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a, \(n_{HCl}=0,2.0,1=0,02\left(mol\right)=n_{H^+}=n_{Cl^-}\)
\(n_{H_2SO_4}=0,2.0,15=0,03\left(mol\right)=n_{SO_4^{2-}}\) \(\Rightarrow n_{H^+}=2n_{H_2SO_4}=0,06\left(mol\right)\)
\(\Rightarrow\Sigma n_{H^+}=0,02+0,06=0,08\left(mol\right)\)
\(n_{Ba\left(OH\right)_2}=0,3.0,05=0,015\left(mol\right)=n_{Ba^{2+}}\)
\(\Rightarrow n_{OH^-}=2n_{Ba\left(OH\right)_2}=0,03\left(mol\right)\)
\(H^++OH^-\rightarrow H_2O\)
0,03___0,03 (mol) ⇒ nH+ dư = 0,05 (mol)
\(Ba^{2+}+SO_4^{2-}\rightarrow BaSO_4\)
0,015___0,015______0,015 (mol) ⇒ nSO42- dư = 0,015 (mol)
⇒ m = mBaSO4 = 0,015.233 = 3,495 (g)
\(\left[Cl^-\right]=\dfrac{0,02}{0,2+0,3}=0,04\left(M\right)\)
\(\left[H^+\right]=\dfrac{0,05}{0,2+0,3}=0,1\left(M\right)\)
\(\left[SO_4^{2-}\right]=\dfrac{0,015}{0,2+0,3}=0,03\left(M\right)\)
b, pH = -log[H+] = 1
nH+=0,04 mol nOH-=0,03 mol
H+ + OH- --------> H20
0,04 0,03
0,03 0,03 0,03
0,01
a/ [H+] du=0,01/0,2=0,05 M
[SO42-]=0,01/0,2=0,05 M
[K+]=0,01/0,2=0,05 M
[Ba2+]=0,01/0,2=0,05M
b/ nH+ du=0,01/0,2=0,05 M
pH=-log(0,05)=1,3
c/ khoi luong chat ran thu duoc sau phan ung la
mcr= mSO42- + mK+ + mBa2+
=0,01.96+0,01.39+0,01.137
=2,72g
ta có : \(\Sigma n_{H^+}=n_{HCl}+2n_{H_2SO_4}=0,04\left(mol\right)\)
\(\Sigma n_{OH^-}=n_{KOH}+2n_{Ba\left(OH\right)_2}=0,03\left(mol\right)\)
\(n_{SO_4^{2-}}=0,01\left(mol\right)\) ; \(n_{Ba^{2+}}=0,01\left(mol\right)\)
a, PT : \(H^++OH^-\rightarrow H_2O\)
0,03 0,03 0,03 (mol)
\(\Rightarrow n_{H^+}dư=0,01\left(mol\right)\)
đến đây tự tính đc nha. dùng ct \(CM=\dfrac{n}{V}\)
b, \(PH=-log[H^+]=-log\left(\dfrac{0,01}{0,2}\right)\simeq1,3\)
c, \(Ba^{2+}+SO_4^{2-}\rightarrow BaSO_4\downarrow\)
0,01 0,01 0,01 (mol)\(mcr=m\downarrow+m_{K^+}=m_{BaSO_4}+m_{K+}=\left(0,01\times233\right)+\left(0,01\times39\right)=2,72\left(g\right)\)
\(n_{NaCl}=0,1.0,2=0,02\left(mol\right)\)
\(m_{Na_2CO_3}=0,1.0,3=0,03\left(mol\right)\)
\(\left\{{}\begin{matrix}n_{Na^+}=0,02+0,03.2=0,08\left(mol\right)\\n_{Cl^-}=0,02\left(mol\right)\\n_{CO_3^{2-}}=0,03\left(mol\right)\end{matrix}\right.\)
=> \(\left\{{}\begin{matrix}C_{M\left(Na^+\right)}=\dfrac{0,08}{0,2+0,3}=0,16M\\C_{M\left(Cl^-\right)}=\dfrac{0,02}{0,2+0,3}=0,04M\\C_{M\left(CO_3^{2-}\right)}=\dfrac{0,03}{0,2+0,3}=0,06M\end{matrix}\right.\)