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Anh bổ sung câu c)
\(C_{MddNa_2SO_4}=\dfrac{0,25}{0,09879+0,5}=0,4175\left(M\right)\)
\(n_{Na_2O}=\dfrac{15,5}{62}=0,25\left(mol\right)\\ PTHH:Na_2O+H_2O\rightarrow2NaOH\\ n_{NaOH}=2.0,25=0,5\left(mol\right)\\ a,C_{MddNaOH}=\dfrac{0,5}{0,5}=1\left(M\right)\\ b,2NaOH+H_2SO_4\rightarrow Na_2SO_4+2H_2O\\ n_{H_2SO_4}=n_{Na_2SO_4}=\dfrac{0,5}{2}=0,25\left(mol\right)\\ m_{H_2SO_4}=0,25.98=24,5\left(g\right)\\ m_{ddH_2SO_4}=\dfrac{24,5.100}{20}=122,5\left(g\right)\\ V_{ddH_2SO_4}=\dfrac{122,5}{1,14}\approx107,456\left(ml\right)\\ c,V_{ddsau}=V_{ddNaOH}+V_{ddH_2SO_4}\approx0,5+0,107456=0,607456\left(l\right)\\C_{MddNa_2SO_4}\approx\dfrac{ 0,25}{0,607456}\approx0,411552\left(M\right)\)
Na2O + H2O → 2NaOH
1 1 2
0,1 0,2
a). nNa2O=\(\dfrac{6,2}{62}\)= 0,1(mol)
CM=\(\dfrac{n}{V}\)=\(\dfrac{0,1}{4}\)= 0,025M
b). Na2O + H2SO4 → Na2SO4 + H2O
1 1 1 1
0,1 0,1
mH2SO4= n.M = 0,1 . 98 = 9,8g
⇒mddH2SO4= mct=\(\dfrac{mct.100\%}{C\%}\)= \(\dfrac{9,8.100}{20}\)= 49(g).
\(n_{K_2O}=\dfrac{23.5}{94}=0.25\left(mol\right)\)
\(K_2O+H_2O\rightarrow2KOH\)
\(0.25...................0.5\)
\(C_{M_{KOH}}=\dfrac{0.5}{0.5}=1\left(M\right)\)
\(2KOH+H_2SO_4\rightarrow K_2SO_4+H_2O\)
\(0.5............0.25............0.25\)
\(m_{dd_{H_2SO_4}}=\dfrac{0.25\cdot98}{20\%}=122.5\left(g\right)\)
\(V_{dd_{H_2SO_4}}=\dfrac{122.5}{1.14}=107.5\left(ml\right)=0.1075\left(l\right)\)
\(C_{M_{K_2SO_4}}=\dfrac{0.25}{0.1075+0.5}=0.4\left(M\right)\)
a, \(Na_2O+H_2O\rightarrow2NaOH\)
Ta có: \(n_{Na_2O}=\dfrac{15,5}{62}=0,25\left(mol\right)\)
Theo PT: \(n_{NaOH}=2n_{Na_2O}=0,5\left(mol\right)\)
\(\Rightarrow CM_{NaOH}=\dfrac{0,5}{0,5}=1\left(M\right)\)
b, \(2NaOH+H_2SO_4\rightarrow Na_2SO_4+2H_2O\)
Theo PT: \(n_{H_2SO_4}=\dfrac{1}{2}n_{NaOH}=0,25\left(mol\right)\)
\(\Rightarrow m_{ddH_2SO_4}=\dfrac{0,25.98}{20\%}=122,5\left(g\right)\)
\(\Rightarrow V_{ddH_2SO_4}=\dfrac{122,5}{1,14}\approx107,46\left(ml\right)\)
Ta có: \(n_{Na_2O}=\dfrac{3,1}{62}=0,05\left(mol\right)\)
PTHH: Na2O + H2O ---> 2NaOH (1)
a. Theo PT(1): \(n_{NaOH}=2.n_{Na_2O}=2.0,05=0,1\left(mol\right)\)
=> \(C_{M_{NaOH}}=\dfrac{0,1}{2}=0,05M\)
b. PTHH: 2NaOH + H2SO4 ---> Na2SO4 + 2H2O
Theo PT: \(n_{H_2SO_4}=\dfrac{1}{2}.n_{NaOH}=\dfrac{1}{2}.0,1=0,05\left(mol\right)\)
=> \(m_{H_2SO_4}=0,05.98=4,9\left(g\right)\)
Ta có: \(C_{\%_{H_2SO_4}}=\dfrac{4,9}{m_{dd_{H_2SO_4}}}.100\%=20\%\)
=> \(m_{dd_{H_2SO_4}}=24,5\left(g\right)\)
a, \(n_{Na_2O}=\dfrac{7,75}{62}=0,125\left(mol\right)\)
PTHH: Na2O + H2O → 2NaOH
Mol: 0,125 0,25
b, \(C_{M_{ddNaOH}}=\dfrac{0,25}{0,25}=1M\)
c,
PTHH: 2NaOH + H2SO4 → Na2SO4 + 2H2O
Mol: 0,25 0,125
\(m_{ddH_2SO_4}=\dfrac{0,125.98.100}{20}=61,25\left(g\right)\)
\(\Rightarrow V_{ddH_2SO_4}=\dfrac{61,25}{1,14}=53,728\left(ml\right)\)
1. \(n_{Na_2O}=\dfrac{15,5}{62}=0,25\left(mol\right)\)
PTHH: Na2O + H2O → 2NaOH
Mol: 0,25 0,5
\(C_{M_{ddNaOH}}=\dfrac{0,5}{0,5}=1M\)
2.
PTHH: 2NaOH + H2SO4 → Na2SO4 + 2H2O
Mol: 0,5 0,25
\(m_{ddH_2SO_4}=\dfrac{0,25.98.100}{20}=122,5\left(g\right)\)
\(V_{ddH_2SO_4}=\dfrac{122,5}{1,14}=107,456\left(ml\right)\)
\(n_{Na2O}=\dfrac{m_{Na2O}}{M_{Na2O}}=0,25\left(mol\right)\)
\(Na_2O+H_2O\rightarrow2NaOH\)
0,25 mol - 0,25 mol - 0,5 mol
a) \(C_{M_{NaOH}}=\dfrac{n_{NaOH}}{V_{NaOH}}=1\left(M\right)\)
b) \(H_2SO_4+2NaOH\rightarrow Na_2SO4+2H_2O\)
0,25 mol - 0,5 mol - 0,25 mol - 0,5 mol
\(m_{ctH2SO4}=n_{H2SO4}.M_{H2SO4}=24,5\left(g\right)\)
\(C_{\%_{H2SO4}}=\dfrac{m_{ctH2SO4}}{m_{ddH2SO4}}.100\%\)
\(\Rightarrow m_{ddH2SO4}=\dfrac{m_{ctH2SO4}.100\%}{C_{\%_{H2SO4}}}=122,5\left(g\right)\)
\(D_{H2SO4}=\dfrac{m_{ddH2SO4}}{V_{H2SO4}}\Rightarrow V_{H2SO4}=\dfrac{m_{ddH2SO4}}{D_{H2SO4}}\approx107,46\left(ml\right)\)
nNa2O=m/M=15,5/62=0,25 (mol)
PT: Na2O + H2O -> 2NaOH
cứ -: 1................1................2 (mol)
Vậy: 0,25 ------------------->0,5(mol)
=> CM NaOH=n/V=0,5/0,5 =1 (M)
b) Ta có PT:
NaOH + H2SO4 -> Na2SO4 + H2O
1.................1................1...............1 (mol)
0,5 ---------->0,5------->0,5 (mol)
=> mH2SO4=n.M=0,5.98=49(gam)
=> md d H2SO4= \(\dfrac{m_{H2SO4}.100\%}{C\%}=\dfrac{49.100}{20}=245\left(g\right)\)
=> Vd d H2SO4=md d H2SO4 / D = 245/1,24\(\approx197,6\left(ml\right)\)=0,1976 lít
Ta có: Vd d sau phản ứng = Vd d H2SO4=0,1976 (lít)
CM=n/M=0,5/0,1976\(\approx2,53\left(M\right)\)
nNa2O= 15.5/62=0.25 mol
PTHH : Na2O + H2O----> 2NaOH
0.25 0.5
a) CMNaOH= n/V=0.5/0.5=1M
b) 2NaOH + H2SO4 -------> Na2SO4 + 2H2O
nH2SO4 = 1/2nNaOH = 0.25 mol
=> mH2SO 4 = 0.25*98 = 24.5
mddH2SO4 = (24.5*100)/20 = 122.5g
=> VH2SO4 = 122.5/1.14 = 107,5ml