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![](https://rs.olm.vn/images/avt/0.png?1311)
\(n_{K_2O}=\dfrac{23.5}{94}=0.25\left(mol\right)\)
\(K_2O+H_2O\rightarrow2KOH\)
\(0.25...................0.5\)
\(C_{M_{KOH}}=\dfrac{0.5}{0.5}=1\left(M\right)\)
\(2KOH+H_2SO_4\rightarrow K_2SO_4+H_2O\)
\(0.5............0.25............0.25\)
\(m_{dd_{H_2SO_4}}=\dfrac{0.25\cdot98}{20\%}=122.5\left(g\right)\)
\(V_{dd_{H_2SO_4}}=\dfrac{122.5}{1.14}=107.5\left(ml\right)=0.1075\left(l\right)\)
\(C_{M_{K_2SO_4}}=\dfrac{0.25}{0.1075+0.5}=0.4\left(M\right)\)
![](https://rs.olm.vn/images/avt/0.png?1311)
1 , \(n_{Na}=\frac{4,6}{23}=0,2\left(mol\right)\)
\(m_{HCl}=200.2,92\%=5,84\left(mol\right)\) => \(n_{HCl}=\frac{5,84}{36,5}=0,16\left(mol\right)\)
\(2Na+2HCl->2NaCl+H_2\left(1\right)\)
vì \(\frac{0,2}{2}>\frac{0,16}{2}\) => Na dư , HCl hết
dung dịch thu được là dung dịch NaCl
theo (1) \(n_{NaCl}=n_{HCl}=0,16\left(mol\right)\) => \(m_{NaCl}=0,16.58,5=9,36\left(g\right)\)
\(n_{H_2}=\frac{1}{2}n_{HCl}=0,08\left(mol\right)\)
khối lượng dung dịch sau phản ứng là
4,6+200-0,08.2=204,44(g)
\(C_{\%\left(NaCl\right)}=\frac{9,36}{204,44}.100\%\approx4,58\%\)
![](https://rs.olm.vn/images/avt/0.png?1311)
a, PT: \(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)
b, Ta có: \(n_{Fe}=\dfrac{19,6}{56}=0,35\left(mol\right)\)
Theo PT: \(n_{H_2}=n_{Fe}=0,35\left(mol\right)\Rightarrow V_{H_2}=0,35.22,4=7,84\left(l\right)\)
c, \(n_{H_2SO_4}=n_{Fe}=0,35\left(mol\right)\Rightarrow C_{M_{H_2SO_4}}=\dfrac{0,35}{0,2}=1,75\left(M\right)\)
d, \(n_{FeSO_4}=n_{Fe}=0,35\left(mol\right)\Rightarrow m_{FeSO_4}=0,35.152=53,2\left(g\right)\)
e, \(C_{M_{FeSO_4}}=\dfrac{0,35}{0,2}=1,75\left(M\right)\)
d, \(n_{H_2SO_4}=0,25.1,6=0,4\left(mol\right)\)
Xét tỉ lệ: \(\dfrac{n_{Fe}}{1}< \dfrac{n_{H_2SO_4}}{1}\), ta được H2SO4 dư.
Theo PT: \(n_{H_2SO_4\left(pư\right)}=n_{Fe}=0,35\left(mol\right)\)
\(\Rightarrow n_{H_2SO_4\left(dư\right)}=0,4-0,35=0,05\left(mol\right)\)
\(\Rightarrow m_{H_2SO_4\left(dư\right)}=0,05.98=4,9\left(g\right)\)
![](https://rs.olm.vn/images/avt/0.png?1311)
CuO + 2HCl -> CuCl2 + H2O (1)
Fe2O3 + 6HCl -> 2FeCl3 + 3H2O (2)
nHCl=0,2.3,5=0,7(mol)
Đặt nCuO=a
nFe2O3=b
Ta có hệ:
80a+160b=20
2a+6b=0,7
=>a=0,05;b=0,1
mCuO=80.0,05=4(g)
mFe2O3=20-4=16(g)
Theo PTHH 1 và 2 ta có:
nCuCl2=nCuO=0,05(mol)
nFeCl3=2nFe2O3=0,2(mol)
mCuCl2=135.0,05=6,75(g)
mFeCl3=162,5.0,2=32,5(g)
mdd =20+200.1,1=240(g)
C% dd CuCl2=6,72\240 .100%=2,8125%
C% dd FeCl3= 32,5\240 .100%=13,54%
\(n_{P_2O_5}=\dfrac{1,42}{142}=0,01\left(mol\right)\)
PTHH: P2O5 + 3H2O → 2H3PO4
Mol: 0,01 0,02
\(C_{M_{ddH_3PO_4}}=\dfrac{0,02}{0,2}=0,1M\)