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![](https://rs.olm.vn/images/avt/0.png?1311)
\(n_{H_2S}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
\(n_{NaOH}=0,15.1=0,15\left(mol\right)\)
Xét tỉ lệ: \(\dfrac{n_{NaOH}}{n_{H_2S}}=\dfrac{0,15}{0,1}=1,5\)
=> Tạo ra 2 muối Na2S, NaHS
PTHH: 2NaOH + H2S --> Na2S + 2H2O
a------>0,5a---->0,5a
NaOH + H2S --> NaHS + H2O
b----->b-------->b
=> \(\left\{{}\begin{matrix}a+b=0,15\\0,5a+b=0,1\end{matrix}\right.\)
=> a = 0,1 (mol); b = 0,05 (mol)
=> \(\left\{{}\begin{matrix}m_{Na_2S}=0,05.78=3,9\left(g\right)\\m_{NaHS}=0,05.56=2,8\left(g\right)\end{matrix}\right.\)
\(\left\{{}\begin{matrix}C_{M\left(Na_2S\right)}=\dfrac{0,05}{0,15}=0,33M\\C_{M\left(NaHS\right)}=\dfrac{0,05}{0,15}=0,33M\end{matrix}\right.\)
![](https://rs.olm.vn/images/avt/0.png?1311)
mH2S= 5.1g
nH2S= 0.15 (mol)
nNaOH= 0.25 (mol)
T=nNaOH/nH2S= 0.25/0.151.7
1<T<2 => tạo ra 2 muối Na2S và NaHS
Đặt: nNa2S= x (mol), nNaHS= y (mol)
2NaOH + H2S --> Na2S + 2H2O
NaOH + H2O --> NaHS + H2O
nNaOH= 2x + y = 0.25 (mol) (1)
nH2S= x +y= 0.15 (mol) (2)
Giải pt (1) và (2) :
x= 0.1
y=0.05
mNa2S= 0.1*78=7.8g
mNaHS= 0.05*56=2.8g
2/ 2H2S + 3O2 -to-> 2SO2 + 2H2O
nH2S= 8.96/22.4= 0.4 (mol)
Từ PTHH trên có: nSO2= 0.4 (mol)
mddNaOH= 50*1.28=64g
mNaOH= 64*25/100=16g
nNaOH= 0.4
T= nNaOH/nH2S=1 => chỉ tạo ra muối NaHS
mNaHS= 0.4*56=22.4g
Chúc bạn học tốt <3
![](https://rs.olm.vn/images/avt/0.png?1311)
Giải thích các bước giải:
nH2S = 3,36/22,4= 0,15 mol
- Giả sử muối sinh ra là Na2S
2NaOH + H2S → Na2S + 2H2O
0,15 0,15 (mol)
Theo PT ⇒ nNa2S = nH2S = 0,15 mol
⇒ m muối = 0,15.78 = 11,7 gam
\(n_{NaOH}=0,25.1=0,25\left(mol\right)\\ n_{H_2S}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)
\(T=\dfrac{0,25}{0,15}=\dfrac{5}{3}\rightarrow\) Tạo cả 2 muối
Gọi \(\left\{{}\begin{matrix}n_{NaOH\left(\text{tạo muối trung hoà}\right)}=a\left(mol\right)\\n_{NaOH\left(\text{tạo muối axit}\right)}=b\left(mol\right)\end{matrix}\right.\)
PTHH:
2NaOH + H2S ---> Na2S + 2H2O
a \(\dfrac{a}{2}\) \(\dfrac{a}{2}\)
NaOH + H2S ---> NaHS + H2O
b b b
Hệ pt \(\left\{{}\begin{matrix}a+b=0,25\\\dfrac{a}{2}+b=0,15\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,2\left(mol\right)\\b=0,05\left(mol\right)\end{matrix}\right.\)
\(\rightarrow m_{muối}=\dfrac{0,2}{2}.78+0,05.56=10,6\left(g\right)\)
![](https://rs.olm.vn/images/avt/0.png?1311)
\(n_{CaCO_3}=\dfrac{40}{100}=0,4\left(mol\right)\\ CaCO_3+2HCl\rightarrow CaCl_2+CO_2+H_2O\\ CO_2+2NaOH\rightarrow Na_2CO_3+H_2O\\ n_{CO_2}=n_{CaCO_3}=0,4\left(mol\right)\\ \Rightarrow n_{NaOH}=0,4.2=0,8\left(mol\right)\\ m_{NaOH}=0,8.40=32\left(g\right)\\ \Rightarrow m_{ddNaOH}=\dfrac{32.100}{25}=128\left(g\right)\\ \Rightarrow V_{ddNaOH}=\dfrac{m_{ddNaOH}}{D_{ddNaOH}}=\dfrac{128}{1,28}=100\left(ml\right)=0,1\left(l\right)\)
![](https://rs.olm.vn/images/avt/0.png?1311)
Chị đã biết tư tâm dưỡng tính rồi đó .
![](https://rs.olm.vn/images/avt/0.png?1311)
Câu 1:
Gọi : nMg=a(mol); nMgO=b(mol) (a,b>0)
a) PTHH: Mg + 2 HCl -> MgCl2 + H2
a________2a_______a______a(mol)
MgO +2 HCl -> MgCl2 + H2O
b_____2b_______b___b(mol)
Ta có hpt:
\(\left\{{}\begin{matrix}24a+40b=8,8\\22,4a=4,48\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,2\\b=0,1\end{matrix}\right.\)
=> mMg=0,2.24=4,8(g)
=>%mMg= (4,8/8,8).100=54,545%
=> %mMgO= 45,455%
b) m(muối)=mMg2+ + mCl- = 0,3. 24 + 0,6.35,5=28,5(g)
c) V=VddHCl=(2a+2b)/2=0,3(l)=300(ml)
Câu 2:
Ta có: \(\left\{{}\begin{matrix}n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\\n_{HCl}=0,4\cdot2=0,8\left(mol\right)\end{matrix}\right.\)
PTHH: \(Ca+2HCl\rightarrow CaCl_2+H_2\uparrow\)
0,2____0,4_____0,2____0,2 (mol)
\(CaO+2HCl\rightarrow CaCl_2+H_2O\)
0,2____0,4______0,2____0,2 (mol)
Ta có: \(\left\{{}\begin{matrix}\%m_{Ca}=\dfrac{0,2\cdot40}{0,2\cdot40+0,2\cdot56}\cdot100\%\approx41,67\%\\\%m_{CaO}=58,33\%\\m_{CaCl_2}=\left(0,2+0,2\right)\cdot111=44,4\left(g\right)\end{matrix}\right.\)
\(n_{H_2S}=\dfrac{2.24}{22.4}=0.1\left(mol\right)\)
\(n_{NaOH}=0.3\cdot0.5=0.15\left(mol\right)\)
\(\dfrac{n_{NaOH}}{n_{H_2S}}=\dfrac{0.15}{0.1}=1.5\)
\(\rightarrow\text{Phản ứng tạo ra 2 muối}\)
\(n_{Na_2S}=a\left(mol\right),n_{NaHS}=b\left(mol\right)\)
\(\left\{{}\begin{matrix}2a+b=0.15\\a+b=0.1\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}a=0.05\\b=0.05\end{matrix}\right.\)
\(m_{\text{Muối}}=0.05\cdot78+0.05\cdot56=6.7\left(g\right)\)