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\(n_{H_2}=\dfrac{8.96}{22.4}=0.4\left(mol\right)\)
\(BTKL:\)
\(m+0.4\cdot2=28.4+7.2\)
\(\Rightarrow m=34.8\left(g\right)\)
\(b.\)
\(m_{Fe}=0.59155\cdot28.4=16.8\left(g\right)\)
\(n_{Fe}=\dfrac{16.8}{56}=0.3\left(mol\right)\)
\(PTHH:\)
\(\dfrac{x}{y}=\dfrac{n_{Fe}}{n_{H_2}}=\dfrac{0.3}{0.4}=\dfrac{3}{4}\)
\(CT:Fe_3O_4\)
nH2= 0,448/22,4= 0,02(mol)
PTHH :
CuO + H2 -tdo--> Cu + H20
FexOy + yH2 -tdo-> xFe + yH20
Cu + HCl --> k pu
Fe + 2HCl ---> FeCl2 + H2
0,02 -- 0,04---> 0,02 --- 0,02 (mol)
mFe = 0,02 .56= 1,12(g)
=> mCu = 1,76 - 1,12= 0,64(g)
n Cu = 0,64 /64 =0,01(mol)
PTHH :
CuO + H2 -tdo-> Cu + H20
0,,01 --0,01 ----> 0,01(mol)
mCuO= 0,01 . 80 = 0,8(g)
=> mFexOy = 2,4-0,8= 1,6(g)
PTHH :
FexOy + yH2 ---> xFe + yH20
56x+ 16y ---------> 56x
1,6 (g) -------------> 1,12(g)
<=> 1,6 .56x = 1,12( 56x + 16y)
<=> 89,6x = 62,72 x + 17,92y
<=> 89,6x - 62,72x = 17,92y
<=> 26,88 x = 17,92y
=> x/y= 17,92 / 26,88 =2/3
Vậy công thức đúng là Fe203.
\(m_O=6-4.2=1.8\left(g\right)\)
\(n_{Fe}=\dfrac{4.2}{56}=0.075\left(mol\right)\)
\(n_O=\dfrac{1.8}{16}=0.1125\left(mol\right)\)
\(n_{Fe}:n_O=0.075:0.1125=2:3\)
\(CT:Fe_2O_3\)
\(n_{Mg}=\dfrac{4,8}{24}=0,2\left(mol\right)\\ pthh:Mg+2HCl\rightarrow MgCl_2+H_2\)
0,2 0,4 0,2
\(\Rightarrow m_{HCl}=0,4.36,5=14,6\left(g\right)\\ V_{H_2}=0,2.22,4=4,48\left(l\right)\\ pthh:FeO+H_2\underrightarrow{t^o}Fe+H_2O\)
0,2 0,2 0,2
\(m_{Fe}=0,2.56=11,2\left(g\right)\)
\(CT:Fe_xO_y\)
\(Fe_xO_y+yH_2\underrightarrow{^{t^o}}xFe+yH_2O\left(1\right)\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\left(2\right)\)
\(n_{Fe}=n_{H_2\left(2\right)}=\dfrac{4.032}{22.4}=0.18\left(mol\right)\)
\(n_{H_2\left(1\right)}=\dfrac{y}{x}\cdot n_{Fe}=\dfrac{5.376}{22.4}=0.24\left(mol\right)\)
\(\Leftrightarrow\dfrac{y}{x}\cdot0.18=0.24\)
\(\Leftrightarrow\dfrac{x}{y}=\dfrac{3}{4}\)
\(CT:Fe_3O_4\)
\(m_{Fe_3O_4}=\dfrac{0.18}{3}\cdot232=13.92\left(g\right)\)
Ta có: \(n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\)
a, PT: \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
______0,2_________________0,2 (mol)
b, VH2 = 0,2.22,4 = 4,48 (l)
c, Ta có: \(n_{FeO}=\dfrac{7,2}{72}=0,1\left(mol\right)\)
PT: \(FeO+H_2\underrightarrow{t^o}Fe+H_2O\)
Xét tỉ lệ: \(\dfrac{0,1}{1}< \dfrac{0,2}{1}\), ta được H2 dư.
Theo PT: \(n_{Fe}=n_{FeO}=0,1\left(mol\right)\)
⇒ mFe = 0,1.56 = 5,6 (g)
Bạn tham khảo nhé!
a) Zn + 2HCl \(\rightarrow\)ZnCl2 + H2
b) mZn = \(\dfrac{13}{65}\)=0,2 (mol)
Zn + 2HCl \(\rightarrow\)ZnCl2 + H2
(mol) 0,2 ----------------------> 0,2
\(V_{H_2}\)= 0,2 . 22,4 = 4,48(lít)
c)\(n_{FeO}\)=\(\dfrac{7,2}{72}\)=0,1 (mol)
H2 + FeO \(\underrightarrow{t^o}\)Fe + H2O
(mol) 0,1----->0,1
mFe = 0,1 . 56 = 5,6(g)
Gọi CT oxit sắt đó là FexOy.
PT: \(Fe_xO_y+yH_2\underrightarrow{t^o}xFe+yH_2O\)
Ta có: \(n_{Fe}=\dfrac{4,2}{56}=0,075\left(mol\right)\)
Theo PT: \(n_{Fe_xO_y}=\dfrac{1}{x}n_{Fe}=\dfrac{0,075}{x}\left(mol\right)\)
\(\Rightarrow M_{Fe_xO_y}=\dfrac{6}{\dfrac{0,075}{x}}=80x\left(g/mol\right)\)
\(\Rightarrow56x+16y=80x\Rightarrow24x=16y\Rightarrow\dfrac{x}{y}=\dfrac{2}{3}\)
Vậy: Oxit sắt đó là Fe2O3.
Theo PT: \(n_{H_2}=\dfrac{y}{x}n_{Fe}=\dfrac{3}{2}.0,075=0,1125\left(mol\right)\Rightarrow V_{H_2}=0,1125.22,4=2,52\left(l\right)\)