Cân bằng pư oxi hóa khử ( giải chi tiết ) M + HNO3 = M(NO3)3 + NO + H2O CxHy + H2SO4= SO2+ CO2+ H20
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b)
$S^{-2} + 2e \to S^0$
$N^{+5} \to N^{+2} + 3e$
$3H_2S + 2HNO_3 \to 3S + 2NO + 4H_2O$
c)
$Mg^0 \to Mg^{+2} + 2e$
$N^{+5} + 3e \to N^{+2}$
$3Mg + 8HNO_3 \to 3Mg(NO_3)_2 + 2NO + 4H_2O$
e)
$Al^0 \to Al^{+3} + 3e$
$S^{+6} + 2e \to S^{+4}$
$2Al + 6H_2SO_4 \to Al_2(SO_4)_3 + 3SO_2 + 6H_2O$
g)
$Cu_2S \to 2Cu^{+2} + S^{+6} + 10e$
$N^{+5} + 3e \to N^{+2}$
$3Cu_2S + 16HNO_3 \to 3Cu(NO_3)_2 + 3CuSO_4 + 10NO + 8H_2O$
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3C2H8+16HNO3-> 6CO2+16NO+20H2O
C2-4 -> 2C+4+2.8e | x3
N+5 +3e-> N+2 |x16
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1,C +2H2SO4->C02+2SO2 +2H2O
2,P +5HNO3 ->H3P4O +5NO2 +H20
3, 2PH3 +4O2 ->P2O5+3H2O
4,4NH3 +5O2 ->4NO+6H2O
5,SO2+Br2 +2H2O -> 2HBr +H2SO4
6, 2KClO3+3C -> 2KCl +3CO2
7, 3P +5HNO3 +2H2O -> 3H3PO4 +5NO
8,2PH3 +4O2 ->P2O5+3H2O
9, CH4 +2O2 -> CO2+ 2H2O
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\(1\\ FeS \to Fe^{3+} + S^{+6} + 9e\\ N^{+5} \to N^{+4} + 1e\\ FeS + 12HNO_3 \to Fe(NO_3)_3 + H_2SO_4 + 9NO_2 + 5H_2O\)
\(2\\ M^0 \to M^{+3} + 3e\\ N^{+5} + 3e \to N^{+2}\\ M + 4HNO_3 \to M(NO_3)_3 + NO + 2H_2O\)
\(xM^{\dfrac{2y}{x}} \to xM^{+n} + (xn-2y)e\\ S^{+6} + 2e \to S^{+4} \\ S^{+6} + 8e \to S^{-2}\\ 10M_xO_y + (5n+2xn-4y)H_2SO_4 \to 5xM_2(SO_4)_n + (xn-2y)SO_2 + (xn-2y)H_2S +(5n+xn-2y) H_2O\)
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1)\(N^{-3}H_3+Cl_2\rightarrow N^0_2+HCl\)
\(\left\{{}\begin{matrix}1\times|2N^{-3}\rightarrow N_2^0+6e\left(oxihóa\right)\\3\times|Cl_2^0+2e\rightarrow2Cl^{-1}\left(khử\right)\end{matrix}\right.\)
\(\Rightarrow2NH_3+3Cl_2\rightarrow N_2+6HCl\). Cl là chất oxi hóa và N là chất khử
2)\(N^{-3}H_3+O_2^0\rightarrow N^{+2}O+H_2O^{-2}\)
\(\left\{{}\begin{matrix}4\times|N^{-3}\rightarrow N^{+2}+5e\left(oxihóa\right)\\5\times|O_2^0+4e\rightarrow2O^{2-}\left(khử\right)\end{matrix}\right.\)
\(\Rightarrow4NH_3+5O_2\rightarrow4NO+6H_2O\). N là chất oxi hóa và O là chất khử
3)\(Al^0+Fe^{+\frac{8}{3}}_3O_4\rightarrow Al^{+3}_2O_3+Fe^0\)
\(\left\{{}\begin{matrix}4\times|2Al^0\rightarrow Al_2^{+3}+6e\left(oxihóa\right)\\3\times|Fe^{+\frac{8}{3}}_3+8e\rightarrow3Fe^0\left(khử\right)\end{matrix}\right.\)
\(\Rightarrow8Al+3Fe_3O_4\rightarrow4Al_2O_3+9Fe\)
Fe là chất khử và Al là chất oxi hóa
(1)
$M^0 \to M^{+3} + 3e$
$N^{+5} + 3e \to N^{+2}$
$M + 4HNO_3 \to M(NO_3)_3 + NO + H_2O$
(2)
\(xC^{-\dfrac{2y}{x}}\rightarrow xC^{+4}+\left(4x+2y\right)e\\ S^{+6}+2e\rightarrow S^{+4}\)
$2C_xH_y + (4x+2y)H_2SO_4 \to (4x+2y)SO_2 +2xCO_2 +(4x+4y) H_2O$