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a)
$Mg + H_2SO_4 \to MgSO_4 + H_2$
$MgO + H_2SO_4 \to MgSO_4 + H_2O$
n Mg = n H2 = 2,24/22,4 = 0,1(mol)
%m Mg = 0,1.24/6,4 .100% = 37,5%
%m MgO = 100% -37,5% = 62,5%
b)
=> n MgO = (6,4 - 0,1.24)/40 = 0,1(mol)
=> n H2SO4 = n Mg + n MgO = 0,2(mol)
=> C% H2SO4 = 0,2.98/200 .100% = 9,8%
c)
n MgSO4 = n Mg + n MgO = 0,2(mol)
Sau phản ứng :
m dd = 6,4 + 200 - 0,1.2 = 206,2(gam)
C% MgSO4 = 0,2.120/206,2 .100% = 11,64%
\(n_{H_2}=\dfrac{3,36}{22,4}0,15(mol)\\ a,PTHH:Fe+H_2SO_4\to FeSO_4+H_2\\ b,n_{Fe}=n_{H_2}=0,15(mol)\\ \Rightarrow \%_{Fe}=\dfrac{0,15.56}{14,8}.100\%=56,76\%\\ \Rightarrow \%_{Cu}=100\%-56,76\%=43,24\%\\ c,n_{H_2SO_4}=0,15(mol)\\ \Rightarrow m_{dd_{H_2SO_4}}=\dfrac{0,15.98}{20\%}=73,5(g)\\ \Rightarrow V_{dd_{H_2SO_4}}=\dfrac{73,5}{1,4}=52,5(l)\)
\(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)
\(CuO+H_2SO_4\rightarrow CuSO_4+H_2O\)
\(n_{H_2}=n_{Fe}=\dfrac{4.48}{22.4}=0.2\left(mol\right)\)
\(m_{CuO}=35.2-0.2\cdot56=24\left(g\right)\)
\(n_{CuO}=\dfrac{24}{80}=0.3\left(mol\right)\)
\(\%Fe=\dfrac{11.2}{35.2}\cdot100\%=31.82\%\)
\(\%CuO=100-31.82=68.18\%\)
\(n_{H_2SO_4}=0.2+0.3=0.5\left(mol\right)\)
\(m_{H_2SO_4}=0.5\cdot98=49\left(g\right)\)
\(C\%H_2SO_4=\dfrac{49}{800}\cdot100\%=6.125\%\)
\(m_{FeSO_4}=0.2\cdot152=30.4\left(g\right)\)
\(m_{CuSO_4}=0.3\cdot160=48\left(g\right)\)
\(a)Zn+H_2SO_4\rightarrow ZnSO_4+H_2\\ Fe+H_2SO_4\rightarrow FeSO_4+H_2\\ n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\\ b)Đặt:n_{Zn}=x\left(mol\right);n_{Fe}=y\left(mol\right)\\ Tacó:\left\{{}\begin{matrix}65x+56y=12,1\\x+y=0,2\end{matrix}\right.\\ \Rightarrow\left\{{}\begin{matrix}x=0,1\\y=0,1\end{matrix}\right.\\ \Rightarrow m_{Fe}=0,1.56=5,6\left(g\right);m_{Zn}=0,1.65=6,5\left(g\right)\\ c)n_{H_2SO_4}=n_{H_2}=0,2\left(mol\right)\\ \Rightarrow C\%_{H_2SO_{\text{ 4}}}=\dfrac{0,2.98}{196}.100=10\%\)
\(n_{Fe}=\dfrac{2.8}{56}=0.05\left(mol\right)\)
\(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)
a) Chất tan : FeSO4
Chất khí : H2
\(m_{FeSO_4}=0.05\cdot152=7.6\left(g\right)\)
\(V_{H_2}=0.05\cdot22.4=1.12\left(l\right)\)
a) CuO +H2SO4--->CuSO4 +H2O
Ta có
m\(_{CuO}=19,2-3,2=16\left(g\right)\)
n\(_{CuO}=\frac{16}{80}=0,2\left(mol\right)\)
Theo pthh
n\(_{H2SO4}=n_{CuO}=0,2\left(mol\right)\)
m\(_{H2SO4}=0,2.98=19,6\left(g\right)\)
m\(_{dd}=\frac{19,6.100}{20}=98\left(g\right)\)
b) Theo pthh
n\(_{CuSO4}=n_{CuO}=0,2\left(mol\right)\)
C%=\(\frac{0,2.160}{98+16}.100\%=20\%\)
Chúc bạn học tốt
PTHH : CuO+H2SO4->CuSO4+H2O
nCRb=nCu=3.2/64=0.05(mol)=>nCuo=(19.2-3.2)/80=0.2(mol)
=>nH2so4=0.2mol
=>mH2so4=0.2*98=19.6(g)
Áp dụng ĐTBTKL có:
m muối=mhh+m h2so4=19.2+(0.2*98):20%=117,2
c%=mCuso4/mdd.100
=0,2.160/117,2.100=27,3% c,nCu=3.2/64=0.05(mol) PTHH:Cu+2H2SO4(dd)-->CuSO4+2h2o+so2 Vso2=0.2*22.4=4.48(l)