4 = 0,2.5 = 1(mol)
n FeSO4.7H2O = n FeSO4 = 1(mol)
=> a = 1.278 = 278(gam)