cho 22,4g sắt vào dung dịch chứa 18,25g axit clohiđric. a tính thể tích của khí hidro thu được (đktc). b dẫn khí h2 sinh ra ở trên vào 13,92g fe3o4 nung nóng. tính khối lượng các chất sau phản ứng.
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![](https://rs.olm.vn/images/avt/0.png?1311)
![](https://rs.olm.vn/images/avt/0.png?1311)
a.b.
\(n_{Fe}=\dfrac{2,8}{56}=0,05mol\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
0,05 0,1 0,05 ( mol )
\(V_{H_2}=0,05.22,4=1,12l\)
\(m_{HCl}=0,1.36,5=3,65g\)
c.
\(CuO+H_2\rightarrow\left(t^o\right)Cu+H_2O\)
0,05 0,05 ( mol )
\(m_{Cu}=0,05.64=3,2g\)
![](https://rs.olm.vn/images/avt/0.png?1311)
\(a) Fe + 2HCl \to FeCl_2 + H_2\\ n_{H_2} = n_{Fe} = \dfrac{16,8}{56} = 0,3(mol)\\ V_{H_2} = 0,3.22,4 = 6,72(lít)\\ b) n_{HCl} = 2n_{Fe} = 0,6(mol)\ \Rightarrow m_{HCl} = 0,6.36,5 = 21,9(gam)\)
(Thiếu C% của HCl nên không tìm được khối lượng dung dịch )
\(c) n_{FeCl_2} = n_{Fe} = 0,3(mol)\\ m_{FeCl_2} = 0,3.127 = 38,1(gam)\)
![](https://rs.olm.vn/images/avt/0.png?1311)
`n_[Fe]=[5,6]/56=0,1(mol)`
`n_[HCl]=[10,95]/[36,5]=0,3(mol)`
`Fe + 2HCl -> FeCl_2 + H_2`
`0,1` `0,2` `0,1` `(mol)`
Ta có:`[0,1]/1 < [0,3]/2`
`=>HCl` dư
`a)V_[H_2]=0,1.22,4=2,24(l)`
`b)`
`H_2 + CuO` $\xrightarrow{t^o}$ `Cu + H_2 O`
`0,1` `0,1` `(mol)`
`=>m_[Cu]=0,1.64=6,4(g)`
\(a,n_{Fe}=\dfrac{5,6}{56}=0,1\left(mol\right)\\ n_{HCl}=\dfrac{10,95}{36,5}=0,3\left(mol\right)\)
PTHH: \(Fe+2HCl\rightarrow FeCl_2+H_2\)
bđ 0,1 0,3
pư 0,1 0,2
spư 0 0,1 0,1 0,1
\(\rightarrow V_{H_2}=0,1.22,4=2,24\left(l\right)\)
b, PTHH: \(H_2+CuO\xrightarrow[]{t^o}Cu+H_2O\)
0,1------------>0,1
\(\rightarrow m_{Cu}=0,1.64=6,4\left(g\right)\)
![](https://rs.olm.vn/images/avt/0.png?1311)
\(1,\\ Mg+2HCl\rightarrow MgCl_2+H_2\\ 2,\\ n_{HCl}=\dfrac{18,25}{36,5}=0,5\left(mol\right)\Rightarrow n_{Mg}=n_{MgCl_2}=n_{H_2}=\dfrac{0,5}{2}=0,25\left(mol\right)\\ V_{H_2\left(đktc\right)}=0,25.22,4=5,6\left(l\right)\\ 3,\\ m_{MgCl_2}=95.0,25=23,75\left(g\right)\\ 4,\\ H_2+CuO\rightarrow\left(t^o\right)Cu+H_2O\\ n_{Cu}=n_{H_2}=0,25\left(g\right)\\ m_{Cu}=0,25.64=16\left(g\right)\)
1. \(Mg+2HCl\rightarrow MgCl_2+H_2\)
2. \(n_{HCl}=\dfrac{m_{HCl}}{M_{HCl}}=\dfrac{18,25}{36,5}\approx0,5\left(mol\right)\)
Theo PTHH: \(n_{H_2}=\dfrac{1}{2}n_{HCl}\)
\(\Rightarrow n_{H_2}=\dfrac{1}{2}.0,5=0,25\left(mol\right)\)
\(\Rightarrow V_{H_2}=n_{H_2}.22,4=0,25.22,4=5,6\left(l\right)\)
3. Theo PTHH: \(n_{MgCl_2}=\dfrac{1}{2}n_{HCl}\)
\(\Rightarrow n_{MgCl_2}=0,25\left(mol\right)\)
\(m_{MgCl_2}=n_{MgCl_2}.M_{MgCl_2}=0,25.95=23,75\left(g\right)\)
4. \(H_2+CuO\rightarrow Cu+H_2O\)
Theo PTHH: \(n_{Cu}=n_{H_2}=0,25\left(mol\right)\)
\(\Rightarrow m_{Cu}=n_{Cu}.M_{Cu}=0,25.64=16\left(g\right)\)
![](https://rs.olm.vn/images/avt/0.png?1311)
a.b.c.\(n_{Al}=\dfrac{2,7}{27}=0,1mol\)
\(2Al+6HCl\rightarrow2AlCl_3+3H_2\)
0,1 0,1 0,15 ( mol )
\(V_{H_2}=0,15.22,4=3,36l\)
\(m_{AlCl_3}=0,1.133,5=13,35g\)
d.\(Fe_2O_3+3H_2\rightarrow\left(t^o\right)2Fe+3H_2O\)
0,15 0,1 ( mol )
\(m_{Fe}=0,1.56=5,6g\)
![](https://rs.olm.vn/images/avt/0.png?1311)
\(n_{Mg}=\dfrac{4,8}{24}=0,2\left(mol\right)\\ pthh:Mg+2HCl\rightarrow MgCl_2+H_2\)
0,2 0,4 0,2
\(\Rightarrow m_{HCl}=0,4.36,5=14,6\left(g\right)\\ V_{H_2}=0,2.22,4=4,48\left(l\right)\\ pthh:FeO+H_2\underrightarrow{t^o}Fe+H_2O\)
0,2 0,2 0,2
\(m_{Fe}=0,2.56=11,2\left(g\right)\)
![](https://rs.olm.vn/images/avt/0.png?1311)
\(n_{Zn}=\dfrac{6,5}{65}=0,1\left(mol\right)\\
pthh:Zn+2HCl\rightarrow ZnCl_2+H_2\)
0,1 0,2 0,1
\(V_{H_2}=0,1.22,4=2,24l\\
m_{HCl}=\left(0,2.36,5\right).10\%=0,73g\)
\(n_{Fe_2O_3}=\dfrac{16}{160}=0,1\left(mol\right)\\
pthh:Fe_2O_3+3H_2\underrightarrow{t^o}2Fe+3H_2O\\
LTL:\dfrac{0,1}{1}>\dfrac{0,1}{3}\)
=> Fe2O3 dư
\(n_{Fe}=\dfrac{2}{3}n_{H_2}=0,067\left(mol\right)\\
m_{Fe}=0,067.56=3,73g\)
a.b.\(n_{Zn}=\dfrac{6,5}{65}=0,1mol\)
\(Zn+2HCl\rightarrow ZnCl_2+H_2\)
0,1 0,2 0,1 ( mol )
\(V_{H_2}=0,1.22,4=2,24l\)
\(m_{ddHCl}=\dfrac{0,2.36,5}{10\%}=73g\)
c.\(n_{Fe_2O_3}=\dfrac{16}{160}=0,1mol\)
\(Fe_2O_3+3H_2\rightarrow\left(t^o\right)2Fe+3H_2O\)
0,1 > 0,1 ( mol )
0,1 1/15 ( mol )
\(m_{Fe}=\dfrac{1}{15}.56=3,73g\)
![](https://rs.olm.vn/images/avt/0.png?1311)
a, nZn = 26/65 = 0,4 (mol)
PTHH: Zn + 2HCl -> ZnCl2 + H2
nZn = nH2 = 0,4 (mol)
VH2 = 0,4 . 22,4 = 8,96 (l)
b, nFe2O3 = 16/160 = 0,1 (mol)
PTHH: Fe2O3 + 3H2 -> (t°) 2Fe + 3H2O
LTL: 0,1 < 0,4/3 => H2 dư
nFe = 0,1 . 3 = 0,3 (mol)
mFe = 0,3 . 56 = 16,8 (g)
a) \(n_{Zn}=\dfrac{26}{65}=0,4\left(mol\right)\)
PTHH: Zn + 2HCl --> ZnCl2 + H2
0,4--------------------->0,4
=> VH2 = 0,4.22,4 = 8,96 (l)
b)
\(n_{Fe_2O_3}=\dfrac{16}{160}=0,1\left(mol\right)\)
PTHH: Fe2O3 + 3H2 --to--> 2Fe + 3H2O
Xét tỉ lệ: \(\dfrac{0,1}{1}< \dfrac{0,4}{3}\) => Fe2O3 hết, H2 dư
PTHH: Fe2O3 + 3H2 --to--> 2Fe + 3H2O
0,1---------------->0,2
=> mFe = 0,2.56 = 11,2 (g)
![](https://rs.olm.vn/images/avt/0.png?1311)
a, \(Fe+2HCl\rightarrow FeCl_2+H_2\)
b, \(n_{Fe}=\dfrac{3,36}{56}=0,06\left(mol\right)\)
Theo PT: \(n_{H_2}=n_{Fe}=0,06\left(mol\right)\Rightarrow V_{H_2}=0,06.22,4=1,344\left(l\right)\)
c, \(n_{Fe_2O_3}=\dfrac{4}{160}=0,025\left(mol\right)\)
PT: \(Fe_2O_3+3H_2\underrightarrow{t^o}2Fe+3H_2O\)
Xét tỉ lệ: \(\dfrac{0,025}{1}>\dfrac{0,06}{3}\), ta được Fe2O3 dư.
Theo PT: \(n_{Fe_2O_3\left(pư\right)}=\dfrac{1}{3}n_{H_2}=0,02\left(mol\right)\Rightarrow n_{Fe_2O_3\left(dư\right)}=0,025-0,02=0,005\left(mol\right)\)
\(\Rightarrow m_{Fe_2O_3\left(dư\right)}=0,005.160=0,8\left(g\right)\)
a)
\(n_{Fe}=\dfrac{22,4}{56}=0,4\left(mol\right)\)
\(n_{HCl}=\dfrac{18,25}{36,5}=0,5\left(mol\right)\)
PTHH: Fe + 2HCl --> FeCl2 + H2
Xét tỉ lệ: \(\dfrac{0,4}{1}>\dfrac{0,5}{2}\) => Fe dư, HCl hết
PTHH: Fe + 2HCl --> FeCl2 + H2
0,5----------->0,25
=> VH2 = 0,25.22,4 = 5,6 (l)
b)\(n_{Fe_3O_4}=\dfrac{13,92}{232}=0,06\left(mol\right)\)
PTHH: Fe3O4 + 4H2 --to--> 3Fe + 4H2O
Xét tỉ lệ: \(\dfrac{0,06}{1}< \dfrac{0,25}{4}\) => Fe3O4 hết, H2 dư
PTHH: Fe3O4 + 4H2 --to--> 3Fe + 4H2O
0,06-->0,24------->0,18-->0,24
=> \(\left\{{}\begin{matrix}m_{Fe}=0,18.56=10,08\left(g\right)\\m_{H_2O}=0,24.18=4,32\left(g\right)\\m_{H_2\left(dư\right)}=\left(0,25-0,24\right).2=0,02\left(g\right)\end{matrix}\right.\)
cảm ơn bạn