cho 200ml dd Ba(OH)2 1M td vừa đủ với 100ml dd H2SO4 aM, sau phản ứng thu đc m gam kết tủa
a, Viết ptpư xảy ra
b, tính a và m
#giúp mk vs ạ
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![](https://rs.olm.vn/images/avt/0.png?1311)
a , \(nFe=\dfrac{11,2}{56}=0,2\left(mol\right)\)
, pthh:
\(Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\)
1mol 2mol 1mol 1mol
0,2 0,4 0,2 0,2
\(FeCl_2+2NaOH\rightarrow Fe\left(OH\right)_2\downarrow+2NaCl\)
1mol 2mol 1mol 2mol
0,2 0,4 0,2 0,4
b, \(mFe\left(OH\right)_2=0,2.90=18\left(gam\right)\)
![](https://rs.olm.vn/images/avt/0.png?1311)
\(n_{FeCl_3}=0.2\cdot0.4=0.08\left(mol\right)\)
\(FeCl_3+3NaOH\rightarrow Fe\left(OH\right)_3+3NaCl\)
\(0.08...........0.24..............0.08\)
\(2Fe\left(OH\right)_3\underrightarrow{^{^{t^0}}}Fe_2O_3+3H_2O\)
\(0.08...........0.04\)
\(m_{Fe_2O_3}=0.04\cdot160=6.4\left(g\right)\)
\(V_{dd_{NaOH}}=\dfrac{0.24}{0.5}=0.48\left(l\right)\)
\(FeCl_3+3NaOH\rightarrow Fe\left(OH\right)_3+3NaCl\) (1)
\(2Fe\left(OH\right)_3\rightarrow Fe_2O_3+3H_2O\) (2)
\(n_{FeCl_3}=0,2.0,4=0,08\left(mol\right)\)
Bảo toàn nguyên tố Fe : \(n_{FeCl_3}=2n_{Fe_2O_3}=0,08\left(mol\right)\)
=> \(n_{Fe_2O_3}=0,04\left(mol\right)\)
=> \(m_{Fe_2O_3}=0,04.160=6,4\left(g\right)\)
Theo PT (1) : \(n_{NaOH}=3n_{FeCl_3}=0,08.3=0,24\left(mol\right)\)
=> \(V_{NaOH}=\dfrac{0,24}{0,5}=0,48\left(l\right)\)
![](https://rs.olm.vn/images/avt/0.png?1311)
a) nNaOH = 0,1 mol
nBa(OH)2 = 0,05 mol
2NaOH (0,1) + H2SO4 (0,05) ----> Na2SO4 + 2H2O (1)
Ba(OH)2 (0,05) + H2SO4 (0,05) -----> BaSO4 (0,05) + 2H2O (2)
- Theo PTHH (1,2): nH2SO4 = 0,1 mol
=> mH2SO4 = 9,8 gam
=> mdd H2SO4 = 98 gam
b) -Theo PTHH 2: nBaSO4 = 0,05 mol
=> mBaSO4 = 11,65 gam
![](https://rs.olm.vn/images/avt/0.png?1311)
a) FeO + 2 HCl -> FeCl2 + H2O
FeCl2 + 2 NaOH -> Fe(OH)2 (kết tủa) + 2 NaCl
m(rắn)=m(kt)=mFe(OH)2=24(g)
=> nFe(OH)2= 24/90= 8/45 (mol)
=> nFeO=nFeCl2=nFe(OH)2= 8/45(mol)
=>m=mFeO=8/45 . 72=12,8(g)
nHCl=2.nFeCl2=2.nFe(OH)2=2. 8/45 = 16/45(mol)
-> VddHCl= (16/45)/ 1= 16/45 (l)= 355,556(ml)
![](https://rs.olm.vn/images/avt/0.png?1311)
\(n_{Na_2CO_3}=0,1.1=0,1\left(mol\right)\)
a. \(Na_2CO_3+Ba\left(OH\right)_2\rightarrow BaCO_3+2NaOH\)
0,1 0,1 0,1 0,2
b. \(m_{kt}=m_{BaCO_3}=0,1.197=19,7\left(g\right)\)
c. \(C\%_{Ba\left(OH\right)_2}=\dfrac{0,1.171.100}{200}=8,55\%\)
d. \(BaCO_3+2HCl\rightarrow BaCl_2+H_2O+CO_2\)
0,1 0,2
=> \(a=m_{dd.HCl}=\dfrac{0,2.36,5.100}{30}=\dfrac{73}{3}\left(g\right)\)
![](https://rs.olm.vn/images/avt/0.png?1311)
a, \(FeCl_3+3NaOH\rightarrow3NaCl+Fe\left(OH\right)_3\)
\(2Fe\left(OH\right)_3\underrightarrow{t^o}Fe_2O_3+3H_2O\)
b, \(n_{FeCl_3}=0,4.2=0,8\left(mol\right)\)
Theo PT: \(n_{NaCl}=3n_{FeCl_3}=2,4\left(mol\right)\)
\(\Rightarrow C_{M_{NaCl}}=\dfrac{2,4}{0,4+0,2}=4\left(M\right)\)
c, \(n_{Fe_2O_3}=\dfrac{1}{2}n_{Fe\left(OH\right)_3}=\dfrac{1}{2}n_{FeCl_3}=0,4\left(mol\right)\)
\(\Rightarrow m_{Fe_2O_3}=0,4.160=64\left(g\right)\)
\(n_{FeCl3}=2.0,4=0,8\left(mol\right)\)
PTHH : \(FeCl_3+3NaOH\rightarrow Fe\left(OH\right)_3+3NaCl\)
0,8----------------------->0,8----------->2,4
b) \(C_{MNaCl}=\dfrac{2,4}{0,4+0,2}=4M\)
c) \(2Fe\left(OH\right)_3\xrightarrow[]{t^o}Fe_2O_3+3H_2O\)
0,8--------------->0,4
\(\Rightarrow a=m_{Fe2O3}=0,4.160=64\left(g\right)\)
![](https://rs.olm.vn/images/avt/0.png?1311)
- Số mol NaOH=0,2a
-Số mol Ba(OH)2=0,2a
- Tổng số mol OH-=0,6a
\(\left[OH^-\right]=\dfrac{0,6a}{0,3}=2a\left(M\right)\)
pH=14+lg\(\left[OH^-\right]\)suy ra: 13=14+lg\(\left[OH^-\right]\)suy ra:
lg\(\left[OH^-\right]\)=-1 suy ra: \(\left[OH^-\right]\)=10-1=0,1M. Vậy:
2a=0,1 suy ra: a=0,05M
- Số mol OH-=0,6a=0,6.0.05=0,03mol
- Số mol H+=0,175.0,2.2=0,07mol
H++OH-\(\rightarrow\)H2O
- Số mol H+ dư= 0,07-0,03=0,04mol
- Tổng thể tích=100+200+200=500ml=0,5 lít
\(\left[H^+\right]=\dfrac{0,04}{0,5}=0,08\left(M\right)\)
pH=-lg\(\left[H^+\right]\)=-lg(0,08)\(\approx\)1,1
a) $Ba(OH)_2 + H_2SO_4 \to BaSO_4 + 2H_2O$
b)
$n_{H_2SO_4} = n_{BaSO_4} = n_{Ba(OH)_2} = 0,2.1 = 0,2(mol)$
$\Rightarrow a = \dfrac{0,2}{0,1} = 2M$
$m = 0,2.233 = 46,6(gam)$