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đổi `250ml=0,25l`
\(n_{H_2SO_4}=C_M\cdot V_{ddH_2SO_4}=0,25\cdot2=0,5\left(mol\right)\)
đặt \(\left\{{}\begin{matrix}n_{Al_2O_3}=a\left(mol\right)\\n_{CuO}=b\left(mol\right)\end{matrix}\right.\)
\(PTHH:Al_2O_3+3H_2SO_4->Al_2\left(SO_4\right)_3+3H_2O\)
tỉ lệ 1 : 3 : 1 ; 3
n(mol) a---------->3a-------------->a------------->3a
\(PTHH:CuO+H_2SO_4->CuSO_4+H_2O\)
tỉ lệ 1 : 1 : 1 : 1
n(mol) b-------->b------------>b----------->b
ta có hệ phương trình sau
\(\left\{{}\begin{matrix}102a+80b=26,2\\3a+b=0,5\end{matrix}\right.\\ < =>\left\{{}\begin{matrix}a=0,1\\b=0,2\end{matrix}\right.\\ =>\left\{{}\begin{matrix}n_{Al_2O_3}=0,1\left(mol\right)\\n_{CuO}=0,2\left(mol\right)\end{matrix}\right.\\ =>\left\{{}\begin{matrix}m_{Al_2O_3}=0,1\cdot102=10,2\left(g\right)\\m_{CuO}=0,2\cdot80=16\left(g\right)\end{matrix}\right.\\ =>\left\{{}\begin{matrix}\%m_{Al_2O_3}=\dfrac{10,2}{26,2}\cdot100\%\approx38,9\%\\\%m_{CuO}=100\%-38,9\%=61,1\%\end{matrix}\right.\)
b)
có \(\left\{{}\begin{matrix}n_{Al_2\left(SO_4\right)_3}=a=0,1\left(mol\right)\\n_{CuSO_4}=b=0,2\left(mol\right)\end{matrix}\right.\)
\(=>\left\{{}\begin{matrix}m_{Al_2\left(SO_4\right)_3}=0,1\cdot342=34,2\left(g\right)\\m_{CuSO_4}=0,2\cdot160=32\left(g\right)\end{matrix}\right.\)
a: \(C+O_2\rightarrow CO_2\)(ĐK: t độ)
x x x
\(S+O_2\rightarrow SO_2\)(ĐK: t độ)
y y y
b: \(n_{O_2}=\dfrac{11.2}{22.4}=0.5\left(mol\right)\)
Theo đề, ta có hệ:
12x+32y=10 và x+y=0,5
=>x=0,3 và y=0,2
\(m_C=0.3\cdot12=3.6\left(g\right)\)
\(m_S=0.2\cdot32=6.4\left(g\right)\)
c: \(n_{CO_2}=n_C=0.3\left(mol\right)\)
\(n_{SO_2}=n_S=0.2\left(mol\right)\)
\(V_{khí}=22.4\left(0.3+0.2\right)=11.2\left(lít\right)\)
\(n_{O_2}=\dfrac{11,2}{22,4}=0,5\left(mol\right)\)
PTHH :
\(C+O_2\rightarrow\left(t^o\right)CO_2\)
x x x
\(S+O_2\rightarrow\left(t^o\right)SO_2\)
y y y
Gọi n C = x
n S = y (mol)
Ta có hệ PT :
\(\left\{{}\begin{matrix}12x+32y=10\\x+y=0,5\end{matrix}\right.\)
\(\rightarrow x=0,3;y=0,2\)
\(m_C=0,3.12=3,6\left(g\right)\)
\(m_S=0,2.32=6,4\left(g\right)\)
\(c,V_{hhk}=\left(0,3+0,2\right).22,4=11,2\left(l\right)\)
a) Đặt nCuO=x(mol); nZnO=y(mol) (x,y>0)
nHCl=0,3(mol)
PTHH: CuO +2 HCl -> CuCl2 + H2O
x_________2x______x(mol)
ZnO +2 HCl -> ZnCl2 + H2O
y_____2y_____y(mol)
Ta có hpt:
\(\left\{{}\begin{matrix}80x+81y=12,1\\2x+2y=0,3\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}x=0,05\\y=0,1\end{matrix}\right.\)
b) mCuO= 80x=4(g)
=>%mCuO=(4/12,1).100=33,058%
=>%mZnO=66,942%
C) mH2SO4=98.0,3=29,4(g)
=>mddH2SO4=(29,4.100)/20=147(g)
a, \(C+O_2\underrightarrow{t^o}CO_2\)
\(S+O_2\underrightarrow{t^o}SO_2\)
b, Ta có: 12nC + 32nS = 2,8 (1)
Theo PT: \(n_{O_2}=n_C+n_S=\dfrac{3,36}{22,4}=0,15\left(mol\right)\left(2\right)\)
Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}n_C=0,1\left(mol\right)\\n_S=0,05\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_C=\dfrac{0,1.12}{2,8}.100\%\approx42,86\%\\\%m_S\approx57,14\%\end{matrix}\right.\)
a, \(Mg+H_2SO_4\rightarrow MgSO_4+H_2\)
\(MgO+H_2SO_4\rightarrow MgSO_4+H_2O\)
b, \(n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
Theo PT: \(n_{Mg}=n_{H_2}=0,1\left(mol\right)\Rightarrow m_{Mg}=0,1.24=2,4\left(g\right)\)
\(\Rightarrow m_{MgO}=4,4-2,4=2\left(g\right)\)
c, \(n_{MgO}=\dfrac{2}{40}=0,05\left(mol\right)\)
Theo PT: \(n_{H_2SO_4}=n_{Mg}+n_{MgO}=0,15\left(mol\right)\)
\(\Rightarrow m_{H_2SO_4}=0,15.98=14,7\left(g\right)\)
\(\Rightarrow m_{ddH_2SO_4}=\dfrac{14,7}{19,6\%}=75\left(g\right)\)
\(a)CuO+HCl\xrightarrow[]{}CuCl_2+H_2O\\ Fe_2O_3+6HCl\xrightarrow[]{}2FeCl_3+H_2O\\ b)n_{HCl}=3,5.0,2=0,7\left(mol\right)\\ Đặt\\ n_{CuO}=a\left(mol\right)\\ n_{Fe_2O_3}=b\left(mol\right)\)
Ta có hệ pt:
\(\left\{{}\begin{matrix}2a+6b=0,7\\80a+160b=20\end{matrix}\right.\\ \Rightarrow a=0,05\left(mol\right),b=0,1\left(mol\right)\\ m_{CuO}=0,05.80=4\left(g\right)\\ m_{Fe_2O_3}=0,1.16=16\left(g\right)\)
\(a.CuO+2HCl->CuCl_2+H_2O\\ Fe_2O_3+6HCl->2FeCl_3+3H_2O\\ b.n_{CuO}=a,n_{Fe_2O_3}=b\\ 80a+160b=20\\ 2a+6b=0,2.3,5=0,7\\ a=0,05;b=0,1\\ \%m_{CuO}=\dfrac{80.0,05}{20}=20\%\\ \%m_{Fe_2O_3}=80\%\)
Đặt :
nS = x mol
nP = y mol
mhh = 32x + 31y = 10.765 (g) (1)
S + O2 -to-> SO2
4P + 5O2 -to-> 2P2O5
nO2 = x + 1.25y = 0.4 (2)
(1) , (2) :
x = 0.11
y = 0.2625
%mP = 0.2625*31 / 10.765 * 100% = 75.59%
%S = 24.41%
moxit = mSO2 + mP2O5 = 0.11*64 + 0.25/2 * 142 = 24.79(g)