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a)
$C_6H_{12}O_6 \xrightarrow{t^o,xt} 2CO_2 + 2C_2H_5OH$
720 ml = 720 cm3
m dd glucozo = D.V = 720.1 = 720(gam)
m glucozo = 720.5% = 36(gam)
n glucozo = 36/180 = 0,2(mol)
Theo PTHH :
n C2H5OH = 2n glucozo = 0,4(mol)
m C2H5OH = 0,4.46 = 18,4(gam)
b)
V rượu = m/D = 18,4/0,8 = 23(ml)
Vậy :
Đr = 23/240 .100 = 9,583o
Bài 1:
PTHH: \(C_2H_5OH+O_2\xrightarrow[]{mengiấm}CH_3COOH+H_2O\)
Ta có: \(n_{C_2H_5OH}=\dfrac{115\cdot0,8}{46}=2\left(mol\right)=n_{CH_3COOH\left(lýthuyết\right)}\)
\(\Rightarrow m_{CH_3COOH\left(thực\right)}=2\cdot60\cdot90\%=108\left(g\right)\)
Bài 2:
PTHH: \(C_2H_5OH+CH_3COOH\xrightarrow[H_2SO_4\left(đ\right)]{t^o}CH_3COOC_2H_5+H_2O\)
Ta có: \(\left\{{}\begin{matrix}n_{CH_3COOH}=\dfrac{60}{60}=1\left(mol\right)\\n_{C_2H_5OH}=\dfrac{92}{46}=2\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\) Rượu còn dư, Axit p/ứ hết
\(\Rightarrow n_{CH_3COOC_2H_5\left(lýthuyết\right)}=1\left(mol\right)\) \(\Rightarrow m_{CH_3COOC_2H_5\left(thực\right)}=1\cdot88\cdot80\%=70,4\left(g\right)\)
a, \(C_2H_6O+3O_2\underrightarrow{t^o}2CO_2+3H_2O\)
b, \(n_{C_2H_6O}=\dfrac{23}{46}=0,5\left(mol\right)\)
Theo PT: \(n_{O_2}=3n_{C_2H_6O}=1,5\left(mol\right)\)
\(\Rightarrow V_{O_2}=1,5.22,4=33,6\left(l\right)\)
c, \(V_{C_2H_6O}=\dfrac{100.46}{100}=46\left(ml\right)\)
\(\Rightarrow m_{C_2H_6O}=46.0,8=36,8\left(g\right)\)
\(\Rightarrow n_{C_2H_6O}=\dfrac{36,8}{46}=0,8\left(mol\right)\)
PT: \(C_2H_5OH+Na\rightarrow C_2H_5ONa+\dfrac{1}{2}H_2\)
Theo PT: \(n_{H_2}=\dfrac{1}{2}n_{C_2H_5ONa}=0,4\left(mol\right)\)
\(\Rightarrow V_{H_2}=0,4.22,4=8,96\left(l\right)\)
a)
\(V_{C_2H_5OH}=\dfrac{96.20}{100}=19,2\left(ml\right)\)
=> \(m_{C_2H_5OH}=19,2.0,8=15,36\left(g\right)\)
b) \(n_{C_2H_5OH}=\dfrac{15,36}{46}=\dfrac{192}{575}\left(mol\right)\)
\(V_{H_2O}=20-19,2=0,8\left(ml\right)\)
=> \(m_{H_2O}=0,8.1=0,8\left(g\right)\)
=> \(n_{H_2O}=\dfrac{0,8}{18}=\dfrac{2}{45}\left(mol\right)\)
PTHH: 2C2H5OH + 2Na --> 2C2H5ONa + H2
\(\dfrac{192}{575}\)------------------------->\(\dfrac{96}{575}\)
2H2O + 2Na --> 2NaOH + H2
\(\dfrac{2}{45}\)----------------------->\(\dfrac{1}{45}\)
=> \(V_{H_2}=22,4.\left(\dfrac{96}{575}+\dfrac{1}{45}\right)=4,238\left(l\right)\)
C2H5OH + Na -- > C2H5OHNa + 1/2 H2
Na+H2O --- > NaOH + 1/2H2
Vr = 20x96/100 = 19,2ml = 0.0192 (l)
mC2H5OH = D.V = 19,2 x 0.8 = 15.36 (g)
nC2H5OH = m/M = 15.36 / 46 = 0.43 (mol)
=> nH2 = 0.215 (mol)
VH2O = 1 ml => mH2O = 1 (g)
=> nH2O = m/M = 1/18 = 0.056 (mol)
=> nH2 = 0.028 (mol)
nH2 = 0.215 + 0.028 = 0.243 (mol)
=> VH2 = 22.4 x 0,243 = 5,4432 (l)
\(n_{CH_3COOH}=\dfrac{300\cdot5\%}{60}=0.25\left(mol\right)\)
\(2CH_3COOH+Zn\rightarrow\left(CH_3COO\right)_2Zn+H_2\)
\(0.25........................................................0.125\)
\(V_{H_2}=0.125\cdot22.4=2.8\left(l\right)\)
\(n_{C_2H_5OH}=0.1\cdot2=0.2\left(mol\right)\)
\(CH_3COOH+C_2H_5OH⇌CH_3COOC_2H_5+H_2O\left(ĐK:H_2SO_{4\left(đ\right)},t^0\right)\)
\(0.2......................0.2.....................0.2\)
\(\Rightarrow CH_3COOHdư\)
\(m_{CH_3COOC_2H_5}=0.2\cdot88=17.6\left(g\right)\)
a) n CH3COOH = 300.5%/60 = 0,25(mol)
Zn + 2CH3COOH $\to$ (CH3COO)2Zn + H2
Theo PTHH :
n H2 = 1/2 n CH3COOH = 0,25/2 = 0,125(mol)
V H2 = 0,125.22,4 = 2,8(lít)
b) n C2H5OH = 0,1.2 = 0,2(mol)
\(CH_3COOH + C_2H_5OH \buildrel{{H_2SO_4,t^o}}\over\rightleftharpoons CH_3COOC_2H_5 + H_2O\)
Ta thấy :
n CH3COOH = 0,25 > n C2H5OH = 0,2 => CH3COOH dư
n CH3COOC2H5 = n C2H5OH = 0,2 mol
=> m CH3COOC2H5 = 0,2.88 = 17,6 gam
\(n_{H_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\)
PTHH: 2C2H5OH + 2Na ---> 2C2H5ONa + H2
0,5 0,25
\(m_{C_2H_5OH}=0,5.46=23\left(g\right)\\ V_{C_2H_5OH}=\dfrac{23}{0,8}=28,75\left(ml\right)\)
Bạn check lại đề cho mik chứ C2H5OH tác dụng với O2 ko ra H2 được
\(C_2H_5OH+3O_2\underrightarrow{t^o}2CO_2+3H_2O\\ C_2H_5OH+O_2\underrightarrow{men.giấm}CH_3COOH+H_2O\)