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![](https://rs.olm.vn/images/avt/0.png?1311)
\(n_{H_2}=\dfrac{20.16}{22.4}=0.9\left(mol\right)\)
\(n_{HCl}=2n_{H_2}=2\cdot0.9=1.8\left(mol\right)\Rightarrow m_{HCl}=1.8\cdot36.5=65.7\left(g\right)\)
Định luật bảo toàn khối lượng :
\(m_{kl}+m_{HCl}=m_{Muối}+m_{H_2}\)
\(\Rightarrow m_{Muối}=29.4+65.7-1.8=93.3\left(g\right)\)
![](https://rs.olm.vn/images/avt/0.png?1311)
Ta có: \(n_{H_2}=\dfrac{11,2}{22,4}=0,5\left(mol\right)\) \(\Rightarrow m_{H_2}=0,5\cdot2=1\left(g\right)\)
Bảo toàn nguyên tố: \(n_{HCl}=2n_{H_2}=1\left(mol\right)\) \(\Rightarrow m_{HCl}=1\cdot36,5=36,5\left(g\right)\)
Bảo toàn khối lượng: \(m_{muối}=m_{KL}+m_{HCl}-m_{H_2}=55,5\left(g\right)\)
![](https://rs.olm.vn/images/avt/0.png?1311)
a) \(n_{H_2}=0,2\left(mol\right)\)
Bảo toàn nguyên tố H : \(n_{HCl}=2n_{H_2}=0,4\left(mol\right)\)
=> \(n_{Cl^-}=0,4\left(mol\right)\)
=> \(m_{muối}=m_{KL}+m_{Cl^-}=20+0,4.35,5=34,2\left(g\right)\)
![](https://rs.olm.vn/images/avt/0.png?1311)
\(n_{H_2SO_4}=n_{H_2}=a(mol)\\ BTKL:\\ m_{hh}+m_{H_2SO_4}=m_{muối}+m_{H_2}\\ 29+98.a=86,6+2.a\\ \to a=0,6(mol)\\ V_{H_2}=0,6.22,4=13,44(l)\)
![](https://rs.olm.vn/images/avt/0.png?1311)
\(\left\{{}\begin{matrix}Mg\\Zn\\Fe\end{matrix}\right.+H_2SO_4\rightarrow\left\{{}\begin{matrix}MgSO_4\\ZnSO_4\\FeSO_4\end{matrix}\right.+H_2\uparrow\)
\(m_{SO_4}=86,8-29=57,8\left(g\right)\)
\(\Rightarrow n_{H_2}=n_{H_2SO_4}=n_{SO_4}=0,6\left(mol\right)\)
\(\Rightarrow b=V_{H_2}=0,6.22,4=13,44\left(l\right)\)
nSO2= 0,15(mol)
PTHH: Mg + 2 H2SO4(đ) -to> MgSO4 + SO2 + 2 H2O
x________2x______________x_______x(mol)
2 Fe + 6 H2SO4(Đ) -to-> Fe2(SO4)3 + 3 SO2 +6 H2O
y____3y__________0,5y___________1,5y(mol)
Ta có hpt:
\(\left\{{}\begin{matrix}24x+56y=5,2\\x+1,5y=0,15\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}x=0,03\\y=0,08\end{matrix}\right.\)
=> m(muối)= mMgSO4+ mFe2(SO4)3= 120.x+0,5.y.400=120.0,03+0,5.0,08.400=19,6(g
=>CHỌN B