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\(n_{H_2SO_4}=\dfrac{200.7,35\%}{98}=0,15\left(mol\right)\)
PTHH: 2NaOH + H2SO4 --> Na2SO4 + 2H2O
0,3<----0,15-------->0,15
=> mNaOH = 0,3.40 = 12 (g)
\(m_{dd.NaOH}=\dfrac{12.100}{8}=150\left(g\right)\)
mdd sau pư = 200 + 150 = 350 (g)
mNa2SO4 = 0,15.142 = 21,3 (g)
=> \(C\%_{dd.Na_2SO_4}=\dfrac{21,3}{350}.100\%=6,086\%\)
\(a) Fe + 2HCl \to FeCl_2 + H_2\\ n_{H_2} = n_{Fe} = \dfrac{16,8}{56} = 0,3(mol)\\ V_{H_2} = 0,3.22,4 = 6,72(lít)\\ b) n_{HCl} = 2n_{Fe} = 0,6(mol)\ \Rightarrow m_{HCl} = 0,6.36,5 = 21,9(gam)\)
(Thiếu C% của HCl nên không tìm được khối lượng dung dịch )
\(c) n_{FeCl_2} = n_{Fe} = 0,3(mol)\\ m_{FeCl_2} = 0,3.127 = 38,1(gam)\)
\(n_{Na}=\dfrac{6,9}{23}=0,3\left(mol\right)\\ 2Na+2H_2O\rightarrow2NaOH+H_2\\ n_{H_2}=\dfrac{0,3}{2}=0,15\left(mol\right)\\ a,V_{H_2\left(đktc\right)}=0,15.22,4=3,36\left(l\right)\\ b,m_{ddsaup.ứ}=m_{Na}+m_{H_2O}-m_{H_2}=6,9+100-0,15.2=106,6\left(g\right)\)
Cu(OH)2 + H2SO4 \(\rightarrow\) CuSO4 + 2H2O
nCu(OH)2 = \(\dfrac{29,4}{98}=0,3mol\)
Theo pt: nH2SO4 = nCu(OH)2 = 0,3 mol
=> mH2SO4 = 0,3.98 = 29,4g
VH2SO4 = 0,3:1 = 0,3l
PTHH: \(CuO+H_2SO_4\rightarrow CuSO_4+H_2O\)
Ta có: \(n_{CuO}=\dfrac{29,4}{80}=0,3675\left(mol\right)=n_{CuSO_4}=n_{H_2SO_4}\)
\(\Rightarrow\left\{{}\begin{matrix}m_{CuSO_4}=0,3675\cdot160=58,8\left(g\right)\\m_{H_2SO_4}=0,3675\cdot98=36,015\left(g\right)\\V_{H_2SO_4}=\dfrac{0,3675}{1}=0,3675\left(l\right)=367,5\left(ml\right)\end{matrix}\right.\)
`1)PTHH:`
`NaOH + HNO_3 -> NaNO_3 + H_2 O`
`0,05` `0,05` `0,05` `(mol)`
`n_[NaOH]=[4/100 .50]/40=0,05(mol)`
`n_[HNO_3]=[[12,6]/100 .50]/63=0,1(mol)`
Ta có:`[0,05]/1 < [0,1]/1`
`=>HNO_3` dư
`m_\text{dd sau p/ư}=50+50=100(g)`
`@C%_[NaNO_3]=[0,05.85]/100 .100=4,25%`
`@C%_[HNO_3(dư)]=[(0,1-0,05).63]/100 .100=3,15%`
a)
\(n_{H_2}=\dfrac{13,44}{22,4}=0,6\left(mol\right)\)
PTHH: \(2A+3H_2SO_4\rightarrow A_2\left(SO_4\right)_3+3H_2\)
=> \(n_A=0,4\left(mol\right)\)
=> \(M_A=\dfrac{10,8}{0,4}=27\left(g/mol\right)\)
=> A là Al
b) \(n_{Al_2\left(SO_4\right)_3}=0,2\left(mol\right)\)
=> \(m_{Al_2\left(SO_4\right)_3}=0,2.342=68,4\left(g\right)\)
a) \(n_{Mg}=\dfrac{2,4}{24}=0,1\left(mol\right)\)
PTHH: Mg + H2SO4 --> MgSO4 + H2
0,1---->0,1------->0,1---->0,1
=> \(m_{dd.H_2SO_4}=\dfrac{0,1.98}{4,9\%}=200\left(g\right)\)
b) mdd sau pư = 2,4 + 200 - 0,1.2 = 202,2 (g)
mMgSO4 = 0,1.120 = 12 (g)
\(C\%_{MgSO_4}=\dfrac{12}{202,2}.100\%=5,9\%\)
c)
\(n_{CuO}=\dfrac{20}{80}=0,25\left(mol\right)\)
PTHH: CuO + H2 --to--> Cu + H2O
Xét tỉ lệ: \(\dfrac{0,25}{1}>\dfrac{0,1}{1}\) => Hiệu suất tính theo H2
\(n_{Cu}=\dfrac{3,2}{64}=0,05\left(mol\right)\)
PTHH: CuO + H2 --to--> Cu + H2O
0,05<-----0,05
=> \(H=\dfrac{0,05}{0,1}.100\%=50\%\)
a, \(n_{Mg}=\dfrac{2,4}{24}=0,1\left(mol\right)\)
PTHH: Mg + H2SO4 ---> MgSO4 + H2
0,1--->0,1---------->0,1-------->0,1
\(m_{dd\left(H_2SO_4\right)}=\dfrac{0,1.98}{4,9\%}=200\left(g\right)\)
b, \(m_{dd\left(sau.pư\right)}=2,4+200-0,2.2=202,2\left(g\right)\)
\(\rightarrow C\%_{MgSO_4}=\dfrac{0,1.120}{202,2}.100\%=5,93\%\)
c, \(n_{CuO}=\dfrac{20}{80}=0,25\left(mol\right)\)
PTHH: CuO + H2 --to--> Cu + H2O
LTL: 0,25 > 0,1 => CuO dư
\(n_{Cu}=\dfrac{3,2}{64}=0,05\left(mol\right)\)
Theo pt: \(n_{H_2}=n_{Cu}=0,05\left(mol\right)\)
=> \(H=\dfrac{0,05}{0,1}.100\%=50\%\)
\(n_{H_2SO_4}=\dfrac{4,9}{98}=0,05\left(mol\right)\\ H_2SO_4+2NaOH\rightarrow Na_2SO_4+2H_2O\\ a,n_{NaOH}=n_{H_2O}2.0,05=0,1\left(mol\right)\\ \Rightarrow m_{NaOH}=0,1.40=4\left(g\right)\\ b,C1:n_{Na_2SO_4}=n_{H_2SO_4}=0,05\left(mol\right)\\ m_{sp}=m_{Na_2SO_4}+m_{H_2O}=0,05.142+18.0,1=8,9\left(g\right)\\ C2:m_{sp}=m_{H_2SO_4}+m_{NaOH}=4,9+4=8,9\left(g\right)\)