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![](https://rs.olm.vn/images/avt/0.png?1311)
\(n_{HCl}=0.1\cdot0.03=0.003\left(mol\right)\)
\(n_{NaOH}=0.1\cdot0.01=0.001\left(mol\right)\)
\(NaOH+HCl\rightarrow NaCl+H_2O\)
Lập tỉ lệ :
\(\dfrac{0.003}{1}>\dfrac{0.001}{1}\Rightarrow HCldư\)
\(n_{HCl\left(dư\right)}=0.003-0.001=0.002\left(mol\right)\)
\(\left[H^+\right]=\dfrac{0.002}{0.1+0.1}=0.01\)
\(pH=-log\left(0.01\right)=2\)
\(b.\)
\(Ba\left(OH\right)_2+2HCl\rightarrow BaCl_2+2H_2O\)
\(0.001..........0.002\)
\(V_{Ba\left(OH\right)_2}=\dfrac{0.001}{1}=0.001\left(l\right)\)
![](https://rs.olm.vn/images/avt/0.png?1311)
pH=12 => nOH-= 10-2 * 0,3 = 0,003 (mol)
để trung hòa thì: nH+ = nOH- = 0,003 => Vdd HCl = 0,003/10-3 = 3 (l)
dd sau khi cô cạn: K+ a (mol) , Na+ b (mol) , Cl- 0,003 (mol)
lập đc hệ: a + b = 0,003
39a + 23b = 0,1915 - 0,003 * 35,5
=> a= 0,001 , b= 0,002
![](https://rs.olm.vn/images/avt/0.png?1311)
\(n_{\left(NH_4\right)_2SO_4}=0,4\cdot0,2=0,08mol\)
\((NH_4)_2SO_4+Ba\left(OH\right)_2\rightarrow2NH_3\uparrow+2H_2O+BaSO_4\downarrow\)
0,08 0,08 0,16 0,08
\(V=0,16\cdot22,4=3,584l\)
\(m_{\downarrow}=0,08\cdot233=18,64g\)
![](https://rs.olm.vn/images/avt/0.png?1311)
a, \(\left\{{}\begin{matrix}n_{Ba^{2+}}=4.10^{-3}\left(mol\right)\\n_{Na^+}=3.10^{-3}\left(mol\right)\\n_{OH^-}=0,011\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}\left[Ba^{2+}\right]=\dfrac{4.10^{-3}}{0,2+0,3}=0,008M\\\left[Na^+\right]=\dfrac{3.10^{-3}}{0,2+0,3}=0,006M\\\left[OH^-\right]=\dfrac{0,011}{0,2+0,3}=0,022M\end{matrix}\right.\)
b, Để trung hòa dung dịch A thì:
\(n_{H^+}=n_{OH^-}\)
\(\Leftrightarrow0,01.V_{ddHCl}=\left(0,02.2+0,01\right).0,2\)
\(\Leftrightarrow V_{ddHCl}=1\left(l\right)\)
1 ) nOH= nNaOH+2nBa(OH)2=0,01+2.0,01=0,03mol
OH- + H+ ----------->H2O
0.03-->0.03
nHCl=nH+ =0.03mol
=>VHCl=0.03/0.3=0.1l=100ml
2 ) (NH4)2SO4 + 2KOH -(t°)-> K2SO4 + 2NH3 + 2H2O
0,05______________________________ 0,1 (mol)
n(NH4)2SO4 = 0,05.1 = 0,05 mol
V NH3 = 0,1 . 22,4 = 2,24 l