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Cho 1,6g CuO tác dụng vừa đủ với 100 ml dung dịch H2SO4.Tính nồng độ mol của dung dịch H2SO4 đã dùng
CuO+H2SO4->CuSO4+H2O
0,02----0,02 mol
n CuO=\(\dfrac{1,6}{80}\)0,02 mol
=>Cm H2SO4=\(\dfrac{0,02}{0,1}\)=0,2 M
\(\text{1)}m_{KOH}=40.35\%=14\left(g\right)\\ \rightarrow n_{KOH}=\dfrac{14}{56}=0,25\left(mol\right)\\ PTHH:KOH+HCl\rightarrow KCl+H_2O\\ \text{Theo pthh}:n_{HCl}=n_{KOH}=0,25\left(mol\right)\\ \rightarrow V_{ddHCl}=0,25.0,5=0,125\left(l\right)\)
\(\text{2)}n_{Al}=\dfrac{4,05}{27}=0,15\left(mol\right)\\ n_{H_2SO_4}=200.14,7\%=29,4\left(g\right)\\ \rightarrow n_{H_2SO_4}=\dfrac{29,4}{98}=0,3\\ \text{PTHH}:2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\uparrow\\ \text{LTL}:\dfrac{0,15}{2}< \dfrac{0,3}{3}\rightarrow H_2SO_4\text{ dư}\)
\(\text{Theo pthh}:\left\{{}\begin{matrix}n_{H_2SO_4\left(pư\right)}=\dfrac{3}{2}n_{Al}=\dfrac{3}{2}.0,15=0,225\left(mol\right)\\n_{H_2}=n_{H_2SO_4\left(pư\right)}=0,225\left(mol\right)\\n_{Al_2\left(SO_4\right)_3}=\dfrac{1}{2}n_{Al}=\dfrac{1}{2}.0,15=0,075\left(mol\right)\end{matrix}\right.\\ \rightarrow m_{dd\left(\text{sau phản ứng}\right)}=200+4,05-0,3.2=203,45\left(g\right)\)
\(\rightarrow\left\{{}\begin{matrix}C\%_{H_2SO_4\text{ dư}}=\dfrac{\left(0,3-0,225\right).98}{203,45}=3,61\%\\C\%_{Al_2\left(SO_4\right)_3}=\dfrac{342.0,075}{203,45}=12,61\%\end{matrix}\right.\)
\(n_{NaOH}=\dfrac{200\cdot4\%}{40}=0.2\left(mol\right)\)
\(2NaOH+H_2SO_4\rightarrow Na_2SO_4+H_2O\)
\(0.2..............0.1..............0.1\)
\(V_{dd_{H_2SO_4}}=\dfrac{0.1}{0.2}=0.5\left(l\right)\)
\(m_{Na_2SO_4}=0.1\cdot142=14.2\left(g\right)\)
\(m_{dd}=200+510=710\left(g\right)\)
\(C\%_{Na_2SO_4}=\dfrac{14.2}{710}\cdot100\%=2\%\)
Ta có: mNaOH = 200.4% = 8 (g)
\(\Rightarrow n_{NaOH}=\dfrac{8}{40}=0,2\left(mol\right)\)
PT: \(2NaOH+H_2SO_4\rightarrow Na_2SO_4+2H_2O\)
_____0,2______0,1_______0,1 (mol)
a, \(V_{ddH_2SO_4}=\dfrac{0,1}{0,2}=0,5\left(l\right)\)
b, Chất có trong dd sau pư là Na2SO4.
Ta có: m dd sau pư = m dd NaOH + m dd H2SO4 = 200 + 510 = 710 (g)
\(\Rightarrow C\%_{Na_2SO_4}=\dfrac{0,1.142}{710}.100\%=2\%\)
Bạn tham khảo nhé!
nZn = 13/65 = 0.2 (mol)
Zn + H2SO4 => ZnSO4 + H2
0.2......0.2..........................0.2
VH2 = 0.2*22.4 = 4.48 (l)
C%H2SO4 = 0.2*98/200 * 100% = 9.8 %
nCuO = 8/80 = 0.1 (mol)
CuO + H2 -to-> Cu + H2O
0.1......0.1...........0.1
=> H2 dư
mCu = 0.1*64 = 6.4 (g)
â) nZn=0,2(mol)
PTHH: Zn + H2SO4 -> ZnSO4 + H2
0,2_____0,2______0,2_____0,2(mol)
=> V(H2,đktc)=0,2.22,4=4,48(l)
b) C%ddH2SO4= [(98.0,2)/200)].100=9,8%
c) nCuO=0,1(mol)
PTHH: CuO + H2 -to-> Cu + H2O
Ta có: 0,1/1 < 0,2/1
=> H2 dư, CuO hết, tính theo nCuO
=> nCu=nCuO=0,1(mol)
=>mCu=6,4(g)
Câu 1:
PTHH: \(NaOH+HCl\rightarrow NaCl+H_2O\)
Ta có: \(n_{HCl}=0,2\cdot2=0,4\left(mol\right)=n_{NaOH}\)
\(\Rightarrow C_{M_{NaOH}}=\dfrac{0,4}{0,2}=2\left(M\right)\)
Câu 2: Bạn xem lại đề !!
a,\(n_{Zn}=\dfrac{9,75}{65}=0,15\left(mol\right)\)
PTHH: Zn + H2SO4 → ZnSO4 + H2
Mol: 0,15 0,15 0,15
\(\Rightarrow C_{M_{ddH_2SO_4}}=\dfrac{0,15}{0,06}=2,5M\)
b, \(V_{H_2}=0,15.22,4=3,36\left(l\right)\)
- Giả sử có 100 gam dd H2SO4 98%
\(m_{H_2SO_4}=\dfrac{100.98}{100}=98\left(g\right)\) => \(n_{H_2SO_4}=\dfrac{98}{98}=1\left(mol\right)\)
\(V_{dd.H_2SO_4.98\%}=\dfrac{100}{1,84}=\dfrac{1250}{23}\left(ml\right)=\dfrac{5}{92}\left(l\right)\)
\(C_{M\left(dd.H_2SO_4.98\%\right)}=\dfrac{1}{\dfrac{5}{92}}=18,4M\)
-
\(n_{H_2SO_4}=18,4.0,05=0,92\left(mol\right)\)
=> \(m_{H_2SO_4}=0,92.98=90,16\left(g\right)\)
=> \(m_{dd.H_2SO_4.10\%}=\dfrac{90,16.100}{10}=901,6\left(g\right)\)