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Ta có: \(n_{Fe}=\dfrac{5,6}{56}=0,1\left(mol\right)\)
PT: \(Fe+2HCl\rightarrow FeCl_2+H_2\)
____0,1______0,2_____0,1____0,1 (mol)
a, \(C_{M_{HCl}}=\dfrac{0,2}{0,15}=\dfrac{4}{3}\left(M\right)\)
\(V_{H_2}=0,1.22,4=2,24\left(l\right)\)
b, \(FeCl_2+2NaOH\rightarrow2NaCl+Fe\left(OH\right)_2\)
Theo PT: \(n_{NaOH}=2n_{FeCl_2}=0,2\left(mol\right)\)
\(\Rightarrow V_{NaOH}=\dfrac{0,2}{2}=0,1\left(l\right)\)
a) PTHH: \(Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\)
a_____2a______a_____a (mol)
\(2Al+6HCl\rightarrow2AlCl_3+3H_2\uparrow\)
b_____3b_______b_____\(\dfrac{3}{2}\)b (mol)
Ta lập HPT: \(\left\{{}\begin{matrix}56a+27b=36,1\\a+\dfrac{3}{2}b=\dfrac{21,28}{22,4}=0,95\end{matrix}\right.\) \(\Leftrightarrow\left\{{}\begin{matrix}a=0,5\\b=0,3\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}m_{Fe}=0,5\cdot56=28\left(g\right)\\m_{Al}=8,1\left(g\right)\end{matrix}\right.\)
b+c) Theo các PTHH: \(\left\{{}\begin{matrix}n_{HCl}=2a+3b=1,9\left(mol\right)\\n_{FeCl_2}=0,5\left(mol\right)\\n_{AlCl_3}=0,3\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}C_{M_{HCl}}=\dfrac{1,9}{0,2}=9,5\left(M\right)\\C_{M_{FeCl_2}}=\dfrac{0,5}{0,2}=2,5\left(M\right)\\C_{M_{AlCl_3}}=\dfrac{0,3}{0,2}=1,5\left(M\right)\end{matrix}\right.\)
\(2Al+6HCl->2AlCl_3+3H_2\\ Fe+2HCl->FeCl_2+H_2\\ n_{Al}=a;n_{Fe}=b\\ 27a+56b=8,3\\ 1,5a+b=\dfrac{5,6}{22,4}=0,25\\ a=b=0,1\\ m_{Al}=27\cdot0,1=2,7g\\ m_{Fe}=8,3-2,7=5,6g\\ a=\dfrac{3a+2b}{500}\cdot36,5=3,65\%\\ m_{ddsau}=508,3-0,25\cdot2=507,8g\\ C\%_{AlCl_3}=\dfrac{133,5a}{507,8}=2,63\%\\ C\%_{FeCl_2}=\dfrac{127b}{507,8}=2,50\%\)
\(n_{H_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\\ PTHH:Zn+2HCl\rightarrow ZnCl_2+H_2\\ n_{ZnCl_2}=n_{Zn}=n_{H_2}=0,15\left(mol\right);n_{HCl}=2.0,15=0,3\left(mol\right)\\ a,m=m_{Zn}=0,15.65=9,75\left(g\right)\\ b,C_{MddHCl}=\dfrac{0,3}{0,15}=0,2\left(l\right)\\ c,m_{ZnCl_2}=0,15.136=20,4\left(g\right)\)
Câu b) là tính nồng độ trong X chứ :v
a)
PTHH: Mg + 2HCl --> MgCl2 + H2
2Al + 6HCl --> 2AlCl3 + 3H2
Theo PTHH: \(n_{H_2}=\dfrac{1}{2}.n_{HCl}=\dfrac{1}{2}.\left(0,4.2\right)=0,4\left(mol\right)\)
=> V = 0,4.22,4 = 8,96 (l)
b)
Gọi số mol Mg, Al là a, b (mol)
=> 24a + 27b = 7,8 (1)
Theo PTHH: nH2 = a + 1,5b = 0,4 (2)
(1)(2) => a = 0,1 (mol); b = 0,2(mol)
=> \(\left\{{}\begin{matrix}n_{MgCl_2}=0,1\left(mol\right)\\n_{AlCl_3}=0,2\left(mol\right)\end{matrix}\right.\)
=> \(\left\{{}\begin{matrix}C_{M\left(AlCl_3\right)}=\dfrac{0,2}{0,4}=0,5M\\C_{M\left(MgCl_2\right)}=\dfrac{0,1}{0,4}=0,25M\end{matrix}\right.\)
Câu b) là tính nồng độ trong X chứ :v
a)
PTHH: Mg + 2HCl --> MgCl2 + H2
2Al + 6HCl --> 2AlCl3 + 3H2
Theo PTHH: nH2=12.nHCl=12.(0,4.2)=0,4(mol)nH2=12.nHCl=12.(0,4.2)=0,4(mol)
=> V = 0,4.22,4 = 8,96 (l)
b)
Gọi số mol Mg, Al là a, b (mol)
=> 24a + 27b = 7,8 (1)
Theo PTHH: nH2 = a + 1,5b = 0,4 (2)
(1)(2) => a = 0,1 (mol); b = 0,2(mol)
=> {nMgCl2=0,1(mol)nAlCl3=0,2(mol){nMgCl2=0,1(mol)nAlCl3=0,2(mol)
=> ⎧⎪ ⎪ ⎪⎨⎪ ⎪ ⎪⎩CM(AlCl3)=0,20,4=0,5MCM(MgCl2)=0,10,4=0,25M
a)
$Fe + 2HCl \to FeCl_2 + H_2$
$FeO + 2HCl \to FeCl_2 + H_2O$
b)
Theo PTHH : $n_{Fe} = n_{H_2} = \dfrac{3,36}{22,4} = 0,15(mol)$
$m_{Fe} = 0,15.56 = 8,4(gam)$
$m_{FeO} = 12 - 8,4 = 3,6(gam)$
$n_{FeO} =0,05(mol)$
Theo PTHH : $n_{HCl} = 2n_{Fe} + 2n_{FeO} = 0,4(mol)$
$V_{dd\ HCl} = \dfrac{0,4}{2} = 0,2(lít)$
c) $Fe + CuSO_4 \to FeSO_4 + Cu$
$n_{Cu} = n_{Fe} = 0,15(mol) \Rightarrow m_{chất\ rắn} = m_{FeO} + m_{Cu}$
$= 3,6 + 0,15.64 = 13,2(gam)$
$a\big)$
$M_A=9,4.2=18,8(g/mol)$
$\to \dfrac{n_{CO_2}}{n_{H_2}}=\dfrac{18,8-2}{44-18,8}=\dfrac{2}{3}$
Mà $n_{CO_2}+n_{H_2}=\dfrac{11,2}{22,4}=0,5(mol)$
\(\begin{array} {l} \to n_{CO_2}=0,2(mol);n_{H_2}=0,3(mol)\\ Fe+2HCl\to FeCl_2+H_2\\ FeCO_3+2HCl\to FeCl_2+CO_2+H_2O\\ \text{Theo PT: }n_{Fe}=n_{H_2}=0,3(mol);n_{FeCO_3}=n_{CO_2}=0,2(mol)\\ \to m=0,3.56+0,2.116=40(g) \end{array}\)
$b\big)$
Đổi $400ml=0,4l$
\(\begin{array} {l} \text{Theo PT: }n_{FeCl_2}=n_{H_2}+n_{CO_2}=0,5(mol)\\ \to C_{M\,FeCl_2}=\dfrac{0,5}{0,4}=1,25M \end{array}\)
$c\big)$
\(\begin{array}{l} m_{dd\,FeCl_2}=\dfrac{400}{1,2}\approx 333,33(g)\\ \to C\%_{FeCl_2}=\dfrac{0,5.127}{333,33}.100\%=19,05\%\end{array}\)
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