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Ta có: \(n_{Zn}=\dfrac{6,5}{65}=0,1\left(mol\right)\)
a. PTHH: Zn + H2SO4 ---> ZnSO4 + H2
b. Theo PT: \(n_{H_2}=n_{Zn}=0,1\left(mol\right)\)
=> \(V_{H_2}=0,1.22,4=2,24\left(lít\right)\)
c. Theo PT: \(n_{H_2SO_4}=n_{Zn}=0,1\left(mol\right)\)
=> \(m_{H_2SO_4}=0,1.98=9,8\left(g\right)\)
Ta có: \(C_{M_{H_2SO_4}}=\dfrac{9,8}{m_{dd_{H_2SO_4}}}.100\%=25\%\)
=> \(m_{dd_{H_2SO_4}}=39,2\left(g\right)\)
Ta có: \(m_{H_2}=0,1.2=0,2\left(g\right)\)
=> \(m_{dd_{ZnSO_4}}=6,5+39,2-0,2=45,5\left(g\right)\)
Theo PT: \(n_{ZnSO_4}=n_{Zn}=0,1\left(mol\right)\)
=> \(m_{ZnSO_4}=0,1.161=16,1\left(g\right)\)
=> \(C_{\%_{ZnSO_4}}=\dfrac{16,1}{45,5}.100\%=35,4\%\)
a) \(n_{Na_2CO_3}=\dfrac{21,2}{106}=0,2\left(mol\right)\)
PTHH: Na2CO3 + 2HCl --> 2NaCl + CO2 + H2O
0,2------------------>0,4---->0,2
mdd sau pư = 200 + 21,2 - 0,2.44 = 212,4(g)
=> \(C\%\left(NaCl\right)=\dfrac{0,4.58,5}{212,4}.100\%=11,017\%\)
$PTHH:Na_2CO_3+2HCl\to 2NaCl+H_2O+CO_2\uparrow$
$n_{Na_2CO_3}=\dfrac{21,2}{106}=0,2(mol)$
Theo PT: $n_{NaCl}=n_{CO_2}=0,2(mol)$
$\Rightarrow m_{NaCl}=0,4.58,5=23,4(g);m_{CO_2}=0,2.44=8,8(g)$
$\Rightarrow C\%_{NaCl}=\dfrac{23,4}{21,2+200-8,8}.100\%\approx 11,01\%$
nAl= 0,5(mol)
a) PTHH: 2 Al + 6 HCl -> 2 AlCl3 + 3 H2
nHCl= 6/2 . 0,5= 1,5(mol)
=>mHCl= 1,5.36,5=54,75(mol)
=> mddHCl= (54,75.100)/18,25=300(g)
b) nH2= 3/2. 0,5=0,75(mol)
=>V(H2,đktc)=0,75.22,4=16,8(l)
c) nAlCl3= nAl= 0,5(mol) -> mAlCl3=0,5. 133,5=66,75(g)
mddAlCl3=mAl+ mddHCl - mH2= 13,5 + 300-0,75.2=312(g)
=> \(C\%ddAlCl3=\dfrac{66,75}{312}.100\approx21,394\%\)
a) \(n_{HCl}=\dfrac{m}{M}=\dfrac{13}{65}=0,2\left(mol\right)\)
\(Zn+2HCl\rightarrow ZnCl_2+H_2\uparrow\)
1 2 1 1 (mol)
0,2 0,4 0,2 0,2 (mol)
b) Thể tích khí hidro:
V = n.22,4 = 0,2.22,4 = 4,48 (l)
c) Khối lượng muối tạo thành:
\(m_{ZnCl_2}=n.M=0,2.\left(65+35,5.2\right)=27,2\left(g\right)\)
d) \(m_{ctHCl}=n.M=0,4.\left(1+35,5\right)=14,6\left(g\right)\)
\(C\%_{HCl}=\dfrac{m_{ctHCl}}{m_{ddHCl}}.100\%=\dfrac{14,6}{200}.100\%=7,3\%\)
\(n_{Al}=\dfrac{21,6}{27}=0,8\left(mol\right)\)
Pt : \(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2O|\)
2 3 1 3
0,8 1,2 0,4 1,2
a) \(n_{H2}=\dfrac{0,8.3}{2}=1,2\left(mol\right)\)
\(V_{H2\left(dktc\right)}=1,2.22,4=26,88\left(l\right)\)
b) \(n_{H2SO4}=\dfrac{0,8.3}{2}=1,2\left(mol\right)\)
⇒ \(m_{H2SO4}=1,2.98=117,6\left(g\right)\)
\(m_{ddH2SO4}=\dfrac{117,6.100}{29,4}=400\left(g\right)\)
c) \(n_{Al2\left(SO4\right)3}=\dfrac{1,2.1}{3}=0,4\left(mol\right)\)
⇒ \(m_{Al2\left(SO4\right)3}=0,4.342=136,8\left(g\right)\)
\(m_{ddspu}=21,6+400-\left(1,2.2\right)=419,2\left(g\right)\)
\(C_{Al2\left(SO4\right)3}=\dfrac{136,8.100}{419,2}=32,63\)0/0
Chúc bạn học tốt
\(Mg+H_2SO_4\rightarrow MgSO_4+H_2\)
1 1 1 1
0,3 0,3 0,3 0,3
\(n_{Mg}=\dfrac{7,2}{24}=0,3\left(mol\right)\)
a). \(n_{H2}=\dfrac{0,3.1}{1}=0,3\left(mol\right)\)
⇒\(V_{H2}=n.22,4=0,3.22,4=6,72\left(l\right)\)
b). \(80ml=0,08l\)
\(n_{H2SO4}=\dfrac{0,3.1}{1}=0,3\left(mol\right)\)
→\(C_M=\dfrac{n}{V}=\dfrac{0,3}{0,08}=3,75\left(M\right)\)
c). \(n_{MgSO4}=\dfrac{0,3.1}{1}=0,3\left(mol\right)\)
\(V_{MgSO4}=n.22,4=0,3.22,4=6,72\left(l\right)\)
→\(C_M=\dfrac{n}{V}=\dfrac{0,3}{6,72}=0,04\left(M\right)\)
d). \(MgSO_4+Ba\left(OH\right)_2\rightarrow Mg\left(OH\right)_2+BaSO_4\downarrow\)
1 1 1 1
0,3 0,3 0,3
\(n_{BaSO4\uparrow}=\dfrac{0,3.1}{1}\)=0,3(mol)
→\(m_{BaSO4\downarrow}=n.M=0,3.233=69,9\left(g\right)\)
\(n_{Ba\left(OH\right)_2}=\dfrac{0,3.1}{1}\)=0,3(mol)
\(\rightarrow V_{ddBa\left(OH\right)_2}=\dfrac{n}{C_M}=\dfrac{0,3}{1,6}=0,1875\left(l\right)\)
\(n_{CuO}=\dfrac{4}{80}=0,05\left(mol\right)\)
\(m_{H_2SO_4}=100.9,8\%=9,8\left(g\right)\Rightarrow n_{H_2SO_4}=\dfrac{9,8}{98}=0,1\left(mol\right)\)
PTHH: CuO + H2SO4 → CuSO4 + H2O
Mol: 0,05 0,05 0,05
Ta có: \(\dfrac{0,05}{1}< \dfrac{0,1}{1}\) ⇒ CuO hết, H2SO4 dư
\(C\%_{ddCuSO_4}=\dfrac{0,05.160.100\%}{4+100}=7,69\%\)
\(C\%_{ddH_2SO_4dư}=\dfrac{\left(0,1-0,05\right).98.100\%}{4+100}=4,71\%\)
PTHH:
Ba+H2SO4➞BaSO4↓+H2↑(1)
0,1 0,1 0,1 0,1
Ba+2H2O➞ Ba(OH)2+ H2(2)
0,1 0,1 0,1
Ta có:{ nBa=\(\frac{27,4}{137}=0,2\left(mol\right)\);\(n_{H_2SO_4}=\frac{100.9,8\%}{98}=0,1\left(mol\right)\)
Lập tỉ lệ : \(\frac{0,2}{1}>\frac{0,1}{1}\)
➞ Ở phương trình 1, Ba dư ,H2SO4 hết
➞ Xảy ra phản ứng(2)
Đặt các số mol trên phương trình ta có:
➞\(V_{H_2}\left(đktc\right)=\left(0,1+0,1\right).22,4=4,48\left(l\right)\)
Lại có \(m_{dd}\) sau phản ứng=\(27,4+100-0,1.233-0,2.2=103,7\left(g\right)\)
➞\(C\%_{Ba\left(OH\right)_2}=\frac{0,1.171}{103,7}.100\%=16,4899\%\)