Cho 9,52 g hh natri sunfit, natri sunfat,natri hidrosunfit tác dụng vừa đủ vs dd H2SO4 sinh ra 1008ml khí .Mặt khác, 2,38gam hh trên tác dụng vừa hết với 18ml dd NaOH 0,5M.Tinh %theo khối lượng các muối có trong hỗn hợp đầu
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\(n_{Na_2SO_3}=\dfrac{12,6}{126}=0,1mol\)
\(Na_2SO_3+H_2SO_4\rightarrow Na_2SO_4+SO_2+H_2O\)
a) \(n_{SO_2}=n_{Na_2SO_3}=0,1mol\) \(\Rightarrow V=2,24l\)
b) \(n_{H_2SO_4}=n_{Na_2SO_3}=0,1mol\) \(\Rightarrow C_M=\dfrac{0,1}{0,2}=0,5M\)
c) \(m_{Na_2SO_4}=0,1\cdot142=14,2g\)
\(n_{H_2}=\dfrac{2,464}{22,4}=0,11mol\)
\(\left\{{}\begin{matrix}Al:x\left(mol\right)\\Fe:y\left(mol\right)\end{matrix}\right.\Rightarrow Muối\left\{{}\begin{matrix}Al_2\left(SO_4\right)_3\\FeSO_4\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}BTe:3x+2y=2n_{H_2}=0,22\\\dfrac{x}{2}\cdot342+y\cdot152=14,44\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}x=0,04mol\\y=0,05mol\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}m_{Al}=0,04\cdot27=1,08g\\m_{Fe}=0,05\cdot56=2,8g\end{matrix}\right.\)
\(Al_2\left(SO_4\right)_3+3BaCl_2\rightarrow2AlCl_3+3BaSO_4\downarrow\)
0,02 0,06
\(FeSO_4+BaCl_2\rightarrow BaSO_4\downarrow+FeCl_2\)
0,05 0,05
\(\Rightarrow\Sigma n_{\downarrow}=0,06+0,05=0,11\Rightarrow m_{BaSO_4}=x=25,63g\)
\(n_{H_2SO_4}=\dfrac{m}{M}=\dfrac{12,25}{98}=0,125mol\)
\(2Na+H_2SO_4\rightarrow Na_2SO_4+H_2\)
0,25 0,125 0,125 ( mol )
\(m_{Na}=n.M=0,25.23=5,75g\)
\(m_{Na_2SO_4}=0,125.142=17,75g\)
\(n_{SO_2}=\dfrac{5,6}{22,4}=0,25mol\)
\(Na_2SO_3+H_2SO_4\rightarrow Na_2SO_4+SO_2+H_2O\)
0,25 0,25 0,25 ( mol )
\(m_{Na_2SO_3}=0,25.126=31,5g\)
\(m_{dd_{H_2SO_4}}=\dfrac{0,25.98}{62\%}=39,51g\)
\(a,n_{H_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\\ n_{NaOH}=0,2.0,1=0,02\left(mol\right)\)
PTHH:
\(CH_3COOH+NaOH\rightarrow CH_3COONa+H_2O\)
0,02<-----------0,02
\(CH_3COOH+Na\rightarrow CH_3COOH+\dfrac{1}{2}H_2\uparrow\)
0,02------------------------------------------>0,01
\(C_2H_5OH+Na\rightarrow C_2H_5ONa+\dfrac{1}{2}H_2\uparrow\)
0,07<-----------------------------------0,14
\(\rightarrow m=0,01.60+0,07.46=3,82\left(g\right)\)
\(b,\left\{{}\begin{matrix}\%m_{CH_3COOH}=\dfrac{0,01.60}{3,82}.100\%=15,71\%\\\%m_{C_2H_5OH}=100\%-15,71\%=84,29\%\end{matrix}\right.\)
\(a,n_{NaOH}=1,5.0,2=0,3\left(mol\right)\\ n_{H_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\)
PTHH:
CH3COOH + NaOH ---> CH3COONa + H2O
0,3<-----------0,3
2CH3COOH + 2Na ---> 2CH3COONa + H2
0,3----------------------------------------------->0,15
2C2H5OH + 2Na ---> 2C2H5ONa + H2
0,2<---------------------------------------0,1
=> m = 0,2.46 +0,3.60 = 27,2 (g)
b) \(\left\{{}\begin{matrix}\%m_{CH_3COOH}=\dfrac{0,3.60}{27,2}.100\%=66,18\%\\\%m_{C_2H_5OH}=100\%-66,18\%=33,82\%\end{matrix}\right.\)
TN2:
\(n_{NaOH}=0,5.0,018=0,009\left(mol\right)\)
PTHH: NaHSO3 + NaOH --> Na2SO3 + H2O
0,009<--0,009
=> 2,38 gam hh chứa 0,009 mol NaHSO3
=> 9,52 gam hh chứa 0,036 mol NaHSO3
Giả sử trong 9,52 gam hh chứa a mol Na2SO3, Na2SO4
=> 126a + 142b = 9,52 - 0,036.104 = 5,776 (1)
PTHH: Na2SO3 + H2SO4 --> Na2SO4 + SO2 + H2O
a---------------------------->a
2NaHSO3 + H2SO4 --> Na2SO4 + 2SO2 + 2H2O
0,036------------------------>0,036
=> \(a+0,036=\dfrac{1,008}{22,4}=0,045\)
=> a = 0,009 (mol)
\(\%m_{NaHSO_3}=\dfrac{0,036.104}{9,52}.100\%=39,33\%\)
\(\%m_{Na_2SO_3}=\dfrac{0,009.126}{9,52}.100\%=11,91\%\)
\(\%m_{Na_2SO_4}=100\%-39,33\%-11,91\%=48,76\%\)