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\(a,PTHH:CuCl_2+2KOH\rightarrow Cu\left(OH\right)_2\downarrow+2KCl\\ n_{CuCl_2}=\dfrac{27}{135}=0,2\left(mol\right)\\ \Rightarrow n_{KOH}=2n_{CuCl_2}=0,4\left(mol\right)\\ \Rightarrow C\%_{KOH}=\dfrac{0,4}{0,2}=2M\\ b,PTHH:Cu\left(OH\right)_2\rightarrow^{t^o}CuO+H_2O\\ \Rightarrow n_{CuO}=n_{Cu\left(OH\right)_2}=n_{CuCl_2}=0,2\left(mol\right)\\ \Rightarrow m_{CuO}=0,2\cdot80=16\left(g\right)\)
\(m_{ct}=\dfrac{13,5.100}{100}=13,5\left(g\right)\)
\(n_{CuCl2}=\dfrac{13,5}{135}=0,1\left(mol\right)\)
\(m_{ct}=\dfrac{5.200}{100}=10\left(g\right)\)
\(n_{NaOH}=\dfrac{10}{40}=0,25\left(mol\right)\)
Pt : \(CuCl_2+2NaOH\rightarrow Cu\left(OH\right)_2+2NaCl|\)
1 2 1 2
0,1 0,25 0,1
a) Lập tỉ số so sánh : \(\dfrac{0,1}{1}< \dfrac{0,25}{2}\)
⇒ CuCl2 phản ứng hết , NaOH dư
⇒ Tính toán dựa vào số mol của CuCl2
\(n_{Cu\left(OH\right)2}=\dfrac{0,1.1}{1}=0,1\left(mol\right)\)
⇒ \(m_{Cu\left(OH\right)2}=0,1.98=9,8\left(g\right)\)
b) Pt : \(Cu\left(OH\right)_2\underrightarrow{t^o}CuO+H_2O|\)
1 1 1
0,1 0,1
\(n_{CuO}=\dfrac{0.1.1}{1}=0,1\left(mol\right)\)
⇒ \(m_{CuO}=0,1.80=8\left(g\right)\)
Chúc bạn học tốt
\(n_{NaOH}=\dfrac{20}{40}=0,5\left(mol\right)\)
a) \(CuCl_2+2NaOH\rightarrow Cu\left(OH\right)_2+2NaCl\left(1\right)\)
\(Cu\left(OH\right)_2\xrightarrow[t^o]{}CuO+H_2O\left(2\right)\)
b) \(Pt\left(1\right):n_{Cu\left(OH\right)2}=\dfrac{1}{2}n_{NaOH}=0,25\left(mol\right)\)
\(Pt\left(2\right):n_{Cu\left(OH\right)2}=n_{CuO}=0,25\left(mol\right)\Rightarrow m_{Cu}=0,25.64=16\left(g\right)\)
c) Pt(1) : \(n_{NaOH}=n_{NaCl}=0,5\left(mol\right)\Rightarrow m_{NaCl}=0,5.58,5=29,25\left(g\right)\)
\(n_{CuCl_2}=2.0,2=0,4(mol)\\ n_{NaOH}=2.0,2=0,4(mol)\\ a,CuCl_2+2NaOH\to Cu(OH)_2+2NaCl\\ Cu(OH)_2\xrightarrow{t^o}CuO+H_2O\\ b,\dfrac{n_{CuCl_2}}{1}>\dfrac{n_{NaOH}}{2}\Rightarrow CuCl_2\text{ dư}\\ \Rightarrow n_{CuO}=0,2(mol)\\ \Rightarrow m_{CuO}=0,2.80=16(g)\\ c,n_{CuCl_2(dư)}=0,4-0,2=0,2(mol)\\n_{NaCl}=0,2(mol)\\ \Rightarrow m_{CuCl_2(dư)}=0,2.135=27(g)\\ m_{NaCl}=0,2.58,5=11,7(g)\)
\(a.n_{CuCl_2}=\dfrac{13,5.10\%}{100\%.135}=0,01mol\\ CuCl_2+Ca\left(OH\right)_2\rightarrow Cu\left(OH\right)_2+CaCl_2\\ n_{Ca\left(OH\right)_2}=n_{Cu\left(OH\right)_2}=n_{CaCl_2}=0,01mol\\ m_{ddCa\left(OH\right)_2}=\dfrac{0,01.74}{25\%}\cdot100\%=2,96g\\ b.m_{Cu\left(OH\right)_2}=0,01.98=0,98g\\ c.m_{dd}=13,5+2,96-0,98=15,48g\\ C_{\%CaCl_2}=\dfrac{0,01.111}{15,48}\cdot100\%=7,17\%\\ d.Cu\left(OH\right)_2\xrightarrow[]{t^0}CuO+H_2O\\ n_{CuO}=n_{Cu\left(OH\right)_2}=0,01mol\\ m_{CuO}=0,01.80=0,8g\)